Citation: Guanxin Zhu, Zheng-Chao Duan, Haiyan Zhu, Dongdong Ye, Dawei Wang. Selective C-C bonds formation, N-alkylation and benzo[d]imidazoles synthesis by a recyclable zinc composite[J]. Chinese Chemical Letters, ;2022, 33(1): 266-270. doi: 10.1016/j.cclet.2021.06.060 shu

Selective C-C bonds formation, N-alkylation and benzo[d]imidazoles synthesis by a recyclable zinc composite

Guanxin Zhu ^{a, b} ,
Zheng-Chao Duan ^{a, c} ,
Haiyan Zhu ^a ,
Dongdong Ye ^a ,
Dawei Wang ^{a, b, *}

a.
The Key Laboratory of Synthetic and Biological Colloids, Ministry of Education, School of Chemical and Material Engineering, Jiangnan University, Wuxi 214122, China
b.
State Key Laboratory of Pulp and Paper Engineering, South China University of Technology, Guangzhou 510640, China
c.
School of Chemical and Environmental Engineering, Hubei Minzu University, Enshi 445000, China

angdw@jiangnan.edu.cn

Received Date: 15 March 2021
Revised Date: 20 June 2021
Accepted Date: 23 June 2021
Available Online: 2 July 2021

Figures(12)

Earth abundant metals are much less expensive, promising, valuable metals and could be served as catalysts for the borrowing hydrogen reaction, dehydrogenation and heterocycles synthesis, instead of noble metals. The uniformly dispersed zinc composites were designed, synthesized and carefully characterized by means of XPS, EDS, TEM and XRD. The resulting zinc composite showed good catalytic activity for the N-alkylation of amines with amines, ketones with alcohols in water under base-free conditions, while unsaturated carbonyl compounds could also be synthesized by tuning the reaction conditions. Importantly, it was the first time to realize the synthesis of 2-aryl-1H-benzo[d]imidazole derivatives by using this zinc composite under green conditions. Meanwhile, this zinc catalyst could be easily recovered and reused for at least five times.
- Unsymmetrical,
- Zinc,
- Borrowing hydrogen,
- Recyclability,
- Selective
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