Citation: Yanpeng Liu, Ming Yang, Junpeng Lu, Ying Liu, Hongwei Liu, Erwen Zhang, Wei Fu, Junyong Wang, Zhenliang Hu, Jun Yin, Goki Eda, Shijie Wang, Jiabao Yi, Ajayan Vinu, Kian Ping Loh. Tuning photoresponse of graphene-black phosphorus heterostructure by electrostatic gating and photo-induced doping[J]. Chinese Chemical Letters, ;2022, 33(1): 368-373. doi: 10.1016/j.cclet.2021.06.079 shu

Tuning photoresponse of graphene-black phosphorus heterostructure by electrostatic gating and photo-induced doping

Yanpeng Liu ^{a, 1, *,} ,
Ming Yang ^{b, 1} ,
Junpeng Lu ^{c, 1} ,
Ying Liu ^d ,
Hongwei Liu ^e ,
Erwen Zhang ^a ,
Wei Fu ^f ,
Junyong Wang ^f ,
Zhenliang Hu ^c ,
Jun Yin ^a ,
Goki Eda ^f ,
Shijie Wang ^g ,
Jiabao Yi ^h ,
Ajayan Vinu ^h ,
Kian Ping Loh ^{f, *,}

a.
Key Laboratory for Intelligent Nano Materials and Devices of the Ministry of Education, State Key Laboratory of Mechanics and Control of Mechanical Structures, Nanjing University of Aeronautics and Astronautics, Nanjing 210016, China
b.
Department of Applied Physics, The Hong Kong Polytechnic University, Hong Kong, China
c.
School of Physics, Southeast University, Nanjing 211189, China
d.
College of Jincheng, Nanjing University of Aeronautics and Astronautics, Nanjing 211156, China
e.
School of Physics and Technology, Nanjing Normal University, Nanjing 210023, China
f.
Department of Chemistry, National University of Singapore, Singapore 117543, Singapore
g.
Institute of Materials Research and Engineering, Agency for Science, Technology and Research (A*STAR), Innovis 138634, Singapore
h.
Global Innovative Centre for Advanced Nanomaterials, College of Engineering, Science and Environment, The University of Newcastle, Newcastle NSW 2308, Australia

chmliuyp@nuaa.edu.cn

chmlohkp@nus.edu.sg

Received Date: 12 May 2021
Revised Date: 21 June 2021
Accepted Date: 27 June 2021
Available Online: 2 July 2021

Figures(4)

