Citation: Jingping Zhong, Jian Zhou, Minsi Xiao, Jun Liu, Jili Shen, Juan Liu, Sili Ren. Design and syntheses of functionalized copper-based MOFs and its adsorption behavior for Pb(Ⅱ)[J]. Chinese Chemical Letters, ;2022, 33(2): 973-978. doi: 10.1016/j.cclet.2021.07.040 shu

Design and syntheses of functionalized copper-based MOFs and its adsorption behavior for Pb(Ⅱ)

Jiangxi Key Laboratory of Mining Engineering, School of Resources and Environmental Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China

sili_ren@163.com

Received Date: 23 February 2021
Revised Date: 7 June 2021
Accepted Date: 14 July 2021
Available Online: 24 August 2021

Figures(4)

A novel copper-based MOFs adsorbent (Cu-BTC-Th) was prepared using an one-step method by introducing a new organic ligand of 4-thioureidobenzoicacid (Th) with active groups for selectively adsorbing Pb(Ⅱ) from aqueous solutions. The chemical composition and structure of the prepared MOFs materials were characterized by scanning electron microscope (SEM), X-ray diffraction (XRD), fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), Brunner−Emmet−Teller (BET) analysis, and zeta potential measurements. The adsorption capability of the prepared Cu-MOFs was significantly enhanced by introducing the new organic ligand of Th in the materials. The maximum adsorption capacity of the Cu-BTC-Th for Pb(Ⅱ) attains 732.86 mg/g under the optimal conditions. In addition, the adsorption kinetics and adsorption isotherm analysis showed that the adsorption process followed the pseudo-second-order kinetic model and Langmuir adsorption model, indicating that the adsorption of Pb(Ⅱ) by Cu-BTC-Th was a monolayer chemisorption. The adsorption mechanism of Cu-BTC-Th for Pb(Ⅱ) was discussed and revealed. On one hand, the adsorption of Pb(Ⅱ) is mainly through ion exchange with the Cu(Ⅱ). On the other hand, the −NH₂ and −C=S functional groups introduced in the Cu-BTC-Th materials have stronger coordination ability with the Pb(Ⅱ) ions to enhance the adsorption capability.
- MOFs,
- Adsorption,
- Cu(Ⅱ) ions,
- Pb(Ⅱ) ions,
- Ion exchange,
- Coordination
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