Citation: Miao Yang, Zhonghui Sun, Ping Nie, Haiyue Yu, Chende Zhao, Mengxuan Yu, Zhongzhen Luo, Hongbo Geng, Xinglong Wu. SbPS₄: A novel anode for high-performance sodium-ion batteries[J]. Chinese Chemical Letters, ;2022, 33(1): 470-474. doi: 10.1016/j.cclet.2021.06.065 shu

SbPS₄: A novel anode for high-performance sodium-ion batteries

Miao Yang ^{a, b, 1} ,
Zhonghui Sun ^{c, 1} ,
Ping Nie ^d ,
Haiyue Yu ^b ,
Chende Zhao ^b ,
Mengxuan Yu ^b ,
Zhongzhen Luo ^{e, *,} ,
Hongbo Geng ^{a, *,} ,
Xinglong Wu ^{b, f, **,}

a.
School of Materials Engineering, Changshu Institute of Technology, Changshu 215500, China
b.
Faculty of Chemistry, Northeast Normal University, Changchun 130024, China
c.
Center for Advanced Analytical Science, School of Chemistry and Chemical Engineering, Guangzhou University, Guangzhou 510006, China
d.
Key Laboratory of Preparation and Application of Environmental Friendly Materials (Jilin Normal University), Ministry of Education, Changchun 130103, China
e.
Key Laboratory of Eco-materials Advanced Technology, College of Materials Science and Engineering, Fuzhou University, Fuzhou 350108, China
f.
Key Laboratory for UV Light-Emitting Materials and Technology, Northeast Normal University, Ministry of Education, Changchun 130024, China

^**

zzluo@fzu.edu.cn

hbgeng@cslg.edu.cn

xinglong@nenu.edu.cn

Received Date: 1 June 2021
Revised Date: 13 June 2021
Accepted Date: 23 June 2021
Available Online: 30 June 2021

Figures(8)

