Citation: Fenghua Chen, Zhaoqian Zhang, Weiwei Liang, Xiaoyun Qin, Zhen Zhang, Liying Jiang. Synthesis of Co₄S₃/Co₉S₈ nanosheets and comparison study toward the OER properties induced by different metal ion doping[J]. Chinese Chemical Letters, ;2022, 33(3): 1395-1402. doi: 10.1016/j.cclet.2021.08.019 shu

Synthesis of Co₄S₃/Co₉S₈ nanosheets and comparison study toward the OER properties induced by different metal ion doping

Fenghua Chen ^{a, *,} ,
Zhaoqian Zhang ^a ,
Weiwei Liang ^a ,
Xiaoyun Qin ^a ,
Zhen Zhang ^{b, *,} ,
Liying Jiang ^c

a.
College of Materials and Chemical Engineering, Zhengzhou University of Light Industry, Zhengzhou 450002, China
b.
Tianjin Key Laboratory of Molecular Optoelectronic Department of Chemistry, School of Science, Tianjin University, Tianjin 300072, China
c.
School of Electrical and Information Engineering, Zhengzhou University of Light Industry, Zhengzhou 450002, China

phenix@zzuli.edu.cn

zhzhen@tju.edu.cn

Received Date: 19 June 2021
Revised Date: 16 July 2021
Accepted Date: 5 August 2021
Available Online: 11 August 2021

Figures(11)

Regulation of chemical composition and nanostructure, such as the introduction of dopant into two-dimensional nanomaterials, is a general and valid strategy for the efficient electrocatalyst design. In this work, Co₄S₃/Co₉S₈ nanosheets, with an ultrathin layer structure, were successfully synthesized via an efficient solvothermal process combined with ultrasonic exfoliation. Different metal ions (M = Fe³⁺, Cr³⁺, Mn²⁺ and Ni²⁺) were then doped by a simple cation exchange method and the effects of different dopants on the OER activities of Co₄S₃/Co₉S₈ NS were further investigated in alkaline media. The corresponding results implied that M-doped Co₄S₃/Co₉S₈ NS (M = Fe³⁺, Cr³⁺, Mn²⁺ and Ni²⁺) exhibited different electrocatalytic properties. Evidenced by XPS spectra, the different OER activities were mainly aroused by the redistribution of charge at the interface due to an electronic interaction between the doped metal ions and Co₄S₃/Co₉S₈ NS.
- Chalcogenides,
- Chemical synthesis,
- Catalytic properties,
- Doping,
- Nanosheets,
- OER
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Synthesis of Co₄S₃/Co₉S₈ nanosheets and comparison study toward the OER properties induced by different metal ion doping