Citation: Jian-Jun Dai, Xin-Xin Teng, Wen Fang, Jun Xu, Hua-Jian Xu. Electrochemically promoted decarboxylative borylation of alkyl N-hydroxyphthalimide esters[J]. Chinese Chemical Letters, ;2022, 33(3): 1555-1558. doi: 10.1016/j.cclet.2021.09.011 shu

Electrochemically promoted decarboxylative borylation of alkyl N-hydroxyphthalimide esters

Jian-Jun Dai ^{a, b, *,} ,
Xin-Xin Teng ^a ,
Wen Fang ^a ,
Jun Xu ^{a, b} ,
Hua-Jian Xu ^{a, b, *,}

a.
School of Food and Biological Engineering, Hefei University of Technology, Hefei 230009, China
b.
Anhui Province Key Laboratory of Advance Catalytic Materials and Reaction Engineering, Hefei University of Technology, Hefei 230009, China

daijj@hfut.edu.cn

hjxu@hfut.edu.cn

Received Date: 1 July 2021
Revised Date: 30 August 2021
Accepted Date: 1 September 2021
Available Online: 8 September 2021

Figures(3)

An electrochemically promoted decarboxylative borylation reaction is reported. The reaction proceeds under mild conditions in an undivided cell without use of transition metal- or photo-catalysts. The key feature of the reaction is the compatibility of diboron reagents with the electrochemical conditions. This reaction exhibits broad substrate scope, good functional group tolerability, and easy scalability.
- Electrochemical,
- Decarboxylation,
- Borylation,
- Alkyl boronic esters,
- Redox active esters
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