With the in-depth research of sodium-ion batteries (SIBs), the development of novel sodium-ion anode material has become a top priority. In this work, tube cluster-shaped SbPS₄ was synthesized by a high-temperature solid phase reaction. Then the typical short tubular ternary thiophosphate SbPS₄ compounded with graphene oxide (SbPS₄/GO) was successfully synthesized after ultrasonication and freeze-drying. SbPS₄ shows a high theoretical specific capacity (1335 mAh/g) according to the conversion-alloying dual mechanisms. The unique short tube inserted in the spongy graphene structure of SbPS₄/GO results in boosting the Na ions transport and alleviating the huge volume change in the charging and discharging processes, improving the sodium storage performance. Consequently, the tubular SbPS₄ compounded with 10% GO provides an outstanding capacity of 359.58 mAh/g at 500 mA/g. The result indicates that SbPS₄/GO anode has a promising application potential for SIBs.
- Sodium-ion batteries,
- High-capacity anode,
- Thiophosphate,
- SbPS₄/GO,
- Full cell
1. [1]
  Y. Wu, C. Zhang, H. Zhao, Y. Lei, J. Mater. Chem. A 9 (2021) 9506-9534. doi: 10.1039/D1TA00831E
2. [2]
  T.G. Allen, J. Bullock, X. Yang, A. Javey, S. De Wolf, Nat. Energy 4 (2019) 914-928. doi: 10.1038/s41560-019-0463-6
3. [3]
  J. Ding, W. Hu, E. Paek, D. Mitlin, Chem. Rev. 118 (2018) 6457-6498. doi: 10.1021/acs.chemrev.8b00116
4. [4]
  Y. Li, Y. Lu, C. Zhao, et al., Energy Storage Mater. 7 (2017) 130-151. doi: 10.1016/j.ensm.2017.01.002
5. [5]
  M. Yang, Q. Ning, C. Fan, X.L. Wu, Chin. Chem. Lett. 32 (2021) 895-899. doi: 10.1016/j.cclet.2020.07.014
6. [6]
  W.H. Li, H.J. Liang, X.K. Hou, et al., J. Energy Chem. 50 (2020) 416-423. doi: 10.1016/j.jechem.2020.03.043
7. [7]
  H. Huang, X. Luo, Y. Yao, et al., InfoMat 3 (2021) 421-431. doi: 10.1002/inf2.12176
8. [8]
  Y. Heng, Z. Gu, J. Guo, X. Wu, Acta Phys. Chim. Sin. 37 (2021) 2005013.
9. [9]
  S. Geng, T. Zhou, M. Jia, et al., Energy Environ. Sci. 14 (2021) 3184-3193. doi: 10.1039/D1EE00193K
10. [10]
  V. Palomares, M. Casas-Cabanas, E. Castillo-Martínez, M.H. Han, T. Rojo, Energy Environ. Sci. 6 (2013) 2312-2337. doi: 10.1039/c3ee41031e
11. [11]
  H. Pan, Y.S. Hu, L. Chen, Energy Environ. Sci. 6 (2013) 2338-2360. doi: 10.1039/c3ee40847g
12. [12]
  X. Hou, W. Li, Y. Wang, et al., Chin. Chem. Lett. 31 (2020) 2314-2318. doi: 10.1016/j.cclet.2020.04.021
13. [13]
  Z.Y. Gu, J.Z. Guo, X.X. Zhao, et al., InfoMat 3 (2021) 694-704. doi: 10.1002/inf2.12184
14. [14]
  Y. Jiang, Y. Wang, J. Ni, L. Li, InfoMat 3 (2021) 339-352. doi: 10.1002/inf2.12175
15. [15]
  H.J. Liang, B.H. Hou, W.H. Li, et al., Energy Environ. Sci. 12 (2019) 3575-3584. doi: 10.1039/C9EE02759A
16. [16]
  S. Haghighat-Shishavan, M. Nazarian-Samani, M. Nazarian-Samani, K.B. Kim, Energy Storage Mater. 39 (2021) 96-107. doi: 10.1016/j.ensm.2021.03.037
17. [17]
  K.T. Chen, S. Chong, L. Yuan, Y.C. Yang, H.Y. Tuan, Energy Storage Mater. 39 (2021) 239-249. doi: 10.1016/j.ensm.2021.04.019
18. [18]
  B. Dou, J. Yan, Q. Chen, et al., Sens. Actuator. B. Chem. 328 (2021) 129082. doi: 10.1016/j.snb.2020.129082
19. [19]
  A. Kato, H. Kowada, M. Deguchi, et al., Solid State Ionics 322 (2018) 1-4. doi: 10.1016/j.ssi.2018.04.011
20. [20]
  A. Qiao, H. Tao, Y. Yue, J. Non-Cryst. Solid 521 (2019) 119476. doi: 10.1016/j.jnoncrysol.2019.119476
21. [21]
  C.D. Malliakas, M.G. Kanatzidis, J. Am. Chem. Soc. 128 (2006) 6538-6539. doi: 10.1021/ja057943m
22. [22]
  H.J. Liang, Z.Y. Gu, X.Y. Zheng, et al., J. Energy Chem. 59 (2021) 589-598. doi: 10.1016/j.jechem.2020.11.039
23. [23]
  Z. Yi, N. Lin, W. Zhang, et al., Nanoscale 10 (2018) 13236-13241. doi: 10.1039/C8NR03829E
24. [24]
  L. Yang, W. Hong, Y. Tian, et al., Chem. Eng. J. 385 (2020) 123838. doi: 10.1016/j.cej.2019.123838
