Citation: Yitao Song, Yewang Peng, Shuang Yao, Peng Zhang, Yujie Wang, Jianmin Gu, Tongbu Lu, Zhiming Zhang. Co-POM@MOF-derivatives with trace cobalt content for highly efficient oxygen reduction[J]. Chinese Chemical Letters, ;2022, 33(2): 1047-1050. doi: 10.1016/j.cclet.2021.08.045 shu

Co-POM@MOF-derivatives with trace cobalt content for highly efficient oxygen reduction

Yitao Song ^a ,
Yewang Peng ^a ,
Shuang Yao ^{a, *,} ,
Peng Zhang ^a ,
Yujie Wang ^a ,
Jianmin Gu ^{b, *,} ,
Tongbu Lu ^a ,
Zhiming Zhang ^{a, *,}

a.
Institute for New Energy Materials and Low Carbon Technologies, School of Materials Science & Engineering, School of Chemistry and Chemical Engineering, Tianjin University of Technology, Tianjin 300384, China
b.
State Key Laboratory of Metastable Materials Science and Technology (MMST), Yanshan University, Qinhuangdao 066004, China

shuangyao@email.tjut.edu.cn

jmgu@ysu.edu.cn

zmzhang@email.tjut.edu.cn

Received Date: 28 June 2021
Revised Date: 19 July 2021
Accepted Date: 8 August 2021
Available Online: 12 August 2021

Figures(4)

A simple and effective method for constructing highly efficient oxygen reduction catalysts with trace amount of isolated cobalt was firstly developed by the pyrolysis of Co-centered polyoxometalate@metal-organic framework (Co-POM@MOF). The Co-centered polyoxometalate ([CoW₁₂O₄₀]⁶⁻) was confined in the well-defined void space of ZIF-8 to achieve homogeneous dispersion of polyoxoanions, where the isolated Co centers were well surrounded by the W-O shell and ZIF-8 framework. The Co-POM@MOF-derived N-doping porous carbon (Co-W-NC) with trace cobalt content was facilely prepared by the pyrolysis of the Co-POM@MOF under Ar atmosphere. The single dispersion of polyoxoanions in the metal-organic framework with complete separation of Co center surrounding by W-O shell and ZIF-8 framework ensures the uniform dispersion of Co atoms, confirmed by the Fourier transform extended X-ray absorption fine structure measurement. The Co-W-NC composite catalysts exhibit high performance for oxygen reduction reactions with a half-wave potential of 0.835 V in 0.1 mol/L KOH solution with excellent durability, which is much superior to that of the control samples derived from the [PW₁₂O₄₀]@ZIF-8, and the commercial Pt/C. This work highlights a new insight for constructing highly efficient catalysts via the introduction of metal-centered polyoxometalate into metal-organic framework following the high temperature treatment process.
- Metal-organic framework,
- Polyoxometalate,
- Polyoxoanion,
- Oxygen reduction,
- Electrocatalysis
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