Citation: Li-Fei Tian, Ming Liu, Li-Xia Chen, Chao Huang, Qian-Jiang Zhu, Kai Chen, Jiang-Lin Zhao, Zhu Tao. Q[8]/SC[6]A-based framework constructed via OSIQ for metal ion capture[J]. Chinese Chemical Letters, ;2022, 33(3): 1524-1528. doi: 10.1016/j.cclet.2021.08.106 shu

Q[8]/SC[6]A-based framework constructed via OSIQ for metal ion capture

Li-Fei Tian ^a ,
Ming Liu ^a ,
Li-Xia Chen ^a ,
Chao Huang ^a ,
Qian-Jiang Zhu ^a ,
Kai Chen ^{b, *,} ,
Jiang-Lin Zhao ^{c, *,} ,
Zhu Tao ^{a, *,}

a.
Key Laboratory of Macrocyclic and Supramolecular Chemistry of Guizhou Province, Guizhou University, Guiyang 550025, China
b.
Jiangsu Collaborative Innovation Center of Atmospheric Environment and Equipment Technology, Jiangsu Key Laboratory of Atmospheric Environment Monitoring and Pollution Control, School of Environmental Science and Engineering, Nanjing University of Information Science & Technology, Nanjing 210044, China
c.
Institute of Biomedical & Health Engineering, Shenzhen Institute of Advanced Technology, Chinese Academy of Sciences, Shenzhen, 518055 China

kaichen85@nuist.edu.cn

jl.zhao@siat.ac.cn

gzutao@263.net

Received Date: 5 June 2021
Revised Date: 19 August 2021
Accepted Date: 24 August 2021
Available Online: 30 August 2021

Figures(4)