Metal-semiconductor diodes constructed from two-dimensional (2D) van der Waals heterostructures show excellent gate electrostatics and a large built-in electric field at the tunnel junction, which can be exploited to make highly sensitive photodetector. Here we demonstrate a metal-semiconductor photodiode constructed by the monolayer graphene (Gr) on a few-layer black phosphorus (BP). Due to the presence of a built-in potential barrier (~0.09 ± 0.03 eV) at the Gr-BP interface, the photoresponsivity of the Gr-BP device is enhanced by a factor of 672%, and the external quantum efficiency (EQE) increases to 648% from 84% of the bare BP. Electrostatic gating allows the BP channel to be switched between p-type and n-type conduction. We further demonstrate that excitation laser power can be used to control the current polarity of the Gr-BP device due to photon-induced doping. The versatility of the Gr-BP junctions in terms of electrostatic bias-induced or light-induced switching of current polarity is potentially useful for making dynamically reconfigurable digital circuits.
- Black phosphorous,
- Graphene,
- Heterostructure,
- Gate-tunable,
- Photodetector,
- Photoinverter
1. [1]
  Li, Y. Yu, G.J. Ye, et al., Nat. Nanotechnol. 9 (2014) 372–377. doi: 10.1038/nnano.2014.35
2. [2]
  F.N. Xia, H. Wang, Y.C. Jia, Nat. Commun. 5 (2014) 4458. doi: 10.1038/ncomms5458
3. [3]
  M. Buscema, D.J. Groenendijk, S.I. Blanter, et al., Nano Lett. 14 (2014), 3347–3352. doi: 10.1021/nl5008085
4. [4]
  T. Low, M. Engel, M. Steiner, P. Avouris. Phys. Rev. B 90 (2014) 081408. doi: 10.1103/PhysRevB.90.081408
5. [5]
  H. Yuan, X. Liu, F. Afshinmanesh, et al., Nat. Nanotechnol. 10 (2015) 707–713. doi: 10.1038/nnano.2015.112
6. [6]
  N. Youngblood, C. Chen, S.J. Koester, M. Li, Nat. Photon. 9 (2015) 247–252. doi: 10.1038/nphoton.2015.23
7. [7]
  Q. Guo, A. Pospischil, M. Bhuiyan, et al., Nano Lett. 16 (2016) 4648–4655. doi: 10.1021/acs.nanolett.6b01977
8. [8]
  D. Xiang, C. Han, J. Wu, et al., Nat. Commun. 6 (2015) 6485. doi: 10.1038/ncomms7485
9. [9]
  Y.J. Xu, J. Yuan, L. Fei, et al., Small 12 (2016) 5000–5007. doi: 10.1002/smll.201600692
10. [10]
  M. Freitag, T. Low, F. Xia, P. Avouris, Nat. Photon. 7 (2013) 53–59. doi: 10.1038/nphoton.2012.314
11. [11]
  W.J. Yu, Y. Liu, H. Zhou, et al., Nat. Nanotechnol. 8 (2013) 952–958. doi: 10.1038/nnano.2013.219
12. [12]
  T. Low, R. Roldán, H. Wang, et al., Phys. Rev. Lett. 113 (2014) 106802. doi: 10.1103/PhysRevLett.113.106802
13. [13]
  Y. Liu, Z. Qiu, A. Carvalho, et al., Nano Lett. 17 (2017) 1970–1977. doi: 10.1021/acs.nanolett.6b05381
14. [14]
  J.P. Lu, A. Carvalho, J. Wu, et al., Adv. Mater. 28 (2016) 4090–4096. doi: 10.1002/adma.201506201
15. [15]
  A.K. Geim, I.V. Grigorieva, Nature, 499 (2013) 419–425. doi: 10.1038/nature12385
16. [16]
  H. Fang, C. Battaglia, C. Carraro, et al., PNAS 111 (2014) 6198–6202. doi: 10.1073/pnas.1405435111
17. [17]
  Q.H. Wang, K. Kalantar-Zadeh, A. Kis, et al., Nature Nanotechnol. 7 (2012), 699–712. doi: 10.1038/nnano.2012.193
18. [18]
