Citation: Shuangyan Liu, Taishan Yan, Qiuxia Wu, Zheng Xu, Jie Han. Accelerating the thermal fading rate of photochromic naphthopyrans by pillar[5]arene-based conjugated macrocycle polymer[J]. Chinese Chemical Letters, ;2022, 33(1): 239-242. doi: 10.1016/j.cclet.2021.07.023 shu

Accelerating the thermal fading rate of photochromic naphthopyrans by pillar[5]arene-based conjugated macrocycle polymer

Shuangyan Liu ^{a, 1} ,
Taishan Yan ^{b, 1} ,
Qiuxia Wu ^b ,
Zheng Xu ^a ,
Jie Han ^{a, b, *,}

a.
Key Laboratory of Advanced Energy Materials Chemistry (Ministry of Energy), College of Chemistry, Nankai University, Tianjin 300071, China
b.
State Key Laboratory of Elemento-Organic Chemistry, College of Chemistry, Nankai University, Tianjin 300071, China

hanjie@nankai.edu.cn

Received Date: 23 March 2021
Revised Date: 5 July 2021
Accepted Date: 8 July 2021
Available Online: 14 July 2021

Figures(5)

A new micro-spherical conjugated macrocycle polymer (P[5]-TFB-CMP) was prepared by the condensation reaction between dihydrazide functionalized pillar[5]arene and 1, 3, 5-triformylbenzene under ambient conditions. P[5]-TFB-CMP exhibits large surface area with excellent thermal stability and has been used as additive to prepare composite PMMA film of photochromic naphthopyrans. The results showed that the addition of P[5]-TFB-CMP could dramatically accelerate the thermal fading rate of the photochromic composite film by up to 12 times. This is a new strategy to overcome the drawback of the matrix effect.
- Pillar[5]arene,
- Conjugated macrocycle polymer,
- Naphothopyran,
- Photochromism,
- Thermal fading rate,
- Matrix effect
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