Citation: Linhong Shi, Xue Zou, Tengfei Wang, Dongmei Wang, Meikun Fan, Zhengjun Gong. Sunlight photocatalytic degradation of ofloxacin using UiO-66/wood composite photocatalysts[J]. Chinese Chemical Letters, ;2022, 33(1): 442-446. doi: 10.1016/j.cclet.2021.06.048 shu

Sunlight photocatalytic degradation of ofloxacin using UiO-66/wood composite photocatalysts

Linhong Shi ^a ,
Xue Zou ^a ,
Tengfei Wang ^a ,
Dongmei Wang ^a ,
Meikun Fan ^{a, b} ,
Zhengjun Gong ^{a, b, *,}

a.
Faculty of Geosciences and Environmental Engineering, Southwest Jiaotong University, Chengdu 611756, China
b.
State-province Joint Engineering Laboratory of Spatial Information Technology of High-Speed Rail Safety, Chengdu 611756, China

gzj@home.swjtu.edu.cn

Received Date: 9 February 2021
Revised Date: 1 May 2021
Accepted Date: 16 June 2021
Available Online: 24 June 2021

Figures(4)

This study synthesized UiO-66 (Zr) in situ on wood via a one-step solvothermal method. UiO-66/wood was successfully prepared and its catalytic performance for the ofloxacin (OFX) photodegradation under simulate sunlight was also explored. UiO-66/wood exhibited a better catalytic performance, and its degradation rate constant was about 1.2 and 1.5 times than that of UiO-66 and wood, respectively. The effects of solution initial concentration, pH of the system and dosage of the photocatalyst were explored. Additionally, the active species trapping experiments and UV–vis diffused reflectance spectra measurements were conducted to investigated the photocatalytic mechanism of the UiO-66/wood composite, superoxide radical (O₂^•–) and hydroxyl radical (^•OH) were the main reactive species. In addition, the possible degradation pathways of OFX were analyzed by LC-MS. Meanwhile, the UiO-66/wood showed outstanding stability and reusability after 4 cycles experiments. The removal performance of UiO-66/wood towards real samples showed it has potential in actual application.
- Photocatalytic degradation,
- Metal-organic frameworks,
- Ofloxacin,
- Antibiotic,
- Water pollution
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