Citation: Jing Chen, Yumei Tang, Shihao Wang, Lingbin Xie, Cheng Chang, Xiaolei Cheng, Mingming Liu, Longlu Wang, Lianhui Wang. Ingeniously designed Ni-Mo-S/ZnIn₂S₄ composite for multi-photocatalytic reaction systems[J]. Chinese Chemical Letters, ;2022, 33(3): 1468-1474. doi: 10.1016/j.cclet.2021.08.103 shu

Ingeniously designed Ni-Mo-S/ZnIn₂S₄ composite for multi-photocatalytic reaction systems

a.
College of Electronic and Optical Engineering & College of Microelectronics, Jiangsu Province Engineering Research Center for Fabrication and Application of Special Optical Fiber Materials and Devices, Nanjing University of Posts and Telecommunications, Nanjing 210023, China
b.
State Key Laboratory of Organic Electronics and Information Displays & Jiangsu Key Laboratory for Biosensors, Institute of Advanced Materials (IAM) & Institute of Flexible Electronics (Future Technology), Nanjing University of Posts and Telecommunications, Nanjing 210023, China

wanglonglu@hnu.edu.cn

Received Date: 24 July 2021
Revised Date: 19 August 2021
Accepted Date: 23 August 2021
Available Online: 27 August 2021

Figures(7)

Molybdenum disulfide (MoS₂) with low cost, high activity and high earth abundance has been found to be a promising catalyst for the hydrogen evolution reaction (HER), but its catalytic activity is considerably limited due to its inert basal planes. Here, through the combination of theory and experiment, we propose that doping Ni in MoS₂ as catalyst can make it have excellent catalytic activity in different reaction systems. In the EY/TEOA system, the maximum hydrogen production rate of EY/Ni-Mo-S is 2.72 times higher than that of pure EY, which confirms the strong hydrogen evolution activity of Ni-Mo-S nanosheets as catalysts. In the lactic acid and Na₂S/Na₂SO₃ systems, when Ni-Mo-S is used as co-catalyst to compound with ZnIn₂S₄ (termed as Ni-Mo-S/ZnIn₂S₄), the maximum hydrogen evolution rates in the two systems are 5.28 and 2.33 times higher than those of pure ZnIn₂S₄, respectively. The difference in HER enhancement is because different systems lead to different sources of protons, thus affecting hydrogen evolution activity. Theoretically, we further demonstrate that the Ni-Mo-S nanosheets have a narrower band gap than MoS₂, which is conducive to the rapid transfer of charge carriers and thus result in multi-photocatalytic reaction systems with excellent activity. The proposed atomic doping strategy provides a simple and promising approach for the design of photocatalysts with high activity and stability in multi-reaction systems.
- Molybdenum disulfide (MoS₂),
- Ni-Mo-S nanosheets,
- Multi-reaction systems,
- Hydrogen evolution reaction (HER),
- Atomic doping strategy
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通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Ingeniously designed Ni-Mo-S/ZnIn2S4 composite for multi-photocatalytic reaction systems

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通讯作者: 陈斌, bchen63@163.com

Ingeniously designed Ni-Mo-S/ZnIn₂S₄ composite for multi-photocatalytic reaction systems