Citation: Yanchun Shi, Chen Gao, Enhui Xing, Jimei Zhang, Feng Duan, He Zhao, Yongbing Xie. Ni nanoparticles encapsulated within H-type ZSM-5 crystals for upgrading palmitic acid to diesel-like fuels[J]. Chinese Chemical Letters, ;2022, 33(2): 803-806. doi: 10.1016/j.cclet.2021.06.086 shu

Ni nanoparticles encapsulated within H-type ZSM-5 crystals for upgrading palmitic acid to diesel-like fuels

Yanchun Shi ^a ,
Chen Gao ^a ,
Enhui Xing ^b ,
Jimei Zhang ^a ,
Feng Duan ^a ,
He Zhao ^a ,
Yongbing Xie ^{a, *,}

a.
CAS Key Laboratory of Green Process and Engineering, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, China
b.
State Key Laboratory of Catalytic Materials and Reaction Engineering, Research Institute of Petroleum Processing, Sinopec, Beijing 100083, China

ybxie@ipe.ac.cn

Received Date: 18 May 2021
Revised Date: 17 June 2021
Accepted Date: 29 June 2021
Available Online: 6 July 2021

Figures(3)

Meso-Ni@HZSM-5 bi-functional catalysts were successfully post-encapsulated with about 3–7 nm Ni nanoparticles within HZSM-5 crystals, which exhibited significantly efficient conversion activity (67.4 g[palmitic acid] g[Ni]⁻¹ h⁻¹) of palmitic acid and 100% selectivity of hydrocarbons with the outstanding stability during recycling application, compared to the impregnated Ni/HZSM-5 catalyst (14.0 g[palmitic acid] g[Ni]⁻¹ h⁻¹).
- Post-encapsulation,
- Ni@HZSM-5,
- Ni nanoparticles,
- Palmitic acid,
- Hydrodeoxygenation,
- Hydrocarbons
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沈阳化工大学材料科学与工程学院沈阳 110142