  S.Z. Butler, S.M. Hollen, L. Cao, et al., ACS Nano 7 (2013) 2898–2926. doi: 10.1021/nn400280c
19. [19]
  F.H.L. Koppens, T. Mueller, P. Avouris, et al., Nat. Nanotechnol. 9 (2014), 780–793. doi: 10.1038/nnano.2014.215
20. [20]
  C.H. Lee, G.H. Lee, A.M. van der Zande, et al., Nat. Nanotechnol. 9 (2014) 676–681. doi: 10.1038/nnano.2014.150
21. [21]
  K. Roy, M. Padmanabhan, S. Goswami, et al., Nat. Nanotechnol. 8 (2013) 826–830. doi: 10.1038/nnano.2013.206
22. [22]
  B.W. Baugher, H.O. Churchill, Y. Yafang, P. Jarillo-Herrero, Nat. Nanotechnol. 9(2014) 262–267. doi: 10.1038/nnano.2014.25
23. [23]
  O. Lopez-Sanchez, D. Lembke, M. Kayci, A. Radenovic, A. Kis, Nat. Nanotechnol. 8 (2013) 497–501. doi: 10.1038/nnano.2013.100
24. [24]
  M. Buscema, D.J. Groenendijk, G.A. Steele, et al., Nat. Commun. 5 (2014) 4651. doi: 10.1038/ncomms5651
25. [25]
  W.J. Yu, Z. Li, H. Zhou, et al., Nat. Mater. 12 (2013) 246–252. doi: 10.1038/nmat3518
26. [26]
  A. Favron, E. Gaufres, F. Fossard, et al., Nat. Mater. 14 (2015) 826–832. doi: 10.1038/nmat4299
27. [27]
  A. Das, S. Pisana, B. Chakraborty, et al., Nat. Nanotechnol. 3 (2008) 210–215. doi: 10.1038/nnano.2008.67
28. [28]
  D. Hanlon, C. Backes, E. Doherty, et al., Nat. Commun. 6 (2015), 8563. doi: 10.1038/ncomms9563
29. [29]
  J. Lu, J. Wu, A. Carvalho, et al., ACS Nano 9 (2015) 10411–10421. doi: 10.1021/acsnano.5b04623
30. [30]
  Y. Liu, L. Yuan, M. Yang, et al., Nat. Commun. 5(2014) 5461. doi: 10.1038/ncomms6461
31. [31]
  Y.J. Yu, Y. Zhao, S. Ryu, et al., Nano Lett. 9 (2009), 3430–3434. doi: 10.1021/nl901572a
32. [32]
  J.E. Padilha, A. Fazzio, A.J. da Silva, Phys. Rev. Lett. 114 (2015), 066803. doi: 10.1103/PhysRevLett.114.066803
33. [33]
  L. Li, G.J. Ye, V. Tran, et al., Nat. Nanotechnol. 10 (2015), 608–613. doi: 10.1038/nnano.2015.91
34. [34]
  L. Ju, J. Velasco Jr., E. Huang, et al., Nat. Nanotechnol. 9 (2014) 348–352. doi: 10.1038/nnano.2014.60
35. [35]
  J.E. Padiha, A. Fazzio, A.J.R. da Silva, Phys. Rev. Lett. 114 (2015) 066803. doi: 10.1103/PhysRevLett.114.066803
36. [36]
  H. Guo, N. Lu, J. Dai, et al., J. Phys. Chem. C 118 (2014) 14051–14059. doi: 10.1021/jp505257g
37. [37]
  Y.Q. Cai, G. Zhang, Y.W. Zhang, J. Phys. Chem. C 119 (2015) 13929–13936. doi: 10.1021/acs.jpcc.5b02634
38. [38]
  P.A. Khomyakov, G. Giovannetti, P.C. Rusu, et al., Phys. Rev. B 79 (2009) 195425. doi: 10.1103/PhysRevB.79.195425
39. [39]
  Z. Xia, P. Li, Y. Liu, et al., Nano Res. 10 (2017) 3848–3856. doi: 10.1007/s12274-017-1598-z
40. [40]
  P.H. Ho, M.K. Li, R. Sankar, et al., ACS Photon. 3 (2016) 1102–1108. doi: 10.1021/acsphotonics.6b00192
41. [41]
  M. Huang, M. Wang, C. Chen, et al., Adv. Mater. 28 (2016) 3481–3485. doi: 10.1002/adma.201506352
42. [42]
  Y. Huang, J. Qiao, K. He, et al., Chem. Mater. 28 (2016) 8330–8339. doi: 10.1021/acs.chemmater.6b03592
1. [1]
  Jiangqi Ning , Junhan Huang , Yuhang Liu , Yanlei Chen , Qing Niu , Qingqing Lin , Yajun He , Zheyuan Liu , Yan Yu , Liuyi Li . Alkyl-linked TiO2@COF heterostructure facilitating photocatalytic CO2 reduction by targeted electron transport. Chinese Journal of Structural Chemistry, 2024, 43(12): 100453-100453. doi: 10.1016/j.cjsc.2024.100453