Since the outer surface interaction of Q[n]s (OSIQ, including self-, anion- and aromatic-induced OSIQs) was proposed in 2014, it has become the most important research area in our group to construct various Q[n]-based supramolecular frameworks via the OSIQ strategy. Herein, we report a novel supramolecular framework constructed using cucurbit[8]uril (Q[8]) and 4-sulfocalix[6]arene (SC[6]A). This Q[8]/SC[6]A-based supramolecular framework is a product via the perfect combination of self-, anion- and aromatic-induced OSIQs. This framework has the characteristics of easy preparation and high stability with the most important feature being the sequence selective capture of specific metal cations, such as common alkali- and alkaline earth metal ions, and renewability. Thus, this framework may be used in seawater desalination, potassium ion enrichment, radioactive cesium ion pollution source treatment, Gruinard's treatment or water softening and other applications.
- Cucurbit[8]uril,
- 4-Sulfocalix[6]arene,
- Outer surface interaction of Q[n]s,
- Supramolecular framework,
- Metal ion capture
1. [1]
  W.A. Freeman, W.L. Mock, N.Y. Shih, J. Am. Chem. Soc. 103 (1981) 7367-7368. doi: 10.1021/ja00414a070
2. [2]
  A.I. Day, A.P. Arnold, R.J. Blanch, (Unisearch Limited, Australia), PCT Int. Appl. 2000, WO2000-2000AU41220000505, 112 (Priority: AU 99-23219990507), 2016.
3. [3]
  J. Kim, I.S. Jung, S.Y. Kim, et al., J. Am. Chem. Soc. 122 (2000) 540-541. doi: 10.1021/ja993376p
4. [4]
  A.I. Day, R.J. Blanch, A.P. Arnold, et al., Angew. Chem. Int. Ed. 41 (2002) 275-277. doi: 10.1002/1521-3773(20020118)41:2<275::AID-ANIE275>3.0.CO;2-M
5. [5]
  X.J. Cheng, L.L. Liang, K. Chen, et al., Angew. Chem. Int. Ed. 52 (2013) 7252-7255. doi: 10.1002/anie.201210267
6. [6]
  K. Kim, N. Selvapalam, Y.H. Ko, et al., Chem. Soc. Rev. 36 (2007) 267-279. doi: 10.1039/B603088M
7. [7]
  K.I. Assaf, W.M. Nau, Chem. Soc. Rev. 44 (2015) 394-418. doi: 10.1039/C4CS00273C
8. [8]
  W. Liu, S.K. Samanta, B.D. Smith, L. Isaacs, Chem. Soc. Rev. 46 (2017) 2391-2403. doi: 10.1039/C7CS00011A
9. [9]
  J. Murray, K. Kim, T. Ogoshi, W. Yao, B.C. Gibb, Chem. Soc. Rev. 46 (2017) 2479-2496. doi: 10.1039/C7CS00095B
10. [10]
  R. Pinalli, A. Pedrini, E. Dalcanale, Chem. Soc. Rev. 47 (2018) 7006-7026. doi: 10.1039/C8CS00271A
11. [11]
  J. Mosquera, Y. Zhao, H. Jang, et al., Adv. Funct. Mater. (2019) 190208. doi: 10.1002/adfm.201902082
12. [12]
  O.A. Gerasko, M.N. Sokolov, V.P. Fedin, Pure Appl. Chem. 76 (2004) 1633-1646. doi: 10.1351/pac200476091633
13. [13]
  J. Lü, J.X. Lin, M.N. Cao, R. Cao, Coord. Chem. Rev. 257 (2013) 1334-1356. doi: 10.1016/j.ccr.2012.12.014
14. [14]
  X.L. Ni, X. Xiao, H. Cong, et al., Chem. Soc. Rev. 42 (2013) 9480-9508. doi: 10.1039/c3cs60261c
15. [15]
  X.L. Ni, S.F. Xue, Z. Tao, et al., Coord. Chem. Rev. 287 (2015) 89-113. doi: 10.1016/j.ccr.2014.12.018
16. [16]
  X.L. Ni, X. Xiao, H. Cong, et al., Acc. Chem. Res. 47 (2014) 1386-1395. doi: 10.1021/ar5000133
17. [17]
  Y. Huang, R.H. Gao, X.L. Ni, et al., Angew. Chem. Int. Ed. 60 (2021) 15166-15191. doi: 10.1002/anie.202002666
18. [18]
  X.Y. Lou, Y.P. Li, Y.W. Yang, Biotechnol. J. 14 (2019) 1800354. doi: 10.1002/biot.201800354
19. [19]
  H. Zhang, R. Zou, Y. Zhao, Coord. Chem. Rev. 292 (2015) 74-90. doi: 10.1016/j.ccr.2015.02.012
20. [20]
  O. Bistri, O. Reinaud, Org. Biomol. Chem. 13 (2015) 2849-2865. doi: 10.1039/C4OB02511C
