Citation: Xiaoyue Zhang, Yong Yang, Lijun Xiong, Tianyu Wang, Zheng Tang, Panjie Li, Nan Yin, Aiwu Sun, Jinyou Shen. 3D dahlia-like NiAl-LDH/CdS heterosystem coordinating with 2D/2D interface for efficient and selective conversion of CO₂[J]. Chinese Chemical Letters, ;2022, 33(4): 2111-2116. doi: 10.1016/j.cclet.2021.08.053 shu

3D dahlia-like NiAl-LDH/CdS heterosystem coordinating with 2D/2D interface for efficient and selective conversion of CO₂

Xiaoyue Zhang ^a ,
Yong Yang ^{b, *,} ,
Lijun Xiong ^b ,
Tianyu Wang ^a ,
Zheng Tang ^b ,
Panjie Li ^a ,
Nan Yin ^b ,
Aiwu Sun ^{b, c} ,
Jinyou Shen ^{a, *,}

a.
Jiangsu Key Laboratory of Chemical Pollution Control and Resources Reuse, School of Environmental and Biological Engineering, Nanjing University of Science and Technology, Nanjing 210094, China
b.
Key Laboratory of Soft Chemistry and Functional Materials, Ministry of Education, School of Chemistry and Chemical Engineering, Nanjing University of Science and Technology, Nanjing 210094, China
c.
Faculty of Chemical Engineering, Huaiyin Institute of Technology, Huaiyin 223001, China

yychem@njust.edu.cn

shenjinyou@njust.edu.cn

Received Date: 3 April 2021
Revised Date: 26 July 2021
Accepted Date: 10 August 2021
Available Online: 16 August 2021

Figures(4)

Developing photocatalyst with high activity, superior stability and prominent selectivity for CO₂ conversion is of great importance for the target of carbon neutralization. Herein, 3D dahlia-like NiAl-LDH/CdS heterosystem is developed through in-situ decoration of exfoliated CdS nanosheets on the scaffold of NiAl-LDH and the on-spot self-assembly. The formation of a hierarchical architecture collaborating with well-defined 2D/2D interfacial interaction is constructed by optimizing the ratio of CdS integrated in the formation of the heterojunction. The light-harvesting capacity of NiAl-LDH/CdS is improved by this unique scaffold, and the charge transfer between NiAl-LDH and CdS is effectively facilitated by virtue of the unique 2D/2D interface. As a result, the 3D hierarchical NiAl-LDH/CdS heterosystem presents 12.45µmol g⁻¹ h⁻¹ of CO production (3.3 and 1.6 folds of pristine NiAl-LDH and CdS) with 96% selectivity and superior stability. This 3D hierarchical design collaborating with 2D/2D interfacial interaction provides a new avenue to develop ideal catalysts for artificial photosynthesis.
- Photocatalysis,
- CdS,
- Photocorrosion,
- NiAl-LDH,
- CO₂Conversion
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

3D dahlia-like NiAl-LDH/CdS heterosystem coordinating with 2D/2D interface for efficient and selective conversion of CO2

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通讯作者: 陈斌, bchen63@163.com

3D dahlia-like NiAl-LDH/CdS heterosystem coordinating with 2D/2D interface for efficient and selective conversion of CO₂