Citation: Ruohan Zhang, Maolian Chen, Zhaokun Xiong, Yong Guo, Bo Lai. Highly efficient degradation of emerging contaminants by magnetic CuO@Fe_xO_y derived from natural mackinawite (FeS) in the presence of peroxymonosulfate[J]. Chinese Chemical Letters, ;2022, 33(2): 948-952. doi: 10.1016/j.cclet.2021.07.029 shu

Highly efficient degradation of emerging contaminants by magnetic CuO@Fe_xO_y derived from natural mackinawite (FeS) in the presence of peroxymonosulfate

Ruohan Zhang ^a ,
Maolian Chen ^b ,
Zhaokun Xiong ^{a, c, *,} ,
Yong Guo ^b ,
Bo Lai ^{a, c, *,}

a.
State Key Laboratory of Hydraulics and Mountain River Engineering, College of Architecture and Environment, Sichuan University-Pittsburgh Institute, Sichuan University, Chengdu 610207, China
b.
Department of Process Equipment and Safety Engineering, School of Chemical Engineering, Sichuan University, Chengdu 610065, China
c.
Sino-German Centre for Water and Health Research, Sichuan University, Chengdu 610065, China

scuxzk@scu.edu.cn

laibo@scu.edu.cn

Received Date: 31 May 2021
Revised Date: 4 July 2021
Accepted Date: 9 July 2021
Available Online: 16 July 2021

Figures(5)