25. [25]
  C. Kang, S. Zhou, J. Liu, et al., J. Mater. Chem. A 9 (2021) 2152-2160. doi: 10.1039/D0TA10556B
26. [26]
  L. Zhou, Z. Cao, J. Zhang, et al., Adv. Mater. 33 (2021) 2005993. doi: 10.1002/adma.202005993
27. [27]
  C. Lin, Y. Wang, F. Zhong, et al., Chem. Eng. J. 407 (2021) 126991. doi: 10.1016/j.cej.2020.126991
28. [28]
  F. Xie, L. Zhang, Q. Gu, et al., Nano Energy 60 (2019) 591-599. doi: 10.1016/j.nanoen.2019.04.008
29. [29]
  B.H. Hou, Y.Y. Wang, Q.L. Ning, et al., Nanoscale 11 (2019) 1304-1312. doi: 10.1039/C8NR08849G
30. [30]
  H. Huang, R. Xu, Y. Feng, et al., Adv. Mater. 32 (2020) 1904320. doi: 10.1002/adma.201904320
31. [31]
  O.A. Jaramillo-Quintero, R.V. Barrera-Peralta, A.G. El Hachimi, et al., J. Colloid Interface Sci. 585 (2021) 649-659. doi: 10.1016/j.jcis.2020.10.044
32. [32]
  H. Lu, F. Ai, Y. Jia, et al., Small 14 (2018) 1802694. doi: 10.1002/smll.201802694
33. [33]
  A. Xu, C. Huang, G. Li, et al., J. Mater. Chem. A 9 (20) (2021) 12169-12178. doi: 10.1039/D1TA01930A
34. [34]
  B.H. Hou, Y.Y. Wang, Q.L. Ning, et al., Adv. Mater. 31 (2019) 1903125. doi: 10.1002/adma.201903125
35. [35]
  H.Y. Yu, H.J. Liang, Z.Y. Gu, et al., Electrochim. Acta 361 (2020) 137041. doi: 10.1016/j.electacta.2020.137041
36. [36]
  X. Li, S. Jiang, S. Li, et al., J. Mater. Chem. A 9 (19) (2021) 11827-11838. doi: 10.1039/D1TA02250D
1. [1]
  Ruofan Yin , Zhaoxin Guo , Rui Liu , Xian-Sen Tao . Ultrafast synthesis of Na₃V₂(PO₄)₃ cathode for high performance sodium-ion batteries. Chinese Chemical Letters, 2025, 36(2): 109643-. doi: 10.1016/j.cclet.2024.109643
2. [2]
  Huixin Chen , Chen Zhao , Hongjun Yue , Guiming Zhong , Xiang Han , Liang Yin , Ding Chen . Unraveling the reaction mechanism of high reversible capacity CuP₂/C anode with native oxidation PO_x component for sodium-ion batteries. Chinese Chemical Letters, 2025, 36(1): 109650-. doi: 10.1016/j.cclet.2024.109650
3. [3]
  Xiping Dong , Xuan Wang , Zhixiu Lu , Qinhao Shi , Zhengyi Yang , Xuan Yu , Wuliang Feng , Xingli Zou , Yang Liu , Yufeng Zhao . Construction of Cu-Zn Co-doped layered materials for sodium-ion batteries with high cycle stability. Chinese Chemical Letters, 2024, 35(5): 108605-. doi: 10.1016/j.cclet.2023.108605
4. [4]
  Zhong-Hui Sun , Yu-Qi Zhang , Zhen-Yi Gu , Dong-Yang Qu , Hong-Yu Guan , Xing-Long Wu . CoPSe nanoparticles confined in nitrogen-doped dual carbon network towards high-performance lithium/potassium ion batteries. Chinese Chemical Letters, 2025, 36(1): 109590-. doi: 10.1016/j.cclet.2024.109590
5. [5]
  Jiaojiao Liang , Youming Peng , Zhichao Xu , Yufei Wang , Menglong Liu , Xin Liu , Di Huang , Yuehua Wei , Zengxi Wei . Boron/phosphorus co-doped nitrogen-rich carbon nanofiber with flexible anode for robust sodium-ion battery. Chinese Chemical Letters, 2025, 36(1): 110452-. doi: 10.1016/j.cclet.2024.110452
6. [6]
  Yan-Jiang Li , Shu-Lei Chou , Yao Xiao . Detecting dynamic structural evolution based on in-situ high-energy X-ray diffraction technology for sodium layered oxide cathodes. Chinese Chemical Letters, 2025, 36(2): 110389-. doi: 10.1016/j.cclet.2024.110389
7. [7]
  Jun Dong , Senyuan Tan , Sunbin Yang , Yalong Jiang , Ruxing Wang , Jian Ao , Zilun Chen , Chaohai Zhang , Qinyou An , Xiaoxing Zhang . Spatial confinement of free-standing graphene sponge enables excellent stability of conversion-type Fe₂O₃ anode for sodium storage. Chinese Chemical Letters, 2025, 36(3): 110010-. doi: 10.1016/j.cclet.2024.110010
8. [8]
  Guangchang Yang , Shenglong Yang , Jinlian Yu , Yishun Xie , Chunlei Tan , Feiyan Lai , Qianqian Jin , Hongqiang Wang , Xiaohui Zhang . Regulating local chemical environment in O3-type layered sodium oxides by dual-site Mg²⁺/B³⁺ substitution achieves durable and high-rate cathode. Chinese Chemical Letters, 2024, 35(9): 109722-. doi: 10.1016/j.cclet.2024.109722
