Citation: Zhuan Chen, Cheng Lian, Kai Huang, Jiahui Ji, Qingyun Yan, Jinlong Zhang, Mingyang Xing. "Small amount for multiple times" of H₂O₂ feeding way in MoS₂-Fe_x heterogeneous fenton for enhancing sulfadiazine degradation[J]. Chinese Chemical Letters, ;2022, 33(3): 1365-1372. doi: 10.1016/j.cclet.2021.08.016 shu

"Small amount for multiple times" of H₂O₂ feeding way in MoS₂-Fe_x heterogeneous fenton for enhancing sulfadiazine degradation

Zhuan Chen ^{a, b} ,
Cheng Lian ^a ,
Kai Huang ^a ,
Jiahui Ji ^{a, b} ,
Qingyun Yan ^{a, b} ,
Jinlong Zhang ^{a, b} ,
Mingyang Xing ^{a, b, *,}

a.
Key Laboratory for Advanced Materials and Joint International Research Laboratory of Precision Chemistry and Molecular Engineering, Feringa Nobel Prize Scientist Joint Research Center, Frontiers Science Center for Materiobiology and Dynamic Chemistry, Institute of Fine Chemicals, School of Chemistry and Molecular Engineering, East China University of Science and Technology, Shanghai 200237, China
b.
Shanghai Engineering Research Center for Multi-media Environmental Catalysis and Resource Utilization, East China University of Science and Technology, Shanghai 200237, China

mingyangxing@ecust.edu.cn

Received Date: 28 April 2021
Revised Date: 24 June 2021
Accepted Date: 5 August 2021
Available Online: 11 August 2021

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In recent years, MoS₂ catalyzed/cocatalyzed Fenton/Fenton-like systems have attracted wide attention in the field of pollution control, but there are few studies on the effect of H₂O₂ feeding way on the whole Fenton process. Here, we report a new type of composite catalyst (MoS₂-Fe_x) prepared in a simple way with highly dispersed iron to provide more active sites. MoS₂-Fe_x was proved to possess selectivity for singlet oxygen (¹O₂) in effectively degrading sulfadiazine with a wide pH adaptability (4.0~10.0). Importantly, the mechanism of the interaction between H₂O₂ and MoS₂ on the Fenton reaction activity was revealed through the combination of experiment and density functional theory (DFT) calculations. Compared to the traditional "a large amount for one time" feeding way of H₂O₂, the "small amount for multiple times" of H₂O₂ feeding way can increase the degradation rate of sulfadiazine from 36.9% to 91.1% in the MoS₂-Fe_x heterogeneous Fenton system. It is demonstrated that the "small amount for multiple times" of H₂O₂ feeding way can reduce the side reaction of decomposition of H₂O₂ by MoS₂ and effectively improve the utilization rate of H₂O₂ and the stability of MoS₂-Fe_x. Compared with Fe₂O₃-based Fenton system, MoS₂-Fe_x can significantly save the amount of H₂O₂. Compared with nano-iron powder, the formation of iron sludge in MoS₂-Fe_x system was significantly reduced. Furthermore, long-term degradation test showed that the MoS₂-Fe₇₅/H₂O₂ system could maintain the effectiveness of degrading organic pollutants for 10 days (or even longer). This study has a guiding significance for the large-scale treatment of industrial wastewater by improved Fenton technology in the future.
- Fenton reaction,
- Co-catalytic,
- Molybdenum sulfide,
- Hydrogen peroxide,
- Singlet oxygen
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"Small amount for multiple times" of H2O2 feeding way in MoS2-Fex heterogeneous fenton for enhancing sulfadiazine degradation

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"Small amount for multiple times" of H₂O₂ feeding way in MoS₂-Fe_x heterogeneous fenton for enhancing sulfadiazine degradation