Citation: Jin Wang, Moupan Cen, Jian Wang, Di Wang, Yue Ding, Guohua Zhu, Bing Lu, Xiaolei Yuan, Yang Wang, Yong Yao. Water-soluble pillar[4]arene[1]quinone: Synthesis, host-guest property and application in the fluorescence turn-on sensing of ethylenediamine in aqueous solution, organic solvent and air[J]. Chinese Chemical Letters, ;2022, 33(3): 1475-1478. doi: 10.1016/j.cclet.2021.08.044 shu

Water-soluble pillar[4]arene[1]quinone: Synthesis, host-guest property and application in the fluorescence turn-on sensing of ethylenediamine in aqueous solution, organic solvent and air

School of Chemistry and Chemical Engineering, Nantong University, Nantong 226019, China

yueding@ntu.edu.cn

zhu.gh@ntu.edu.cn

yaoyong1986@ntu.edu.cn

Received Date: 15 June 2021
Revised Date: 5 August 2021
Accepted Date: 8 August 2021
Available Online: 12 August 2021

Figures(7)

Water-soluble pillar[5]arenes are a class of typical macrocycles and have aroused tremendous attention for its easy to modify, abundant host-guest properties and extensive applications. However, up to now, all the reported water-soluble pillar[5]arenes acted as the host molecules, whereas they failed to be postsynthetically modified, which seriously impeded the development of the pillar[5]arene-based supramolecular chemistry. In this work, a new water-soluble pillar[5]arene, pillar[4]arene[1]quinone, was designed and synthsized with eight quaternary ammonium groups as well as a quinone units. Such a new water-soluble pillar[4]arene[1]quinone was capable of forming 1:1 stable complex with sodium 1-octanesulfonate in aqueous solution. Since the 1, 4-quinone unit of WP[4]Q[1] could react with ethylenediamine (EDA) to form a conjugated quinoxaline structure, so pillar[4]arene[1]quinone could apply to the facile fluorescence turn-on sensing of EDA in aqueous solution, organic solvent and air.
- Pillar[5]arene,
- Host-guest chemistry,
- Fluorescence sensing,
- Pillar[4]arene[1]quinone,
- Ethylenediamine
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