Citation: Qi Gan, Mingli Fu, Peng Liu, Yuchen Zhang, Juxia Xiong, Jinping Zhong, Lei Liu, Junliang Wu, Xiaojun Niu, Yun Hu, Daiqi Ye. Synergistic catalytic ozonation of toluene with manganese and cerium varies at low temperature[J]. Chinese Chemical Letters, ;2022, 33(5): 2726-2730. doi: 10.1016/j.cclet.2021.09.006 shu

Synergistic catalytic ozonation of toluene with manganese and cerium varies at low temperature

Qi Gan ^a ,
Mingli Fu ^{a, b, c, d, *,} ,
Peng Liu ^a ,
Yuchen Zhang ^a ,
Juxia Xiong ^a ,
Jinping Zhong ^a ,
Lei Liu ^a ,
Junliang Wu ^{a, b, c, d} ,
Xiaojun Niu ^a ,
Yun Hu ^a ,
Daiqi Ye ^{a, b, c, d}

a.
School of Environment and Energy, South China University of Technology, Guangzhou 510006, China
b.
National Engineering Laboratory for VOCs Pollution Control Technology and Equipment (SCUT), Guangzhou 510006, China
c.
Guangdong Provincial Key Laboratory of Atmospheric Environment and Pollution Control (SCUT), Guangzhou 510006, China
d.
Guangdong Provincial Engineering and Technology Research Center for Environmental Risk Prevention and Emergency Disposal (SCUT), Guangzhou 510006, China

mlfu@scut.edu.cn

Received Date: 9 July 2021
Revised Date: 20 August 2021
Accepted Date: 2 September 2021
Available Online: 9 September 2021

Figures(4)

The temperature of waste gas in refuse transfer station, airport smoking area, and RTO terminal is low, which needs deep oxidation. Catalytic ozonation is one of the most effective treatment techniques in these scenarios. In this study, we reported that catalysts were modified under the condition of magnetic field to simulate the low temperature dynamic conditions of low concentration toluene for catalytic ozonation. This paper aims to explore the relationship between oxygen vacancy and active oxygen species, and the specific pathways of toluene oxidation. The study found that citric acid can enhance the synergistic effect between Mn and Ce, and promote the generation of oxygen vacancies. The surface molecule adsorption oxygen is more conducive to catalytic oxidation than subsurface atom adsorption oxygen. Finally, we proposed the main pathways of toluene in this reaction system, which runs through the whole process of the reaction.
- Ozone,
- Oxygen vacancy,
- Active oxygen species,
- Synergism,
- Pathway
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