2. [2]
  Yuchen Guo , Xiangyu Zou , Xueling Wei , Weiwei Bao , Junjun Zhang , Jie Han , Feihong Jia . Fe regulating Ni3S2/ZrCoFe-LDH@NF heterojunction catalysts for overall water splitting. Chinese Journal of Structural Chemistry, 2024, 43(2): 100206-100206. doi: 10.1016/j.cjsc.2023.100206
3. [3]
  Cheng Guo , Xiaoxiao Zhang , Xiujuan Hong , Yiqiu Hu , Lingna Mao , Kezhi Jiang . Graphene as adsorbent for highly efficient extraction of modified nucleosides in urine prior to liquid chromatography-tandem mass spectrometry analysis. Chinese Chemical Letters, 2024, 35(4): 108867-. doi: 10.1016/j.cclet.2023.108867
4. [4]
  Sanmei Wang , Yong Zhou , Hengxin Fang , Chunyang Nie , Chang Q Sun , Biao Wang . Constant-potential simulation of electrocatalytic N₂ reduction over atomic metal-N-graphene catalysts. Chinese Chemical Letters, 2025, 36(3): 110476-. doi: 10.1016/j.cclet.2024.110476
5. [5]
  Sanmei Wang , Dengxin Yan , Wenhua Zhang , Liangbing Wang . Graphene-supported isolated platinum atoms and platinum dimers for CO₂ hydrogenation: Catalytic activity and selectivity variations. Chinese Chemical Letters, 2025, 36(4): 110611-. doi: 10.1016/j.cclet.2024.110611
6. [6]
  Wenjing Xiong , Yulin Xu , Fangzhou Zhao , Baokai Xia , Hongqiang Wang , Wei Liu , Sheng Chen , Yongzhi Zhang . Graphene architecture interpenetrated with mesoporous carbon nanosheets promotes fast and stable potassium storage. Chinese Chemical Letters, 2025, 36(4): 109738-. doi: 10.1016/j.cclet.2024.109738
7. [7]
  Caili Yang , Tao Long , Ruotong Li , Chunyang Wu , Yuan-Li Ding . Pseudocapacitance dominated Li₃VO₄ encapsulated in N-doped graphene via 2D nanospace confined synthesis for superior lithium ion capacitors. Chinese Chemical Letters, 2025, 36(2): 109675-. doi: 10.1016/j.cclet.2024.109675
8. [8]
  Yixin Lu , Minghan Qin , Shixian Zhang , Zhen Liu , Wang Sun , Zhenhua Wang , Jinshuo Qiao , Kening Sun . Triple-conducting heterostructure anodes for electrochemical ethane nonoxidative dehydrogenation by protonic ceramic electrolysis cells. Chinese Chemical Letters, 2025, 36(4): 110567-. doi: 10.1016/j.cclet.2024.110567
9. [9]
  Dai-Huo Liu , Ao Wang , Hong-Yan Lü , Xing-Long Wu , Dan Luo , Wen-Hao Li , Jin-Zhi Guo , Haozhen Dou , Qianyi Ma , Zhongwei Chen . In situ constructing (MnS/Mn₂SnS₄)@N,S-ACTs heterostructure with superior Na/Li-storage capabilities in half-cells and pouch full-cells. Chinese Chemical Letters, 2024, 35(11): 109285-. doi: 10.1016/j.cclet.2023.109285
10. [10]
  Chaozheng He , Pei Shi , Donglin Pang , Zhanying Zhang , Long Lin , Yingchun Ding . First-principles study of the relationship between the formation of single atom catalysts and lattice thermal conductivity. Chinese Chemical Letters, 2024, 35(6): 109116-. doi: 10.1016/j.cclet.2023.109116
11. [11]
