Citation: Yu Hu, Cheng Tang, Haitao Li, Aijun Du, Wei Luo, Minghong Wu, Haijiao Zhang. B-incorporated, N-doped hierarchically porous carbon nanosheets as anodes for boosted potassium storage capability[J]. Chinese Chemical Letters, ;2022, 33(1): 480-485. doi: 10.1016/j.cclet.2021.06.063 shu

B-incorporated, N-doped hierarchically porous carbon nanosheets as anodes for boosted potassium storage capability

Yu Hu ^a ,
Cheng Tang ^b ,
Haitao Li ^a ,
Aijun Du ^b ,
Wei Luo ^{d, *,} ,
Minghong Wu ^c ,
Haijiao Zhang ^{a, *,}

a.
Institute of Nanochemistry and Nanobiology, Shanghai University, Shanghai 200444, China
b.
School of Chemistry, Physics and Mechanical Engineering, Science and Engineering Faculty, Queensland University of Technology, Brisbane QLD 4001, Australia
c.
School of Environmental and Chemical Engineering, Shanghai University, Shanghai 200444, China
d.
State Key Laboratory for Modification of Chemical Fibers and Polymer Materials, College of Materials Science and Engineering, Donghua University, Shanghai 201620, China

wluo@dhu.edu.cn

hjzhang128@shu.edu.cn

Received Date: 17 May 2021
Revised Date: 11 June 2021
Accepted Date: 23 June 2021
Available Online: 29 June 2021

Figures(5)

Carbonaceous nanomaterials with porous structure have become the highly promising anode materials for potassium-ion batteries (PIBs) due to their abundant resources, low-cost, and excellent conductivity. Nevertheless, the sluggish reaction kinetics and inferior cycling life caused by the large radius of K ions severely restrict their commercial development. Herein, B,N co-doped hierarchically porous carbon nanosheets (BNPC) are achieved via a facile template-assisted route, followed by a simple one-step carbonization process. The resultant BNPC possesses a unique porous structure, large surface area, and high-level B,N co-doping. The structural features endows it with remarkable potassium storage performances, which delivers a high reversible capacity (242.2 mAh/g at 100 mA/g after 100 cycles), and long cycling stability (123.1 mAh/g at 2000 mA/g and 62.9 mAh/g at 5000 mA/g after 2000 cycles, respectively). Theoretical simulations further validate that the rich B doping into N-modified carbon configuration can greatly boost the potassium storage capability of the BNPC anode.
- Carbon nanosheets,
- Hierarchical nanostructure,
- B,N co-doping,
- Anode materials,
- Potassium-ion batteries
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