Citation: Yuying Qin, Yuhao Xie, Han Zhao, Chunyan Zhu, Tong Li, Shuxian Zhang, Rutao Wang, Yuanchang Shi, Longwei Yin. Scalable synthesis of macroscopic porous carbon sheet anode for potassium-ion capacitor[J]. Chinese Chemical Letters, ;2022, 33(3): 1463-1467. doi: 10.1016/j.cclet.2021.08.101 shu

Scalable synthesis of macroscopic porous carbon sheet anode for potassium-ion capacitor

Yuying Qin ^a ,
Yuhao Xie ^a ,
Han Zhao ^a ,
Chunyan Zhu ^a ,
Tong Li ^a ,
Shuxian Zhang ^a ,
Rutao Wang ^{a, b, c, *,} ,
Yuanchang Shi ^{a, *,} ,
Longwei Yin ^{a, *,}

a.
Key Laboratory for Liquid-Solid Structural Evolution and Processing of Materials, Ministry of Education, School of Materials Science and Engineering, Shandong University, Ji'nan 250061, China
b.
Suzhou Institute of Shandong University, Suzhou 215123, China
c.
CAS Key Laboratory of Carbon Materials, Institute of Coal Chemistry, Chinese Academy of Sciences, Taiyuan 030001, China

rtwang@sdu.edu.cn

yuanchangshi@sdu.edu.cn

yinlw@sdu.edu.cn

Received Date: 23 June 2021
Revised Date: 15 August 2021
Accepted Date: 22 August 2021
Available Online: 26 August 2021

Figures(4)