In this study, natural mackinawite (FeS), a chalcophilic mineral, was utilized to prepare iron/copper bimetallic oxides (CuO@Fe_xO_y) by displacement plating and calcination process. Various characterization methods prove that Cu⁰ is successfully coated on the surface of FeS, which were further oxidized to CuO, Fe₃O₄ and/or Fe₂O₃ during calcination process, respectively. CuO@Fe_xO_y performed highly efficient capacity to activate PMS for the degradation of various emerging pollutants including sulfamethoxazole (SMX), carbamazepine (CBZ), bisphenol A (BPA), 2, 4-dichlorophenol (2, 4-DCP) and diclofenac (DCF) in aqueous solution. Complete removal of the above pollutants was observed after 8 min of CuO@Fe_xO_y/PMS treatment. Taking SMX as an example, the key parameters including CuO@Fe_xO_y dosage, PMS dosage and initial pH were optimized. The results show that the catalytic system can be worked in a wide pH range (3.0-9.0). The quenching experiments and electron spin resonance (ESR) test demonstrated that the main reactive oxygen species in CuO@Fe_xO_y/PMS system were hydroxyl radicals (^•OH) and sulfate radicals (SO₄^•–), and SO₄^•– was the primary reactive species. Besides, the influence of coexisting anions (i.e., Cl^–, NO₃^–, HCO₃^– and H₂PO₄^–) for the degradation of SMX was explored. CuO@Fe_xO_y/PMS system can maintain good catalytic activity and reusability in different water bodies and long-term running. This work provided a green strategy to fabricate the efficient catalyst in PMS-based advanced oxidation processes.
- Emerging organic contaminants,
- Mackinawite,
- Peroxymonosulfate,
- CuO@Fe_xO_y,
- Reactive oxygen species
1. [1]
  Q.Q. Zhang, G.G. Ying, C.G. Pan, Y.S. Liu, J.L. Zhao, Environ. Sci. Technol.49 (2015) 6772-6782. doi: 10.1021/acs.est.5b00729
2. [2]
  H. Wang, J. Yang, X. Yu, et al., Environ. Sci. Technol., 52 (2018) 13942-13950. doi: 10.1021/acs.est.8b03979
3. [3]
  Y. Li, J. Li, Y. Pan, et al., Chem. Eng. J. 384 (2020) 123361. doi: 10.1016/j.cej.2019.123361
4. [4]
  S. Nimai, H. Zhang, Z. Wu, N. Li, B. Lai, Chin. Chem. Lett. 31 (2020) 2657-2660. doi: 10.1016/j.cclet.2020.08.008
5. [5]
  M. Feng, J.C. Baum, N. Nesnas, et al., Environ. Sci. Technol. 53 (2019) 2695-2704. doi: 10.1021/acs.est.8b06535
6. [6]
  J. Li, Y. Li, Z. Xiong, G. Yao, B. Lai, Chin. Chem. Lett. 30 (2019) 2139-2146. doi: 10.1016/j.cclet.2019.04.057
7. [7]
  H. Zhang, Q. Ji, L. Lai, G. Yao, B. Lai, Chin. Chem. Lett. 30 (2019) 1129-1132. doi: 10.1016/j.cclet.2019.01.025
8. [8]
  B. Huang, Z. Wu, H. Zhou, et al., J. Hazard. Mater. 412 (2021) 125253. doi: 10.1016/j.jhazmat.2021.125253
9. [9]
  Z. Xiong, Y. Jiang, Z. Wu, G. Yao, B. Lai, Chem. Eng. J. 421 (2021) 127863.
10. [10]
  J. Wang, S. Wang, Chem. Eng. J., 334 (2018) 1502-1517. doi: 10.1016/j.cej.2017.11.059
11. [11]
  Z. Wu, Y. Wang, Z. Xiong, et al., Appl. Catal. B-Environ. 277 (2020) 119136. doi: 10.1016/j.apcatb.2020.119136
12. [12]
  J. Li, M. Xu, G. Yao, B. Lai, Chem. Eng. J. 348 (2018) 1012-1024. doi: 10.1016/j.cej.2018.05.032
13. [13]
  J. Li, J. Yan, G. Yao, et al., Chem. Eng. J. 361 (2019) 1317-1332. doi: 10.1016/j.cej.2018.12.144
14. [14]
  Y. Lei, C.S. Chen, Y.J. Tu, Y.H. Huang, H. Zhang, Environ. Sci. Technol. 49 (2015) 6838-6845. doi: 10.1021/acs.est.5b00623
15. [15]
  J. Peng, H. Zhou, W. Liu, et al., Chem. Eng. J. 397 (2020) 125387. doi: 10.1016/j.cej.2020.125387
16. [16]
  L. Lai, H. Zhou, B. Lai, Chem. Eng. J. 349 (2018) 633-645. doi: 10.1016/j.cej.2018.05.134
17. [17]
  L. Lai, H. Ji, H. Zhang, et al., Appl. Catal. B Environ. 282 (2021) 119559. doi: 10.1016/j.apcatb.2020.119559
18. [18]
  D. Cheng, S. Yuan, P. Liao, P. Zhang, Environ. Sci. Technol. 50 (2016) 11646-11653. doi: 10.1021/acs.est.6b02833
19. [19]
  Y. Gong, J. Tang, D. Zhao, Water Res. 89 (2016) 309-320. doi: 10.1016/j.watres.2015.11.063
20. [20]
  Y. He, J. Zhang, H. Zhou, G. Yao, B. Lai, Chem. Eng. J. 380 (2020) 122568. doi: 10.1016/j.cej.2019.122568
21. [21]
  Y. Dai, L. Niu, J. Zou, et al., Chin. Chem. Lett. 29 (2018) 887-891. doi: 10.1016/j.cclet.2017.11.029
22. [22]
  F. Ji, C. Li, L. Deng, Chem. Eng. J., 178 (2011) 239-243. doi: 10.1016/j.cej.2011.10.059
23. [23]
  Y. Zhu, Z. -S. Bai, H. -L. Wang, Chin. Chem. Lett. 28 (2017) 633-641. doi: 10.1016/j.cclet.2016.10.031
24. [24]
  S. Wang, L. Xu, J. Wang, Chem. Eng. J. 375 (2019) 122041. doi: 10.1016/j.cej.2019.122041
25. [25]
  L. Li, Q. Zhang, Y. She, Y. Yu, J. Hong, Sep. Purif. Technol. 270 (2021) 118770. doi: 10.1016/j.seppur.2021.118770
26. [26]
  F. Pan, H. Ji, P. Du, et al., J. Hazard. Mater. 402 (2021) 123779. doi: 10.1016/j.jhazmat.2020.123779
27. [27]
  L. Chen, H. Ji, J. Qi, et al., Chem. Eng. J. 406 (2021) 126877. doi: 10.1016/j.cej.2020.126877
28. [28]
  M. Ma, L. Chen, J. Zhao, W. Liu, H. Ji, Chin. Chem. Lett. 30 (2019) 2191-2195. doi: 10.1016/j.cclet.2019.09.031
29. [29]
  R. Luo, M. Li, C. Wang, et al., Water Res. 148 (2019) 416-424.
30. [30]
  F. Chen, L.L. Liu, J.J. Chen, et al., Water Res. 191 (2021) 116799. doi: 10.1016/j.watres.2020.116799
31. [31]
  T. Sun, Z. Zhao, Z. Liang, et al., Chem. Eng. J. 334 (2018) 1527-1536. doi: 10.1016/j.cej.2017.11.052
32. [32]
  Z. Xiong, J. Li, Y. Li, et al., J. Hazard. Mater. 406 (2021) 124725. doi: 10.1016/j.jhazmat.2020.124725
33. [33]
  X. Wang, X. Pu, Y. Yuan, et al., Chin. Chem. Lett. 31 (2020) 2634-2640. doi: 10.1016/j.cclet.2020.08.007
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

Highly efficient degradation of emerging contaminants by magnetic CuO@FexOy derived from natural mackinawite (FeS) in the presence of peroxymonosulfate

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通讯作者: 陈斌, bchen63@163.com

Highly efficient degradation of emerging contaminants by magnetic CuO@Fe_xO_y derived from natural mackinawite (FeS) in the presence of peroxymonosulfate