Citation: Qi Cao, Zhihuan Weng, Yu Qi, Jiahui Li, Wentao Liu, Chengde Liu, Shouhai Zhang, Zhiyong Wei, Yousi Chen, Xigao Jian. Achieving higher performances without an external curing agent in natural magnolol-based epoxy resin[J]. Chinese Chemical Letters, ;2022, 33(4): 2195-2199. doi: 10.1016/j.cclet.2021.09.025 shu

Achieving higher performances without an external curing agent in natural magnolol-based epoxy resin

State Key Laboratory of Fine Chemicals, Liaoning High Performance Resin Engineering Research Center, Department of Polymer Science & Engineering, Dalian University of Technology, Dalian 116024, China

zweng@dlut.edu.cn

Received Date: 9 July 2021
Revised Date: 14 August 2021
Accepted Date: 6 September 2021
Available Online: 11 September 2021

Figures(5)

Bio-based epoxy thermoset prepared from renewable biomass raw materials can alleviate fossil energy crisis and reduce environmental pollution, which satisfies the needs of sustainable social development. In this study, a bio-based epoxy thermoset precursor (MGOL-EP) was synthesized from a naturally occurring magnolol through a facile and efficient one-step process. And the fully bio-based epoxy thermoset (MGOL-EP-SC) was obtained by self-curing without adding any other hardener. MGOL-EP-SC revealed an extremely high glass-transition temperature (T_g) of 265 ℃ and char yield of 53.2% (in N₂), which were at the highest level among the fully bio-based epoxy thermosets reported so far. In addition, when the MGOL-EP was cured with 4, 4′-methylenedianiline (DDM), T_g of the MGOL-EP/DDM was decreased by 61 ℃ and the other comprehensive performance had also been decreased, which was due to a reduction in biphenyl structure content and cross-linking density by adding the external curing agents. Moreover, the MGOL-EP-SC presented certain killing rate (48.4%) to Staphylococcus aureus. These findings provide a new design strategy for engineering high-performance and functional epoxy thermoset with high biomass content.
- Epoxy resin,
- Magnolol,
- Self-curing,
- Fully bio-based,
- Antimicrobial properties
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