Carbon materials hold the great promise for application in energy storage devices owing to their low cost, high thermal/chemical stability, and high electrical conductivity. However, it remains challenging to synthesize high-performance carbon electrodes in a simple, scalable and sustainable way. Here, we report a facile method for scalable synthesis of porous carbon anode by using cheap and easily accessible zeolitic imidazolate framework-8 as a template and polyvinylpyrrolidone as an additional carbon source. The obtained porous carbon shows the macroscopic sheet-like morphology, which has the highly disordered structure, expanded interlayer spacing, abundant pore structure, and nitrogen doping properties. This porous carbon anode is demonstrated to have the excellent K⁺ charge storage properties in specific capacity, rate capability, and cycling stability. A potassium-ion capacitor assembled by using this porous carbon as the anode, delivers a maximum energy density of 85.12 Wh/kg and power density of 11860 W/kg as well as long cycle life exceeding 3000 cycles. This represents a critical advance in the design of low cost and scalable carbon material for applications in energy storage devices.
- Carbon materials,
- Anode,
- Nitrogen doping,
- Porous carbon,
- Potassium-ion capacitor,
- K⁺ charge storage
1. [1]
  S. Dhir, S. Wheeler, I. Capone, et al., Chem6 (2020) 2442–2460. doi: 10.1016/j.chempr.2020.08.012
2. [2]
  X. Wu, D. P. Leonard, X. Ji, Chem. Mater. 29 (2017) 5031–5042. doi: 10.1021/acs.chemmater.7b01764
3. [3]
  M. Liu, L. Chang, Z. Le, et al., ChemSusChem13 (2020) 5837–5862. doi: 10.1002/cssc.202000578
4. [4]
  T. Li, H. Zhao, C. Li, et al., New Carbon Mater. 36 (2021) 253–277. doi: 10.1016/S1872-5805(21)60019-7
5. [5]
  R. Rajagopalan, Y. Tang, X. Ji, et al., Adv. Funct. Mater. 30 (2020) 1909486. doi: 10.1002/adfm.201909486
6. [6]
  W. Zhang, Y. Liu, Z. Guo, Sci. Adv. 5 (2019) eaav7412. doi: 10.1126/sciadv.aav7412
7. [7]
  M. Shao, C. Li, T. Li, et al., Adv. Funct. Mater. 30 (2020) 2006561. doi: 10.1002/adfm.202006561
8. [8]
  Y. Li, Y. Lu, P. Adelhelm, et al., Chem. Soc. Rev. 48 (2019) 4655-4687. doi: 10.1039/c9cs00162j
9. [9]
  Y. Xu, C. Zhang, M. Zhou, et al., Nat. Commun. 9 (2018) 1720. doi: 10.1038/s41467-018-04190-z
10. [10]
  S. Dong, Z. Li, Z. Xing, et al., ACS Appl. Mater. Interfaces10 (2018) 15542-15547. doi: 10.1021/acsami.7b15314
11. [11]
  Y. Luo, L. Liu, K. Lei, et al., Chem. Sci. 10 (2019) 2048-2052. doi: 10.1039/c8sc04489a
12. [12]
  F. Ming, Ha. Liang, W. Zhang, et al., Nano Energy62 (2019) 853-860. doi: 10.1016/j.nanoen.2019.06.013
13. [13]
  D. Wang, J. Zhang, Y. Dong, et al., New Carbon Mater. 36 (2021) 435-448. doi: 10.1016/S1872-5805(21)60039-2
14. [14]
  D. Qiu, J. Guan, M. Li, et al., Adv. Funct. Mater. 20 (2019) 1903496. doi: 10.1002/adfm.201903496
15. [15]
  W. Wang, J. Zhou, Z. Wang, et al., Adv. Energy Mater. 8 (2018) 1701648. doi: 10.1002/aenm.201701648
16. [16]
  J. Ding, H. Zhang, H. Zhou, et al., Adv. Mater. 31 (2019) 1900429. doi: 10.1002/adma.201900429
17. [17]
  J. Chen, B. Yang, H. Hou, et al., Adv. Energy Mater. 9 (2019) 1803894. doi: 10.1002/aenm.201803894
18. [18]
  Y. Sun, H. Wang, W. Wei, et al., ACS Nano15 (2021) 1652-1665. doi: 10.1021/acsnano.0c09290
19. [19]
  Y. Luan, R. Hu, Y. Fang, et al., Nano Micro Lett. 11 (2019) 30. doi: 10.1007/s40820-019-0260-6
20. [20]
  L. Zou, C. Hou, Q. Wang, et al., Angew. Chem. Int. Ed. 59 (2020) 19627-19632. doi: 10.1002/anie.202004737
21. [21]
  C. Wang, J. Kim, J. Tang, et al., Angew. Chem. Int. Ed. 58 (2019) 2066-2070.
22. [22]
  H. Wang, Z. Xu, Z. Li, et al., Nano Lett. 14 (2014) 1987-1994. doi: 10.1021/nl500011d
23. [23]
  R. Wang, D. Jin, Y. Zhang, et al., J. Mater. Chem. A5 (2017) 292-302. doi: 10.1039/C6TA09143A
24. [24]
  Y. Xia, Z. Xiao, X. Dou, et al., ACS Nano7 (2013) 7083-7092. doi: 10.1021/nn4023894
25. [25]
  L. G. Cançado, K. Takai, T. Enoki, et al., Appl. Phys. Lett. 88 (2006) 163106. doi: 10.1063/1.2196057
26. [26]
  X. Zhou, L. Chen, W. Zhang, et al., Nano Lett. 19 (2019) 4965-4973. doi: 10.1021/acs.nanolett.9b01127
27. [27]
  J. Lu, C. Wang, H. Yu, et al., Adv. Funct. Mater. 29 (2019) 1906126. doi: 10.1002/adfm.201906126
28. [28]
  G. Zhang, X. Ou, C. Cui, et al., Adv. Funct. Mater. 29 (2019) 1806722. doi: 10.1002/adfm.201806722
29. [29]
  J. Yang, Z. Ju, Y. Jiang, et al., Adv. Mater. 30 (2018) 1700104. doi: 10.1002/adma.201700104
30. [30]
  D. Qiu, J. Guan, M. Li, et al., Adv. Funct. Mater. 29 (2019) 1903496. doi: 10.1002/adfm.201903496
31. [31]
  J. Ruan, F. Mo, Z. Chen, et al., Adv. Energy Mater. 10 (2020) 1904045. doi: 10.1002/aenm.201904045
32. [32]
  A. Le. Comte, Y. Reynier, C. Vincens, et al., J. Power Sources363 (2017) 34-43. doi: 10.1016/j.jpowsour.2017.07.005
33. [33]
  X. Xie, S. Q., D. Wu, et al., Chin. Chem. Lett., 31 (2020) 223-226. doi: 10.1016/j.cclet.2019.10.008
34. [34]
  X. Yu, M. Shao, X. Yang, et al., Chin. Chem. Lett., 31 (2020) 2215-2218. doi: 10.1016/j.cclet.2019.11.012
35. [35]
  L. Zhou, M. Zhang, Y. Wang, et al., Electrochim. Acta, 232 (2017) 106-113. doi: 10.1016/j.electacta.2017.02.096
36. [36]
  H. V. Ramasama, B. Senthilkumar, P. R. Barpand, et al., Chem. Eng. J. 368 (2019) 235-243. doi: 10.1016/j.cej.2019.02.172
37. [37]
  X. Liu, G. Antonio Elia, B. Qin, et al., ACS Energy Lett. 4 (2019) 2675-2682. doi: 10.1021/acsenergylett.9b01675
38. [38]
  Z. Zhang, M. Li, Y. Gao, et al., Adv. Funct. Mater. 28 (2018) 1802684. doi: 10.1002/adfm.201802684
39. [39]
  L. Fan, K. Lin, J. Wang, et al., Adv. Mater. 30 (2018) 1800804. doi: 10.1002/adma.201800804
40. [40]
  R. Pothu, R. Bolagam, Q. H. Wang, et al., Rare Met. 40 (2021) 353-373. doi: 10.1007/s12598-020-01470-w
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