Citation: Yue Niu, Denghui Wang, Yingjie Ma, Linjie Zhi. Cascading V₂O₃/N-doped carbon hybrid nanosheets as high-performance cathode materials for aqueous zinc-ion batteries[J]. Chinese Chemical Letters, ;2022, 33(3): 1430-1434. doi: 10.1016/j.cclet.2021.08.058 shu

Cascading V₂O₃/N-doped carbon hybrid nanosheets as high-performance cathode materials for aqueous zinc-ion batteries

Yue Niu ^{a, b, 1} ,
Denghui Wang ^{a, b, 1} ,
Yingjie Ma ^{a, *,} ,
Linjie Zhi ^{a, *,}

a.
CAS Key Laboratory of Nanosystem and Hierarchical Fabrication, CAS Center for Excellence in Nanoscience, National Center for Nanoscience and Technology, Beijing 100190, China
b.
University of Chinese Academy of Sciences, Beijing 100039, China

mayj@nanoctr.cn

zhilj@nanoctr.cn

Received Date: 28 June 2021
Revised Date: 16 July 2021
Accepted Date: 10 August 2021
Available Online: 16 August 2021

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In recent years, especially when there is increasing concern about the safety issue of lithium-ion batteries (LIBs), aqueous Zn-ion batteries (ZIBs) have been getting a lot of attention because of their cost-effectiveness, materials abundance, high safety, and ecological friendliness. Their working voltage and specific capacity are mainly determined by their cathode materials. Vanadium oxides are promising cathode materials for aqueous ZIBs owing to their low cost, abundant resources, and multivalence. However, vanadium oxide cathodes still suffer from unsatisfactory capacity, poor stability, and low electrical conductivity. In this work, cascading V₂O₃/nitrogen doped carbon (V₂O₃/NC) hybrid nanosheets are prepared for high-performance aqueous ZIBs by pyrolyzing pentyl viologen dibromide (PV) intercalated V₂O₅ nanosheets. The unique structure features of V₂O₃/NC nanosheets, including thin sheet-like morphology, small crystalline V₂O₃ nanoparticles, and conductive NC layers, endow V₂O₃/NC with superior performance compared to most of the reported vanadium oxide cathode materials for aqueous ZIBs. The V₂O₃/NC cathode exhibits the discharge capacity of 405 mAh/g at 0.5 A/g, excellent rate capability (159 mAh/g at 20 A/g), and outstanding cycling stability with 90% capacity retention over 4000 cycles at 20 A/g.
- Aqueous zinc ion batteries,
- Cathode materials,
- Vanadium oxides,
- Nitrogen doped carbon,
- 2D nanosheets,
- High performance
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Cascading V₂O₃/N-doped carbon hybrid nanosheets as high-performance cathode materials for aqueous zinc-ion batteries