21. [21]
  R.G. Lin, L.S. Long, R.B. Huang, L.S. Zheng, Cryst. Growth Des. 8 (2008) 791-794. doi: 10.1021/cg701084x
22. [22]
  X. Tian, L.X. Chen, Y.Q. Yao, et al., ACS Omega 3 (2018) 6665-6672. doi: 10.1021/acsomega.8b00829
23. [23]
  Y.Q. Yao, Y.J. Zhang, C. Huang, et al., Chem. Mater. 39 (2017) 5468-5472. doi: 10.1021/acs.chemmater.7b01751
24. [24]
  L.X. Chen, M. Liu, Y.Q. Zhang, et al., Chem. Commun. 55 (2019) 14271-14274. doi: 10.1039/C9CC07147D
25. [25]
  Z. Zeng, Y. Zhang, X. Zhang, et al., Chin. Chem. Lett. 32 (2021) 2572-2576. doi: 10.1016/j.cclet.2021.03.071
26. [26]
  X. Qian, S. Deng, X. Chen, et al., Chin. Chem. Lett. 31 (2020) 2211-2214. doi: 10.1016/j.cclet.2019.09.024
27. [27]
  N. Liu, L. Shia, X. Han, et al., Chin. Chem. Lett. 31 (2020) 386-390. doi: 10.1016/j.cclet.2019.06.050
28. [28]
  X. Li, T. Lu, Y. Wang, Y. Yang, Chin. Chem. Lett. 30 (2019) 2318-2322. doi: 10.1016/j.cclet.2019.05.056
1. [1]
  Qian Ren , Xue Dai , Ran Cen , Yang Luo , Mingyang Li , Ziyun Zhang , Qinghong Bai , Zhu Tao , Xin Xiao . A cucurbit[8]uril-based supramolecular phosphorescent assembly: Cell imaging and sensing of amino acids in aqueous solution. Chinese Chemical Letters, 2024, 35(12): 110022-. doi: 10.1016/j.cclet.2024.110022
2. [2]
  Yu Xia , Yangming Jiang , Xin-Long Ni , Qiaochun Wang , Daoping Wang . A macrocycle-based "Russian doll": The smallest cucurbit[4]uril in cucurbit[10]uril. Chinese Chemical Letters, 2024, 35(12): 109782-. doi: 10.1016/j.cclet.2024.109782
3. [3]
  Shaojie Deng , Peihua Ma , Qinghong Bai , Xin Xiao . The transformation of nor-seco-cucurbit[10]uril to cucurbit[5]uril and cucurbit[8]uril controlled by its own concentration. Chinese Chemical Letters, 2025, 36(2): 109878-. doi: 10.1016/j.cclet.2024.109878
4. [4]
  Lijun Mao , Shuo Li , Xin Zhang , Zhan-Ting Li , Da Ma . Cucurbit[n]uril-based nanostructure construction and modification. Chinese Chemical Letters, 2024, 35(8): 109363-. doi: 10.1016/j.cclet.2023.109363
5. [5]
  Ran Cen , Yan-Yan Tang , Li-Xia Chen , Zhu Tao , Xin Xiao . A novel supramolecular assembly based on nor-seco-cucurbit[10]uril for spermine sensing and artificial light-harvesting. Chinese Chemical Letters, 2025, 36(1): 109744-. doi: 10.1016/j.cclet.2024.109744
6. [6]
  Ke-Ai Zhou , Lian Huang , Xing-Ping Fu , Li-Ling Zhang , Yu-Ling Wang , Qing-Yan Liu . Fluorinated metal-organic framework for methane purification from a ternary CH4/C2H6/C3H8 mixture. Chinese Journal of Structural Chemistry, 2023, 42(11): 100172-100172. doi: 10.1016/j.cjsc.2023.100172
7. [7]
  Jianqiu Li , Yi Zhang , Songen Liu , Jie Niu , Rong Zhang , Yong Chen , Yu Liu . Cucurbit[8]uril-based non-covalent heterodimer realized NIR cell imaging through topological transformation from nanowire to nanorod. Chinese Chemical Letters, 2024, 35(10): 109645-. doi: 10.1016/j.cclet.2024.109645
8. [8]
  Ying Li , Yanjun Xu , Xingqi Han , Di Han , Xuesong Wu , Xinlong Wang , Zhongmin Su . A new metal–organic rotaxane framework for enhanced ion conductivity of solid-state electrolyte in lithium-metal batteries. Chinese Chemical Letters, 2024, 35(9): 109189-. doi: 10.1016/j.cclet.2023.109189
9. [9]
  Zhijie Zhang , Xun Li , Huiling Tang , Junhao Wu , Chunxia Yao , Kui Li . Cs₂CuBr₄ perovskite quantum dots confined in mesoporous CuO framework as a p-n type S-scheme heterojunction for efficient CO₂ photoconversion. Chinese Chemical Letters, 2024, 35(11): 109700-. doi: 10.1016/j.cclet.2024.109700
