Citation: Miao Yang, Zhonghui Sun, Ping Nie, Haiyue Yu, Chende Zhao, Mengxuan Yu, Zhongzhen Luo, Hongbo Geng, Xinglong Wu. SbPS₄: A novel anode for high-performance sodium-ion batteries[J]. Chinese Chemical Letters, ;2022, 33(1): 470-474. doi: 10.1016/j.cclet.2021.06.065 shu

SbPS₄: A novel anode for high-performance sodium-ion batteries

Miao Yang ^{a, b, 1} ,
Zhonghui Sun ^{c, 1} ,
Ping Nie ^d ,
Haiyue Yu ^b ,
Chende Zhao ^b ,
Mengxuan Yu ^b ,
Zhongzhen Luo ^{e, *,} ,
Hongbo Geng ^{a, *,} ,
Xinglong Wu ^{b, f, **,}

a.
School of Materials Engineering, Changshu Institute of Technology, Changshu 215500, China
b.
Faculty of Chemistry, Northeast Normal University, Changchun 130024, China
c.
Center for Advanced Analytical Science, School of Chemistry and Chemical Engineering, Guangzhou University, Guangzhou 510006, China
d.
Key Laboratory of Preparation and Application of Environmental Friendly Materials (Jilin Normal University), Ministry of Education, Changchun 130103, China
e.
Key Laboratory of Eco-materials Advanced Technology, College of Materials Science and Engineering, Fuzhou University, Fuzhou 350108, China
f.
Key Laboratory for UV Light-Emitting Materials and Technology, Northeast Normal University, Ministry of Education, Changchun 130024, China

^**

zzluo@fzu.edu.cn

hbgeng@cslg.edu.cn

xinglong@nenu.edu.cn

Received Date: 1 June 2021
Revised Date: 13 June 2021
Accepted Date: 23 June 2021
Available Online: 30 June 2021

Figures(8)

With the in-depth research of sodium-ion batteries (SIBs), the development of novel sodium-ion anode material has become a top priority. In this work, tube cluster-shaped SbPS₄ was synthesized by a high-temperature solid phase reaction. Then the typical short tubular ternary thiophosphate SbPS₄ compounded with graphene oxide (SbPS₄/GO) was successfully synthesized after ultrasonication and freeze-drying. SbPS₄ shows a high theoretical specific capacity (1335 mAh/g) according to the conversion-alloying dual mechanisms. The unique short tube inserted in the spongy graphene structure of SbPS₄/GO results in boosting the Na ions transport and alleviating the huge volume change in the charging and discharging processes, improving the sodium storage performance. Consequently, the tubular SbPS₄ compounded with 10% GO provides an outstanding capacity of 359.58 mAh/g at 500 mA/g. The result indicates that SbPS₄/GO anode has a promising application potential for SIBs.
- Sodium-ion batteries,
- High-capacity anode,
- Thiophosphate,
- SbPS₄/GO,
- Full cell
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沈阳化工大学材料科学与工程学院沈阳 110142

SbPS4: A novel anode for high-performance sodium-ion batteries

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通讯作者: 陈斌, bchen63@163.com

SbPS₄: A novel anode for high-performance sodium-ion batteries