Citation: Yi-Lu Yang, Yi-Rong Wang, Guang-Kuo Gao, Ming Liu, Chang Miao, Le-Yan Li, Wei Cheng, Zi-Yue Zhao, Yifa Chen, Zhifeng Xin, Shun-Li Li, Dong-Sheng Li, Ya-Qian Lan. Self-assembly of single metal sites embedded covalent organic frameworks into multi-dimensional nanostructures for efficient CO₂ electroreduction[J]. Chinese Chemical Letters, ;2022, 33(3): 1439-1444. doi: 10.1016/j.cclet.2021.08.063 shu

Self-assembly of single metal sites embedded covalent organic frameworks into multi-dimensional nanostructures for efficient CO₂ electroreduction

Yi-Lu Yang ^{a, 1} ,
Yi-Rong Wang ^{a, 1} ,
Guang-Kuo Gao ^{a, 1} ,
Ming Liu ^a ,
Chang Miao ^a ,
Le-Yan Li ^a ,
Wei Cheng ^a ,
Zi-Yue Zhao ^a ,
Yifa Chen ^{a, b, *,} ,
Zhifeng Xin ^{c, *,} ,
Shun-Li Li ^a ,
Dong-Sheng Li ^d ,
Ya-Qian Lan ^{a, b, *,}

a.
Jiangsu Collaborative Innovation Centre of Biomedical Functional Materials, Jiangsu Key Laboratory of New Power Batteries, School of Chemistry and Materials Science, Nanjing Normal University, Nanjing 210023, China
b.
School of Chemistry, South China Normal University, Guangzhou 510006, China
c.
Institute of Molecular Engineering and Applied Chemistry, Anhui University of Technology, Ma'anshan 243002, China
d.
College of Materials and Chemical Engineering, Hubei Provincial Collaborative Innovation Center for New Energy Microgrid, Key Laboratory of Inorganic Nonmetallic Crystalline and Energy Conversion Materials, China Three Gorges University, Yichang 443002, China

chyf927821@163.com

xinzf521@ahut.edu.cn

yqlan@njnu.edu.cn

Received Date: 27 May 2021
Revised Date: 19 July 2021
Accepted Date: 12 August 2021
Available Online: 18 August 2021

Figures(4)

Morphology-controlled electrocatalysts with the ability of CO₂ adsorption/activation, mass transfer, high stability and porosity are much desired in electrochemical CO₂ reduction reaction (CO₂RR). Here, three kinds of multi-dimensional nanostructures (i.e., hollow sphere, nanosheets and nanofibers) have been successfully produced through the modulation of porphyrin-based covalent organic frameworks (COFs) with various modulators. The obtained nanostructures with high-stability, large surface-area, and single metal sites enable efficient CO₂RR into CH₄. Notably, they all exhibit higher FE (hollow sphere, 68.2%; nanosheet, 64.2% and nanofiber, 71.0%, −0.9 V) than COF-366-Cu (43.0%, −0.9 V) after morphology control. Noteworthy, the FE of COF-366-Cu (HS) keeps higher than 52.4% over a wide potential range from −0.9 V to −1.1 V and the achieved FE_{CH₄+C₂H₄} (82.8%, −0.9 V) is superior to most of reported COFs and copper-based electrocatalysts. This work paves a new way in the exploration of COF-based multi-dimensional nanostructures applicable in efficient CO₂RR to CH₄.
- CO₂ electroreduction,
- Covalent organic frameworks,
- Hollow sphere,
- Nanofiber,
- Nanosheet
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沈阳化工大学材料科学与工程学院沈阳 110142

Self-assembly of single metal sites embedded covalent organic frameworks into multi-dimensional nanostructures for efficient CO2 electroreduction

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通讯作者: 陈斌, bchen63@163.com

Self-assembly of single metal sites embedded covalent organic frameworks into multi-dimensional nanostructures for efficient CO₂ electroreduction