Citation: Yanru Zhu, Minghuan Yang, Zhen Zhang, Zhe An, Jian Zhang, Xin Shu, Jing He. NiCu bimetallic catalysts derived from layered double hydroxides for hydroconversion of n-heptane[J]. Chinese Chemical Letters, ;2022, 33(4): 2069-2072. doi: 10.1016/j.cclet.2021.08.120 shu

NiCu bimetallic catalysts derived from layered double hydroxides for hydroconversion of n-heptane

State Key Laboratory of Chemical Resource Engineering, Beijing Advanced Innovation Center for Soft Matter Science and Engineering, Beijing University of Chemical Technology, Beijing 100029, China

jinghe@263.net.cn

hejing@mail.buct.edu.cn

Received Date: 9 May 2021
Revised Date: 29 July 2021
Accepted Date: 29 August 2021
Available Online: 4 September 2021

Figures(4)

Supported NiCu bimetallic catalysts have been produced in-situ on commercial Al₂O₃ by using layered double hydroxides as precursors. The resulting catalysts show a uniform Ni and Cu distribution, thus providing good activity and selectivity in the reforming reaction of n-heptane. The catalytic performance has been found to depend on the Cu/Ni ratio, revealing the synergic catalysis between homogeneously dispersed Ni and Cu sites. The good catalysis of NiCu bimetallic catalysts makes it possible to partly or even completely replace Pt with NiCu bimetallic catalysts.
- n-Heptane reforming,
- NiCu bimetallic catalysts,
- Synergic catalysis,
- Uniform distribution,
- Layered double hydroxides
1. [1]
  G.J. Antos, A.M. Aitani, Catalytic Naphtha Reforming, Revised and Expanded, second ed., CRC Press, New York, 2004
2. [2]
  V. Haensel, U.S. Patent 2 611 736, 1952 (UOP)
3. [3]
  H.E. Kluksdahl, U.S. Patent 3 415 737, 1968 (UOP)
4. [4]
  N. Parsafard, M.H. Peyrovi, N. Parsafard, Chin. Chem. Lett. 28 (2017) 546-552 doi: 10.1016/j.cclet.2016.10.028
5. [5]
  Á. Morales-García, F. Calle-Vallejo, F. Illas, ACS Catal. 10 (2020) 13487-13503 doi: 10.1021/acscatal.0c03106
6. [6]
  J.G. Chen, B. Fruhberger, J. Eng Jr., et al., J. Mol. Catal. A: Chem. 131 (1998) 285-299 doi: 10.1016/S1381-1169(97)00271-9
7. [7]
  A.P.E. York, C. Pham-Huu, P.D. Gallo, M.J. Ledoux, Catal. Today 35 (1997) 51-57 doi: 10.1016/S0920-5861(96)00134-4
8. [8]
  L.O. Alemán-Vázquez, F. Hernández-Pérez, J.L. Cano-Domínguez, et al., Fuel 117 (2014) 463-469 doi: 10.1016/j.fuel.2013.08.085
9. [9]
  H. Al-Kandari, S. Al-Kandari, F. Al-Kharafi, A. Katrib, Energy Fuels 23 (2009) 5737-5742 doi: 10.1021/ef900617d
10. [10]
  H. Al-Kandari, F. Al-Kharafi, A. Katrib, Appl. Catal. A 383 (2010) 141-148 doi: 10.1016/j.apcata.2010.05.043
11. [11]
  J. Kim, S.W. Han, J.C. Kim, et al., ACS Catal. 8 (2018) 10545-10554 doi: 10.1021/acscatal.8b03301
12. [12]
  P. Lanzafame, S. Perathoner, G. Centi, et al., ChemCatChem 9 (2017) 1632-1640 doi: 10.1002/cctc.201601670
13. [13]
  A. Corma, A. Martinez, S. Pergher, et al., Appl. Catal. A 152 (1997) 107-125 doi: 10.1016/S0926-860X(96)00338-9
14. [14]
  Y. Tan, W. Hu, Y. Du, et al., Appl. Catal. A 611 (2021) 117916 doi: 10.1016/j.apcata.2020.117916
15. [15]
  D. Li, F. Li, J. Ren, Y. Sun, Appl. Catal. A 241 (2003) 15-24 doi: 10.1016/S0926-860X(02)00454-4
16. [16]
  I. Eswaramoorthi, N. Lingappan, Appl. Catal. A 245 (2003) 119-135 doi: 10.1016/S0926-860X(02)00637-3
17. [17]
  M.H. Jordão, V. Simões, D. Cardoso, Appl. Catal. A 319 (2007) 1-6 doi: 10.1016/j.apcata.2006.09.039
18. [18]
  S. Veldurthi, C.H. Shin, O.S. Joo, K.D. Jung, Catal. Today 185 (2012) 88-93 doi: 10.1016/j.cattod.2011.11.021
19. [19]
  M. Laipan, J. Yu, R. Zhu, et al., Mater. Horiz. 7 (2020) 715-745 doi: 10.1039/c9mh01494b
20. [20]
  Y. Zhu, H. Guo, J. Zhang, et al., Ind. Eng. Chem. Res. 59 (2020) 8649-8660 doi: 10.1021/acs.iecr.0c00954
21. [21]
  Y. Zhu, J. Zhang, X. Ma, et al., J. Catal. 389 (2020) 78-86 doi: 10.1016/j.jcat.2020.05.027
22. [22]
  G. Fan, F. Li, D.G. Evans, et al., Chem. Soc. Rev. 43 (2014) 7040-7066 doi: 10.1039/C4CS00160E
23. [23]
  Y. Cao, H. Zhang, S. Ji, et al., Angew. Chem. Int. Ed. 59 (2020) 11647-11652 doi: 10.1002/anie.202004966
24. [24]
  Y. Zhu, W. Zhao, J. Zhang, et al., ACS Catal. 10 (2020) 8032-8041 doi: 10.1021/acscatal.0c01276
25. [25]
  Y. Zhu, Z. An, J. He, J. Catal. 341 (2016) 44-54 doi: 10.1016/j.jcat.2016.06.004
26. [26]
  M.B. Barakat, M. Motlak, A.A. Elzatahry, K.A. Khalil, E.A.M. Abdelghani, Int. J. Hydrogen Energy 39 (2014) 305-316 doi: 10.1016/j.ijhydene.2013.10.061
27. [27]
  Y. Yang, S. Li, C. Xie, et al., Chin. Chem. Lett. 30 (2019) 203-206 doi: 10.1016/j.cclet.2018.04.006
28. [28]
  H. Liang, P. Hua, Y. Zhou, et al., Chin. Chem. Lett. 30 (2019) 2245-2248 doi: 10.1016/j.cclet.2019.05.046
29. [29]
  F. Locatelli, J.P. Candy, B. Didillon, G.P. Niccolai, et al., J. Am. Chem. Soc. 123 (2001) 1658-1663 doi: 10.1021/ja000290j
30. [30]
  C. Poupin, L. Pirault-Roy, C.L. Fontaine, et al., J. Catal. 272 (2010) 315-319 doi: 10.1016/j.jcat.2010.04.013
31. [31]
  I. Gandarias, J. Requies, P.L. Arias, et al., J. Catal. 290 (2012) 79-89 doi: 10.1016/j.jcat.2012.03.004
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