Citation: Binbin Jin, Xin Ye, Heng Zhong, Fangming Jin, Yun Hang Hu. Enhanced photocatalytic CO₂ hydrogenation with wide-spectrum utilization over black TiO₂ supported catalyst[J]. Chinese Chemical Letters, ;2022, 33(2): 812-816. doi: 10.1016/j.cclet.2021.07.046 shu

Enhanced photocatalytic CO₂ hydrogenation with wide-spectrum utilization over black TiO₂ supported catalyst

Binbin Jin ^a ,
Xin Ye ^a ,
Heng Zhong ^{a, b, c} ,
Fangming Jin ^{a, b, c, *} ,
Yun Hang Hu ^{d, *}

a.
School of Environmental Science and Engineering, State Key Lab of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, China
b.
Center of Hydrogen Science, Shanghai Jiao Tong University, Shanghai 200240, China
c.
Shanghai Institute of Pollution Control and Ecological Security, Shanghai 200092, China
d.
Department of Materials Science and Engineering, Michigan Technological University, Houghton, Michigan 49931-1295, United States

fmjin@sjtu.edu.cn

yunhangh@mtu.edu

Received Date: 8 June 2021
Revised Date: 29 June 2021
Accepted Date: 20 July 2021
Available Online: 30 July 2021

Figures(4)

Light-driven conversion of CO₂ into chemicals/fuels is a desirable approach for achieving carbon neutrality using clean and sustainable energy. However, its scale-up application is restricted due to insufficient efficiency. Herein, we present a photothermal catalytic hydrogenation of CO₂ into CH₄ over Ru/black TiO₂ catalysts, aiming to achieve the synergistic use of light and heat in solar energy during CO₂ conversion. Owing to the desirable spectral response ability and photothermal conversion performance of black TiO₂, an efficient combination of photocatalysis and thermocatalysis has been established. The CO₂ hydrogenation was significantly accelerated because of the increased catalyst surface temperature enabled by the photothermal effect of black TiO₂. Simultaneously, through the in situ X-ray photoelectron spectroscopy (XPS) observation, electron-rich Ru nanoparticles was achieved based on the photo-induced excitation, thereby providing more negative hydride to improve nucleophilic attack to the CO₂, obtaining the CH₄ yield of 93.8%.
- Photothermal,
- Black TiO₂,
- CO₂,
- Electron-rich,
- Hydrogenation
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Enhanced photocatalytic CO2 hydrogenation with wide-spectrum utilization over black TiO2 supported catalyst

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通讯作者: 陈斌, bchen63@163.com

Enhanced photocatalytic CO₂ hydrogenation with wide-spectrum utilization over black TiO₂ supported catalyst