Citation: Xiaonan Zheng, Yang Liu, Yu Yan, Xiaoxiao Li, Yuan Yao. Modulation effect in adjacent dual metal single atom catalysts for electrochemical nitrogen reduction reaction[J]. Chinese Chemical Letters, ;2022, 33(3): 1455-1458. doi: 10.1016/j.cclet.2021.08.102 shu

Modulation effect in adjacent dual metal single atom catalysts for electrochemical nitrogen reduction reaction

MIIT Key Laboratory of Critical Materials Technology for New Energy Conversion and Storage & State Key Laboratory of Advanced Welding and Joining, School of Chemistry and Chemical Engineering, Harbin Institute of Technology, Harbin 150080, China

yang.liu@hit.edu.cn

yyuan@hit.edu.cn

Received Date: 2 August 2021
Revised Date: 20 August 2021
Accepted Date: 22 August 2021
Available Online: 26 August 2021

Figures(4)

Nitrogen reduction reaction (NRR) is a clean mode of energy conversion and the development of highly efficient NRR electrocatalysts under ambient conditions for industrial application is still a big challenge. Metal-nitrogen-carbon (M-N-C) has emerged as a class of single atom catalyst due to the unique geometric structure, high catalytic activity, and clear selectivity. Herein, we designed a series of dual metal single atom catalysts containing adjacent M-N-C dual active centers (MN₄/M'N₄-C) as NRR electrocatalysts to uncover the structure-activity relationship. By evaluating structural stability, catalytic activity, and selectivity using density functional theory (DFT) calculations, 5 catalysts, such as CrN₄/M'N₄-C (M' = Cr, Mn, Fe, Cu and Zn), were determined to exhibit the best NRR catalytic performance with the limiting potential ranging from −0.64 V to −0.62 V. The CrN₄ center acted as the main catalytic site and the adjacent M'N₄ center could enhance the NRR catalytic activity by modulation effect based on the analysis of the electronic properties including the charge density difference, partial density of states (PDOS), and Bader charge variation. This study offers useful insights on understanding the structure-activity relationship of dual metal single atom catalysts for electrochemical NRR.
- Nitrogen reduction reaction,
- Electrocatalysts,
- Density functional theory,
- Dual metal single atom catalysts,
- Modulation effect
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