10. [10]
  Hui-Juan Wang , Wen-Wen Xing , Zhen-Hai Yu , Yong-Xue Li , Heng-Yi Zhang , Qilin Yu , Hongjie Zhu , Yao-Yao Wang , Yu Liu . Cucurbit[7]uril confined phenothiazine bridged bis(bromophenyl pyridine) activated NIR luminescence for lysosome imaging. Chinese Chemical Letters, 2024, 35(6): 109183-. doi: 10.1016/j.cclet.2023.109183
11. [11]
  Zhibin Ren , Shan Li , Xiaoying Liu , Guanghao Lv , Lei Chen , Jingli Wang , Xingyi Li , Jiaqing Wang . Penetrating efficiency of supramolecular hydrogel eye drops: Electrostatic interaction surpasses ligand-receptor interaction. Chinese Chemical Letters, 2024, 35(11): 109629-. doi: 10.1016/j.cclet.2024.109629
12. [12]
  Lei Zhou , Youjun Zhou , Lizhen Fang , Yiqiao Bai , Yujia Meng , Liang Li , Jie Yang , Yong Yao . Pillar[5]arene based artificial light-harvesting supramolecular polymer for efficient and recyclable photocatalytic applications. Chinese Chemical Letters, 2024, 35(9): 109509-. doi: 10.1016/j.cclet.2024.109509
13. [13]
  Bingbing Shi , Yuchun Wang , Yi Zhou , Xing-Xing Zhao , Yizhou Li , Nuoqian Yan , Wen-Juan Qu , Qi Lin , Tai-Bao Wei . A supramolecular oligo[2]rotaxane constructed by orthogonal platinum(Ⅱ) metallacycle and pillar[5]arene-based host–guest interactions. Chinese Chemical Letters, 2024, 35(10): 109540-. doi: 10.1016/j.cclet.2024.109540
14. [14]
  Hao Zhang , Haonan Qu , Ehsan Bahojb Noruzi , Haibing Li , Feng Liang . A nanocomposite film with layer-by-layer self-assembled gold nanospheres driven by cucurbit[7]uril for the selective transport of L-tryptophan and lysozyme. Chinese Chemical Letters, 2025, 36(1): 109731-. doi: 10.1016/j.cclet.2024.109731
15. [15]
  Hui Li , Yanxing Qi , Jia Chen , Juanjuan Wang , Min Yang , Hongdeng Qiu . Synthesis of amine-pillar[5]arene porous adsorbent for adsorption of CO₂ and selectivity over N₂ and CH₄. Chinese Chemical Letters, 2024, 35(11): 109659-. doi: 10.1016/j.cclet.2024.109659
16. [16]
  Xiaofei NIU , Ke WANG , Fengyan SONG , Shuyan YU . Self-assembly of [Pd₆(L)₄]⁸⁺-type macrocyclic complexes for fluorescent sensing of HSO₃^-. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1233-1242. doi: 10.11862/CJIC.20240057
17. [17]
  Ya-Nan Yang , Zi-Sheng Li , Sourav Mondal , Lei Qiao , Cui-Cui Wang , Wen-Juan Tian , Zhong-Ming Sun , John E. McGrady . Metal-metal bonds in Zintl clusters: Synthesis, structure and bonding in [Fe₂Sn₄Bi₈]^3– and [Cr₂Sb₁₂]^3–. Chinese Chemical Letters, 2024, 35(8): 109048-. doi: 10.1016/j.cclet.2023.109048
18. [18]
  Ziyi Zhu , Yang Cao , Jun Zhang . CO2-switched porous metal-organic framework magnets. Chinese Journal of Structural Chemistry, 2024, 43(2): 100241-100241. doi: 10.1016/j.cjsc.2024.100241
19. [19]
  Manoj Kumar Sarangi , L․D Patel , Goutam Rath , Sitansu Sekhar Nanda , Dong Kee Yi . Metal organic framework modulated nanozymes tailored with their biomedical approaches. Chinese Chemical Letters, 2024, 35(11): 109381-. doi: 10.1016/j.cclet.2023.109381
20. [20]
  Linshan Peng , Qihang Peng , Tianxiang Jin , Zhirong Liu , Yong Qian . Highly efficient capture of thorium ion by citric acid-modified chitosan gels from aqueous solution. Chinese Chemical Letters, 2024, 35(5): 108891-. doi: 10.1016/j.cclet.2023.108891

Get Citation

PDF

XML

Metrics

PDF Downloads(5)
Abstract views(619)
HTML views(50)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142