Citation: Xiaofei Wang, Xuezhen Lin, Huijuan Qiu, Jianda Xie, Zhengyu Lu, Yusong Wang, Weitai Wu. Light-mediated CO₂-responsiveness of metallopolymer microgels[J]. Chinese Chemical Letters, ;2022, 33(3): 1445-1449. doi: 10.1016/j.cclet.2021.08.051 shu

Light-mediated CO₂-responsiveness of metallopolymer microgels

Xiaofei Wang ^{a, 1} ,
Xuezhen Lin ^{a, 1} ,
Huijuan Qiu ^a ,
Jianda Xie ^b ,
Zhengyu Lu ^a ,
Yusong Wang ^c ,
Weitai Wu ^{a, d, *,}

a.
State Key Laboratory for Physical Chemistry of Solid Surfaces, Collaborative Innovation Center of Chemistry for Energy Materials, The Key Laboratory for Chemical Biology of Fujian Province, and Department of Chemistry, College of Chemistry and Chemical Engineering, Xiamen University, Xiamen 361005, China
b.
School of Materials Science and Engineering, Xiamen University of Technology, Xiamen 361024, China
c.
Hefei National Laboratory for Physical Sciences at the Microscale, University of Science and Technology of China, Hefei 230026, China
d.
School of Chemistry and Chemical Engineering, Ningxia University, Yinchuan 750021, China

wuwtxmu@xmu.edu.cn

Received Date: 17 June 2021
Revised Date: 4 August 2021
Accepted Date: 11 August 2021
Available Online: 17 August 2021

Figures(5)

