Citation: Zhanqi Cao, Dongpu Wu, Mengzhen Li, Fan Yang, Zhikai Li, Wankai An, Song Jiang, Xin Zheng, Caoyuan Niu, Dahui Qu. An acid-base responsive linear-cyclic polymer rotaxane molecular shuttle with fluorescence signal output[J]. Chinese Chemical Letters, ;2022, 33(3): 1533-1536. doi: 10.1016/j.cclet.2021.09.001 shu

An acid-base responsive linear-cyclic polymer rotaxane molecular shuttle with fluorescence signal output

Zhanqi Cao ^{a, *,} ,
Dongpu Wu ^a ,
Mengzhen Li ^a ,
Fan Yang ^a ,
Zhikai Li ^c ,
Wankai An ^a ,
Song Jiang ^a ,
Xin Zheng ^a ,
Caoyuan Niu ^a ,
Dahui Qu ^{b, *,}

a.
College of Science, Henan Agricultural University, Zhengzhou 450002, China
b.
Key Laboratory for Advanced Materials and Joint International Research Laboratory of Precision Chemistry and Molecular Engineering, Feringa Nobel Prize Scientist Joint Research Center, Frontiers Science Center for Materiobiology and Dynamic Chemistry, Institute of Fine Chemicals, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, China
c.
College of Chemistry and Environmental Engineering, Shenzhen University, Shenzhen 518060, China

zqcao@henau.edu.cn

dahui_qu@ecust.edu.cn

Received Date: 30 May 2021
Revised Date: 28 August 2021
Accepted Date: 1 September 2021
Available Online: 27 September 2021

Figures(6)

The preparation of intelligent-responsive materials with controllable topology structure has long been a significant objective for chemists in the field of materials science. In this paper, we designed and prepared a linear-cyclic reversible topological structure polymer based on the bistable [1]rotaxane molecular shuttle. A ferrocene-functionalized [1]rotaxane and naphthalimide fluorophore group are introduced into the both ends of the polymer, which exhibit distance-induced photo-electron transfer effect. The structural transformation between linear and cyclic state of polymer is demonstrated by simple acid-base stimuli, accompanying visual fluorescence changes. The transformation process was characterized by ¹H NMR spectra and fluorescence spectra. This work provides a novel strategy to construct functionalized polymers with topological structure.
- Supramolecular polymer,
- Rotaxane molecular shuttle,
- Stimuli responsive,
- Fluorescence signal,
- Topological structure
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