Citation: Juan Li, Zaizhu Lou, Baojun Li. Nanostructured materials with localized surface plasmon resonance for photocatalysis[J]. Chinese Chemical Letters, ;2022, 33(3): 1154-1168. doi: 10.1016/j.cclet.2021.07.059 shu

Nanostructured materials with localized surface plasmon resonance for photocatalysis

Juan Li ^a ,
Zaizhu Lou ^{a, b, *,} ,
Baojun Li ^a

a.
Institute of Nanophotonics, Jinan University, Guangzhou 511443, China
b.
State Key Laboratory for Crystal Materials, Shandong University, Ji'nan 250100, China

zzlou@jnu.edu.cn

Received Date: 21 April 2021
Revised Date: 6 June 2021
Accepted Date: 25 July 2021
Available Online: 31 July 2021

Figures(14)

Localized surface plasmon resonance (LSPR) enhanced photocatalysis has fascinated much interest and considerable efforts have been devoted toward the development of plasmonic photocatalysts. In the past decades, noble metal nanoparticles (Au and Ag) with LSPR feature have found wide applications in solar energy conversion. Numerous metal-based photocatalysts have been proposed including metal/semiconductor heterostructures and plasmonic bimetallic or multimetallic nanostructures. However, high cost and scarce reserve of noble metals largely limit their further practical use, which drives the focus gradually shift to low-cost and abundant nonmetallic nanostructures. Recently, various heavily doped semiconductors (such as WO_3-x, MoO_3-x, Cu_2-xS, TiN) have emerged as potential alternatives to costly noble metals for efficient photocatalysis due to their strong LSPR property in visible-near infrared region. This review starts with a brief introduction to LSPR property and LSPR-enhanced photocatalysis, the following highlights recent advances of plasmonic photocatalysts from noble metal to semiconductor-based plasmonic nanostructures. Their synthesis methods and promising applicability in plasmon-driven photocatalytic reactions such as water splitting, CO₂ reduction and pollution decomposition are also summarized in details. This review is expected to give guidelines for exploring more efficient plasmonic systems and provide a perspective on development of plasmonic photocatalysis.
- Localized surface plasmon resonance,
- Plasmonic photocatalysis,
- Plasmonic semiconductor,
- Hot electrons,
- Solar energy harvesting
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