Here, we report a finding on light-mediated CO₂-responsiveness. It is found on the microgels that are made of side-chain type metallopolymers containing metalla-aromatics. Turbidity and laser light scattering studies on dilute aqueous dispersion of these microgels in dark indicate high CO₂-responsivity, but poor reversibility upon N₂ purge, which can be improved by exposing to light. This light-mediated CO₂-responsiveness can be elucidated by the loss of aromaticity from initial photoexcitation and concurrent formation of a less reactive, antiaromatic excited state of relatively low CO₂ binding affinity, and by subsequent relief of antiaromaticity that can enhance the CO₂ removal. The finding is also checked by CO₂ uptake-release experiments on the microgels, which enables both CO₂ capture of high capacity and CO₂ removal of good reversibility under a mild condition, allowing effective and reversible response to dilute CO_2.
- Stimuli-responsive,
- Metallopolymers,
- Light,
- Dilute CO₂,
- Reversible uptake-release
1. [1]
  Q. Yan, R. Zhou, C.K. Fu, et al., Angew. Chem. Int. Ed. 50 (2011) 4923-4927. doi: 10.1002/anie.201100708
2. [2]
  D.H. Han, X. Tong, O. Boissière, Y. Zhao, ACS Macro Lett. 1 (2012) 57-61. doi: 10.1021/mz2000175
3. [3]
  H. Yu, K. Imamura, M. Yue, G. Inoue, Y.Y. Miura, J. Am. Chem. Soc. 134 (2012) 18177-18180. doi: 10.1021/ja3080192
4. [4]
  K.C. Jie, Y. Yao, X.D. Chi, F.H. Huang, Chem. Commun. 50 (2014) 5503-5505. doi: 10.1039/c4cc01704h
5. [5]
  K.C. Jie, Y.J. Zhou, Y. Yao, B.B. Shi, F.H. Huang, J. Am. Chem. Soc. 137 (2015) 10472-10475. doi: 10.1021/jacs.5b05960
6. [6]
  K. Jie, Y. Zhou, Y. Yao, B. Shi, F. Huang, J. Am. Chem. Soc. 137 (2015) 10472-10475. doi: 10.1021/jacs.5b05960
7. [7]
  A. Darabi, P.G. Jessop, M.F. Cunningham, Chem. Soc. Rev. 45 (2016) 4391-4436. doi: 10.1039/C5CS00873E
8. [8]
  Q. Zhang, L. Lei, S.P. Zhu, ACS Macro Lett. 6 (2017) 515-522. doi: 10.1021/acsmacrolett.7b00245
9. [9]
  H.B. Liu, S.J. Lin, Y.J. Feng, P. Theato, Polym. Chem. 8 (2017) 12-23. doi: 10.1039/C6PY01101B
10. [10]
  B.X. Jiang, Y.C. Zhang, X.D. Huang, et al., Ind. Eng. Chem. Res. 58 (2019) 15088-15108. doi: 10.1021/acs.iecr.9b02433
11. [11]
  M.F. Cunningham, P.G. Jessop, Macromolecules52 (2019) 6801-6816. doi: 10.1021/acs.macromol.9b00914
12. [12]
  S.Y. Wang, Q.H. Liu, L. Li, M.W. Urban, Macromol. Rapid Commun. (2021) 2100054. doi: 10.1002/marc.202100054
13. [13]
  B.S. Zheng, J.F. Bai, J.G. Duan, L. Wojtas, M.J. Zaworotkoet, J. Am. Chem. Soc. 133 (2011) 748-751. doi: 10.1021/ja110042b
14. [14]
  F. Ding, X. He, X.Y. Luo, et al., Chem. Commun. 50 (2014) 15041-15044. doi: 10.1039/C4CC06944G
15. [15]
  X.Y. Luo, X.Y. Chen, R.X. Qiu, et al., Dalton Trans. 48 (2019) 2300-2307. doi: 10.1039/c8dt04680h
16. [16]
  P. Das, S.K. Mandal, Chem. Mater. 31 (2019) 1584-1596. doi: 10.1021/acs.chemmater.8b04683
17. [17]
  L. Chen, R.J. Liu, Q. Yan, Angew. Chem. Int. Ed. 57 (2018) 9336-9340. doi: 10.1002/anie.201804034
18. [18]
  L. Chen, R.J. Liu, X. Hao, Q. Yan, Angew. Chem. Int. Ed. 58 (2019) 264-268. doi: 10.1002/anie.201812365
19. [19]
  D.W. Stephan, G. Erker, Angew. Chem. Int. Ed. 54 (2015) 6400-6441. doi: 10.1002/anie.201409800
20. [20]
  M. Aresta, A. Angelini. The carbon dioxide molecule and the effects of its interaction with electrophiles and nucleophiles, in: X.B. Lu (Ed. ), Carbon Dioxide and Organometallics, Vol. 53, Springer Nature Switzerland AG, 2016, pp. 1-38.
21. [21]
  Y.L. Wang, D. Astruc, A.S. Abd-El-Aziz, Chem. Soc. Rev. 48 (2019) 558-636. doi: 10.1039/C7CS00656J
22. [22]
