Citation: Xueting Bai, Yongle Guo, Zhongkui Zhao. Silicotungstic acid-derived WO₃ composited with ZrO₂ supported on SBA-15 as a highly efficient mesoporous solid acid catalyst for the alkenylation of p-xylene with phenylacetylene[J]. Chinese Chemical Letters, ;2022, 33(3): 1325-1330. doi: 10.1016/j.cclet.2021.07.071 shu

Silicotungstic acid-derived WO₃ composited with ZrO₂ supported on SBA-15 as a highly efficient mesoporous solid acid catalyst for the alkenylation of p-xylene with phenylacetylene

State Key Laboratory of Fine Chemicals, Department of Catalysis Chemistry and Engineering, School of Chemical Engineering, Dalian University of Technology, Dalian 116024, China

zkzhao@dlut.edu.cn

Received Date: 9 April 2021
Revised Date: 1 June 2021
Accepted Date: 27 July 2021
Available Online: 5 August 2021

Figures(3)

Highly dispersed silicotungstic acid-derived WO₃ composited with ZrO₂ supported on SBA-15 (WZ/SBA-15) as an ordered mesoporous solid acid catalyst was prepared via a facile incipient wetness impregnation (IWI) method that active ingredients, ZrO₂ and WO₃, were impregnated into the channels of SBA-15 simultaneously with a subsequent calcination process. The relationship between catalyst nature and performance was explored by high resolution transmission electron microscopy (HRTEM), high-angle annular dark-field scanning transmission electron microscopy (HAADF-STEM), FT-IR, X-ray photoelectron spectroscopy (XPS), X-ray diffraction (XRD), N₂ adsorption-desorption, NH₃ temperature-programmed desorption (NH₃-TPD), and FT-IR of pyridine adsorption (Py-IR) characterization techniques. The catalytic performance of W₁₂Z₁₅/SBA-15 is not only greater than that of single component solid acid catalysts, WO₃/SBA-15 and ZrO₂/SBA-15, but also W₁₂/Z₁₅/SBA-15 prepared by impregnating active ingredients, ZrO₂ and WO₃, into SBA-15 in sequence. The outstanding performance of W₁₂Z₁₅/SBA-15 is derived from the strong interaction between ZrO₂ and WO₃, which results in more acid sites, and relatively high specific surface area, large pore volume, and ordered mesoporous structure of SBA-15. The characterization and reaction results clearly demonstrate that the synergy of ZrO₂ and WO₃ has a clear boost for the alkenylation. The optimized W₁₂Z₁₅/SBA-15-500 achieves a 99.4% conversion of phenylacetylene and a 92.3% selectivity of main product α-arylstyrene for the alkenylation of p-xylene with phenylacetylene, with very low level of oligomers producing at the same time. Moreover, W₁₂Z₁₅/SBA-15-500 shows excellent catalytic stability and regeneration. Therefore, W₁₂Z₁₅/SBA-15-500 is a promising solid acid catalyst for the alkenylation.
- Alkenylation,
- SBA-15,
- Zirconium dioxide,
- Tungsten trioxide,
- Silicotungstic acid,
- Solid acid
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Silicotungstic acid-derived WO3 composited with ZrO2 supported on SBA-15 as a highly efficient mesoporous solid acid catalyst for the alkenylation of p-xylene with phenylacetylene

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通讯作者: 陈斌, bchen63@163.com

Silicotungstic acid-derived WO₃ composited with ZrO₂ supported on SBA-15 as a highly efficient mesoporous solid acid catalyst for the alkenylation of p-xylene with phenylacetylene