9. [9]
  Xuan Wang , Peng Sun , Siteng Yuan , Lu Yue , Yufeng Zhao . P2-type low-cost and moisture-stable cathode for sodium-ion batteries. Chinese Chemical Letters, 2025, 36(5): 110015-. doi: 10.1016/j.cclet.2024.110015
10. [10]
  Shimei Wu , Yining Li , Lantao Chen , Yufei Zhang , Lingxing Zeng , Haosen Fan . Hexapod cobalt phosphosulfide nanorods encapsulating into multiple hetero-atom doped carbon frameworks for advanced sodium/potassium ion battery anodes. Chinese Chemical Letters, 2025, 36(4): 109796-. doi: 10.1016/j.cclet.2024.109796
11. [11]
  Mingxin Song , Lijing Xie , Fangyuan Su , Zonglin Yi , Quangui Guo , Cheng-Meng Chen . New insights into the effect of hard carbons microstructure on the diffusion of sodium ions into closed pores. Chinese Chemical Letters, 2024, 35(6): 109266-. doi: 10.1016/j.cclet.2023.109266
12. [12]
  Shengyu Zhao , Xuan Yu , Yufeng Zhao . A water-stable high-voltage P3-type cathode for sodium-ion batteries. Chinese Chemical Letters, 2024, 35(9): 109933-. doi: 10.1016/j.cclet.2024.109933
13. [13]
  Fan Wu , Shaoyang Wu , Xin Ye , Yurong Ren , Peng Wei . Research progress of high-entropy cathode materials for sodium-ion batteries. Chinese Chemical Letters, 2025, 36(4): 109851-. doi: 10.1016/j.cclet.2024.109851
14. [14]
  Jianbao Mei , Bei Li , Shu Zhang , Dongdong Xiao , Pu Hu , Geng Zhang . Enhanced Performance of Ternary NASICON-Type Na_3.5-xMn_0.5V_1.5-xZr_x(PO₄)₃/C Cathodes for Sodium-Ion Batteries. Acta Physico-Chimica Sinica, 2024, 40(12): 2407023-. doi: 10.3866/PKU.WHXB202407023
15. [15]
  Tao Long , Peng Chen , Bin Feng , Caili Yang , Kairong Wang , Yulei Wang , Can Chen , Yaping Wang , Ruotong Li , Meng Wu , Minhuan Lan , Wei Kong Pang , Jian-Fang Wu , Yuan-Li Ding . Reinforced concrete-like Na_3.5V_1.5Mn_0.5(PO₄)₃@graphene hybrids with hierarchical porosity as durable and high-rate sodium-ion battery cathode. Chinese Chemical Letters, 2024, 35(4): 109267-. doi: 10.1016/j.cclet.2023.109267
16. [16]
  Shengyu Zhao , Qinhao Shi , Wuliang Feng , Yang Liu , Xinxin Yang , Xingli Zou , Xionggang Lu , Yufeng Zhao . Suppression of multistep phase transitions of O3-type cathode for sodium-ion batteries. Chinese Chemical Letters, 2024, 35(5): 108606-. doi: 10.1016/j.cclet.2023.108606
17. [17]
  Fanjun Kong , Yixin Ge , Shi Tao , Zhengqiu Yuan , Chen Lu , Zhida Han , Lianghao Yu , Bin Qian . Engineering and understanding SnS_0.5Se_0.5@N/S/Se triple-doped carbon nanofibers for enhanced sodium-ion batteries. Chinese Chemical Letters, 2024, 35(4): 108552-. doi: 10.1016/j.cclet.2023.108552
18. [18]
  Haiying Lu , Weijie Li . The electrolyte solvation and interfacial chemistry for anode-free sodium metal batteries. Chinese Journal of Structural Chemistry, 2024, 43(11): 100334-100334. doi: 10.1016/j.cjsc.2024.100334
19. [19]
  Mianying Huang , Zhiguang Xu , Xiaoming Lin . Mechanistic analysis of Co2VO4/X (X = Ni, C) heterostructures as anode materials of lithium-ion batteries. Chinese Journal of Structural Chemistry, 2024, 43(7): 100309-100309. doi: 10.1016/j.cjsc.2024.100309
20. [20]
  Xinpin Pan , Yongjian Cui , Zhe Wang , Bowen Li , Hailong Wang , Jian Hao , Feng Li , Jing Li . Robust chemo-mechanical stability of additives-free SiO₂ anode realized by honeycomb nanolattice for high performance Li-ion batteries. Chinese Chemical Letters, 2024, 35(10): 109567-. doi: 10.1016/j.cclet.2024.109567

Get Citation

PDF

XML

Metrics

PDF Downloads(21)
Abstract views(740)
HTML views(123)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

SbPS4: A novel anode for high-performance sodium-ion batteries

Metrics

通讯作者: 陈斌, bchen63@163.com

SbPS₄: A novel anode for high-performance sodium-ion batteries