Citation: Yinghui Xia, Kunming Sun, Ya-Nan Zuo, Shuyun Zhu, Xian-En Zhao. Fluorescent MOF-based nanozymes for discrimination of phenylenediamine isomers and ratiometric sensing of o-phenylenediamine[J]. Chinese Chemical Letters, ;2022, 33(4): 2081-2085. doi: 10.1016/j.cclet.2021.08.083 shu

Fluorescent MOF-based nanozymes for discrimination of phenylenediamine isomers and ratiometric sensing of o-phenylenediamine

School of Chemistry and Chemical Engineering, Qufu Normal University, Qufu 273165, China

shuyunzhu1981@163.com

xianenzhao@163.com

Received Date: 22 June 2021
Revised Date: 19 July 2021
Accepted Date: 17 August 2021
Available Online: 22 August 2021

Figures(4)

Although peroxidase-like nanozymes have made great progress in bioanalysis, few current nanozyme-based biosensors are constructed for discriminating isomers of organic compounds. Herein, fluorescent metal-organic framework (MOF)-based nanozyme is utilized for phenylenediamine isomers discrimination and detection. NH₂-MIL-101(Fe), as a member of Fe-based MOFs, functions as not only fluorescent indicator but also peroxidase mimics. In the presence of H₂O₂, NH₂-MIL-101(Fe) can catalyze the oxidation of o-phenylenediamine (OPD) and p-phenylenediamine (PPD) into their corresponding oxidation products (OPDox and PPDox), which in turn quench its intrinsic fluorescence at 445 nm via inner filter effect (IFE). Differently, a new fluorescence peak at 574 nm is observed for OPDox. Thus, a ratiometric fluorescence method for the detection of OPD can be designed with the fluorescence intensity ratio F₅₇₄/F₄₄₅ as readout. This proposed strategy displays excellent discrimination ability for three phenylenediamines and may open new applications of MOFs in environmental science.
- Bifunctional MOF,
- Nanozyme,
- Photoluminescence,
- Aromatic diamine isomers,
- Ratiometric fluorescence
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