Citation: Bei-Dou Liang, Tong Jin, Le-Ping Miao, Chao-Yang Chai, Chang-Chun Fan, Xiang-Bin Han, Wen Zhang. Deuteration triggered downward shift of dielectric phase transition temperature in a hydrogen-bonded molecular crystal[J]. Chinese Chemical Letters, ;2022, 33(3): 1422-1424. doi: 10.1016/j.cclet.2021.08.032 shu

Deuteration triggered downward shift of dielectric phase transition temperature in a hydrogen-bonded molecular crystal

Jiangsu Key Laboratory for Science and Applications of Molecular Ferroelectrics and School of Chemistry and Chemical Engineering, Southeast University, Nanjing 211189, China

hanxiangbin@seu.edu.cn

zhangwen@seu.edu.cn

Received Date: 2 July 2021
Revised Date: 26 July 2021
Accepted Date: 8 August 2021
Available Online: 12 August 2021

Figures(5)

Deuteration of hydrogen-bonded phase transition crystals can increase the transition temperatures due to the isotope effect. But rare examples show the opposite trend that originates from the structural changes of the hydrogen bond, known as the geometric H/D isotope effect. Herein, we report an organic crystal, diethylammonium hydrogen 1,4-terephthalate, exhibits a reversible structural phase transition and dielectric switching. Structural study shows the cations reside in channels formed by one-dimensional hydrogen-bonded anionic chains and undergo an order-disorder transition at around 206 K. The deuterated counterpart shows an elongation of the O···O hydrogen bond by about 0.005 Å. This geometric isotope effect releases the internal pressure of the anionic host on the cation guests and results in a downward shift of the phase transition temperature by 10 K.
- Dielectric phase transition,
- Stimulus responsive material,
- Deuteration,
- Geometric isotope effect,
- Downward shift of transition temperature
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