  E.J. Kim, R.L. Siegelman, H.Z. Jiang, A. C. Forse, J. R. Long, Science369 (2020) 392-396. doi: 10.1126/science.abb3976
23. [23]
  C.Q. Zhu, S.H. Li, M. Luo, et al., Nat. Chem. 5 (2013) 698-703. doi: 10.1038/nchem.1690
24. [24]
  D.F. Chen, Y.H. Hua, H.P. Xia, Chem. Rev. 120 (2020) 12994-13086. doi: 10.1021/acs.chemrev.0c00392
25. [25]
  I. Fernández, F.M. Bickelhaupt, Chem. Soc. Rev. 43 (2014) 4953-4967. doi: 10.1039/C4CS00055B
26. [26]
  J.J. Cabrera-Trujillo, I. Fernández, Chem. Commun. 55 (2019) 675-678. doi: 10.1039/c8cc09777a
27. [27]
  D.L. Zhuang, A.M. Rouf, Y.Y. Li, C. Dai, J. Zhu, Chem. Asian J. 15 (2020) 266-272. doi: 10.1002/asia.201901415
28. [28]
  M. Rosenberg, C. Dahlstrand, K. Kilså, H. Ottosson, Chem. Rev. 114 (2014) 5379-5425. doi: 10.1021/cr300471v
29. [29]
  Y.M. Sung, M.C. Yoon, J.M. Lim, et al., Nat. Chem. 7 (2015) 418-422. doi: 10.1038/nchem.2233
30. [30]
  B. Oruganti, P.P. Kalapos, V. Bhargav, G. London, D. Bo, J. Am. Chem. Soc. 142 (2020) 13941-13953. doi: 10.1021/jacs.0c06327
31. [31]
  M.C. Yue, Y. Hoshino, Y. Miura, Chem. Sci. 6 (2015) 6112-6123. doi: 10.1039/C5SC01978H
32. [32]
  P.D.L. Werz, J. Kainz, B. Rieger, Macromolecules48 (2015) 6433-6439. doi: 10.1021/acs.macromol.5b01367
33. [33]
  X.F. Wang, H.J. Qiu, Q.S. Wu, et al., ACS Macro Lett. 9 (2020) 1611-1616. doi: 10.1021/acsmacrolett.0c00617
34. [34]
  F. Lu, X.Z. Lin, Q.S. Wu, et al., ACS Macro Lett. 9 (2020) 266-271. doi: 10.1021/acsmacrolett.9b01031
35. [35]
  Z.Y. Lu, J.X. Chen, H.P. Xia, Chin. J. Org. Chem. 37 (2017) 1181-1188. doi: 10.6023/cjoc201703003
36. [36]
  M. Yan, Y. Kawamata, P.S. Baran, Chem. Rev. 117 (2017) 13230-13319. doi: 10.1021/acs.chemrev.7b00397
37. [37]
  S.T. Farrell, C.B. Breslin, Electrochim. Acta49 (2004) 4497-4503. doi: 10.1016/j.electacta.2004.05.007
38. [38]
  Q.J. Chen, R. Ranaweera, L. Luo, J. Phys. Chem. C122 (2018) 15421-15426. doi: 10.1021/acs.jpcc.8b03770
39. [39]
  C.D. Jones, L.A. Lyon, Langmuir19 (2003) 4544-4547. doi: 10.1021/la034392+
40. [40]
  R. Pelton, Adv. Colloid Interface Sci. 85 (2000) 1-33. doi: 10.1016/S0001-8686(99)00023-8
41. [41]
  C. Wu, J. Polym. Sci. Part B: Polym. Phys. 32 (1994) 1503-1509. doi: 10.1002/polb.1994.090320822
42. [42]
  S. Romer, F. Scheffold, P. Schurtenberger, Phys. Rev. Lett. 85 (2000) 4980-4983. doi: 10.1103/PhysRevLett.85.4980
43. [43]
  B. Chu, In Laser Light Scattering, 2nd ed., Academic Press: New York, 1991.
44. [44]
  Q. J. Chen, H. Zhao, T. Ming, J. F. Wang, C. Wu, J. Am. Chem. Soc. 131 (2009) 16650-16651. doi: 10.1021/ja907898u
45. [45]
  H. Lischka, D. Nachtigallová, A. J. A. Aquino, et al., Chem. Rev. 118 (2018) 7293-7361. doi: 10.1021/acs.chemrev.8b00244
46. [46]
  H.S. Jung, P. Verwilst, A. Sharma, et al., Chem. Soc. Rev. 47 (2018) 2280-2297. doi: 10.1039/C7CS00522A
47. [47]
  G. McKay, Processes Impacts22 (2020) 1139-1165. doi: 10.1039/d0em00056f
48. [48]
  K.N. Solovyov, E.A. Borisevich, Phys. Usp. 48 (2005) 231-253. doi: 10.1070/PU2005v048n03ABEH001761
49. [49]
  D.D. Chen, D.W. Szczepanik, J. Zhu, M. Solà, Chem. Eur. J. 26 (2020) 12964-12971. doi: 10.1002/chem.202001830
50. [50]
  O.L.I. Brown, J. Chem. Educ. 28 (1951) 428. doi: 10.1021/ed028p428
51. [51]
  C.A. Trickett, A. Helal, B.A. Al-Maythalony, et al., Nat. Rev. Mater. 2 (2017) 1-16.
52. [52]
  P.M. Bhatt, Y. Belmabkhout, A. Cadiau, et al., J. Am. Chem. Soc. 138 (2016) 9301-9307. doi: 10.1021/jacs.6b05345
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Light-mediated CO2-responsiveness of metallopolymer microgels

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Light-mediated CO₂-responsiveness of metallopolymer microgels