Citation: Siyi Rong, Pengcheng Su, Shizheng Chen, Miaomiao Jia, Wanbin Li. Sub-5 nm porous polymer decoration toward superhydrophobic MOFs with enhanced stability and processability[J]. Chinese Chemical Letters, ;2022, 33(4): 2134-2138. doi: 10.1016/j.cclet.2021.09.012 shu

Sub-5 nm porous polymer decoration toward superhydrophobic MOFs with enhanced stability and processability

Guangdong Key Laboratory of Environmental Pollution and Health, School of Environment, Jinan University, Guangzhou 511443, China

pengchengsu@jnu.edu.cn

gandeylin@126.com

Received Date: 9 July 2021
Revised Date: 24 August 2021
Accepted Date: 2 September 2021
Available Online: 8 September 2021

Figures(5)

Metal-organic frameworks (MOFs) show great potential for various applications, but many of them suffer from the drawbacks of hydrolysis propensity and poor processability. Herein, we employ polymers of intrinsic microporosity (PIMs) with hydrophobic pores to decorate MOFs toward substantially improved water stability and shapeability. Through simple PIM-1 decoration, the sub-5 nm polymer layers can be uniformly deposited on MOF surfaces with almost no deterioration in porosity. Owing to the existence of superhydrophobic coating and the obstruction of water entrance into MOFs, the PIM-1 coated CuBTC exhibits impressive water resistance and excellent pore preservation ability after exposure in water, even in acidic and alkaline solutions. Moreover, polymer decoration improves the processability of MOFs, while various MOF/PIM-1 bulk wafers and oil-water separators can be obtained straightforwardly.
- Metal-organic framework,
- Porous polymer decoration,
- Hydrophobicity,
- Stability,
- Processability
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