Citation: Wei Xiang, Mingjie Huang, Xiaohui Wu, Fugang Zhang, Dan Li, Tao Zhou. Amplification effects of magnetic field on hydroxylamine-promoted ZVI/H₂O₂ near-neutral Fenton like system[J]. Chinese Chemical Letters, ;2022, 33(3): 1275-1278. doi: 10.1016/j.cclet.2021.07.072 shu

Amplification effects of magnetic field on hydroxylamine-promoted ZVI/H₂O₂ near-neutral Fenton like system

Wei Xiang ^{a, b} ,
Mingjie Huang ^a ,
Xiaohui Wu ^{a, b} ,
Fugang Zhang ^c ,
Dan Li ^c ,
Tao Zhou ^{a, *,}

a.
School of Environmental Science and Engineering, Huazhong University of Science and Technology, Wuhan 430074, China
b.
Key Laboratory of Water and Wastewater Treatment (HUST), MOHURD, Wuhan 430074, China
c.
Three Gorges Base Development Co., Ltd, Yichang 443002, China

zhoutao@hust.edu.cn

Received Date: 29 May 2021
Revised Date: 15 July 2021
Accepted Date: 31 July 2021
Available Online: 6 August 2021

Figures(6)

This study has demonstrated an interesting amplification effect of magnetic field (MF) on the hydroxylamine (HA)-promoted zero valent iron (ZVI)/H₂O₂ Fenton-like system. Sulfamethoxazole (SMX) could be efficiently degraded at near neutral pH. Conditional parameters affecting the SMX degradation in the ZVI/H₂O₂/HA/MF system, e.g., pH and the dosages of ZVI, HA and H₂O₂, were investigated. Unlike the acid-favorable ZVI/H₂O₂ and ZVI/H₂O₂/HA systems, the MF-assisted system exhibited good performances even at pH up to 6.0 and highest degradation rate at pH of 5.0. ^•OH was still identified as the responsible oxidant. A mechanism involving the MF-enhanced heterogeneous-homogeneous iron cycle was proposed in the near-neutral ZVI/H₂O₂/HA system. Without MF, HA-induced reductive dissolution of the surface iron oxides occurred and thus leaded to homogeneous Fenton reactions. After the introduction of MF, the gradient magnetic field formed on the ZVI particles would induce the generation of concentration cells of Fe(Ⅱ) and local corrosion of iron. Large amounts of aqueous and bounded Fe(Ⅱ) catalyzed H₂O₂ to efficiently produce ^•OH, while HA maintained the surface and bulk cycles of Fe(Ⅱ)/Fe(Ⅲ). The result of study is expected to provide a green, energy-free method in improving the effectiveness of ZVI-based Fenton-like technologies at weak-acidic circumstances.
- Fenton like,
- Zero valent iron,
- Hydroxylamine,
- Magnetic field
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Amplification effects of magnetic field on hydroxylamine-promoted ZVI/H2O2 near-neutral Fenton like system

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Amplification effects of magnetic field on hydroxylamine-promoted ZVI/H₂O₂ near-neutral Fenton like system