  Chang Liu , Zirui Song , Xinglan Deng , Shihong Xu , Renji Zheng , Wentao Deng , Hongshuai Hou , Guoqiang Zou , Xiaobo Ji . Interfacial/bulk synergetic effects accelerating charge transferring for advanced lithium-ion capacitors. Chinese Chemical Letters, 2024, 35(6): 109081-. doi: 10.1016/j.cclet.2023.109081
12. [12]
  Jiayu Bai , Songjie Hu , Lirong Feng , Xinhui Jin , Dong Wang , Kai Zhang , Xiaohui Guo . Manganese vanadium oxide composite as a cathode for high-performance aqueous zinc-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109326-. doi: 10.1016/j.cclet.2023.109326
13. [13]
  Shudi Yu , Jie Li , Jiongting Yin , Wanyu Liang , Yangping Zhang , Tianpeng Liu , Mengyun Hu , Yong Wang , Zhengying Wu , Yuefan Zhang , Yukou Du . Built-in electric field and core-shell structure of the reconstructed sulfide heterojunction accelerated water splitting. Chinese Chemical Letters, 2024, 35(12): 110068-. doi: 10.1016/j.cclet.2024.110068
14. [14]
  Qing Li , Yumei Feng , Yingjie Yu , Yazhou Chen , Yuhua Xie , Fang Luo , Zehui Yang . Engineering e_g filling of RuO₂ enables a robust and stable acidic water oxidation. Chinese Chemical Letters, 2025, 36(3): 110612-. doi: 10.1016/j.cclet.2024.110612
15. [15]
  Ming Zhong , Xue Guo , Yang Liu , Kun Zhao , Hui Peng , Suijun Liu , Xiaobo Zhang . Molybdenum-glycerate@zeolitic imidazolate framework spheres derived hierarchical nitrogen-doped carbon-encapsulated bimetallic selenides heterostructures for improved lithium-ion storage. Chinese Chemical Letters, 2025, 36(5): 109873-. doi: 10.1016/j.cclet.2024.109873
16. [16]
  Yu-Hui Zhang , Ye Tian , Xianliang Sheng , Chen-Shuang Liu , Lu-Qiang Wei , Jie Wang , Yong Chen . Construction of a black phosphorous-based noncovalent multiple nanosupramolecular assembly for synergistic targeted photothermal and chemodynamic therapy. Chinese Chemical Letters, 2025, 36(4): 110193-. doi: 10.1016/j.cclet.2024.110193
17. [17]
  Jie Zhou , Chuanxiang Zhang , Changchun Hu , Shuo Li , Yuan Liu , Zhu Chen , Song Li , Hui Chen , Rokayya Sami , Yan Deng . Electrochemical aptasensor based on black phosphorus-porous graphene nanocomposites for high-performance detection of Hg²⁺. Chinese Chemical Letters, 2024, 35(11): 109561-. doi: 10.1016/j.cclet.2024.109561
18. [18]
  Yuhang Zhang , Weiwei Zhao , Hongwei Liu , Junpeng Lü . 基于低维材料的自供电光电探测器研究进展. Acta Physico-Chimica Sinica, 2025, 41(3): 2310004-. doi: 10.3866/PKU.WHXB202310004
19. [19]
  Mengfei He , Chao Chen , Yue Tang , Si Meng , Zunfa Wang , Liyu Wang , Jiabao Xing , Xinyu Zhang , Jiahui Huang , Jiangbo Lu , Hongmei Jing , Xiangyu Liu , Hua Xu . Epitaxial Growth of Nonlayered 2D MnTe Nanosheets with Thickness-Tunable Conduction for p-Type Field Effect Transistor and Superior Contact Electrode. Acta Physico-Chimica Sinica, 2025, 41(2): 100016-. doi: 10.3866/PKU.WHXB202310029
20. [20]
  Yao Ma , Xin Zhao , Hongxu Chen , Wei Wei , Liang Shen . Progress and Perspective of Perovskite Thin Single Crystal Photodetectors. Acta Physico-Chimica Sinica, 2025, 41(4): 100030-. doi: 10.3866/PKU.WHXB202309045

Get Citation

PDF

XML

Metrics

PDF Downloads(4)
Abstract views(499)
HTML views(14)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142