Citation: Dan Wang, Zhaofan Yang, Feng Liu, Chengyi Xiao, Yonggang Wu, Weiwei Li. A benzo[ghi]-perylene triimide based double-cable conjugated polymer for single-component organic solar cells[J]. Chinese Chemical Letters, ;2022, 33(1): 466-469. doi: 10.1016/j.cclet.2021.06.042 shu

A benzo[ghi]-perylene triimide based double-cable conjugated polymer for single-component organic solar cells

Dan Wang ^{a, b, 1} ,
Zhaofan Yang ^{b, 1} ,
Feng Liu ^{a, c, *,} ,
Chengyi Xiao ^b ,
Yonggang Wu ^{a, *,} ,
Weiwei Li ^{b, *,}

a.
College of Chemistry and Environmental Science, Hebei University, Baoding 071002, China
b.
Beijing Advanced Innovation Center for Soft Matter Science and Engineering & State Key Laboratory of Organic-Inorganic Composites, Beijing University of Chemical Technology, Beijing 100029, China
c.
College of Basic Medicine, Hebei University, Baoding 071002, China

liufeng@hbu.edu.cn

wuyonggang@hbu.edu.cn

liweiwei@iccas.ac.cn

Received Date: 12 May 2021
Revised Date: 31 May 2021
Accepted Date: 15 June 2021
Available Online: 25 June 2021

Figures(3)

Single-component organic solar cells (SCOSCs) with high stability and simplified fabrication process are supposed to accelerate the commercialization of organic photovoltaics. However, the types of photo-active materials and photovoltaic performance of SCOSCs are still far lagging behind the bulk-heterojunction type organic solar cells (BHJ OSCs). It is still an arduous task to introduce new photo-active materials into SCOSCs, aiming to improve the efficiencies of SCOSCs. One feasible way is to construct double-cable polymers with new structures and tune conformation, morphology and mobility for the improvement in power conversion efficiencies (PCEs). Hence, in this work, we constructed a new double-cable polymer PBTT-BPTI by introducing fused core 5,7-dibromo-2,3-bis(2-ethylhexyl)benzo[1,2-b:4,5-c']dithiophene-4,8-dione (TTDO) into the main backbone and benzo[ghi]-perylene triimide (BPTI) unit into the side chain. Both of the two units show strong electron-withdrawing property, which are expected to broaden absorption spectra and enhance intermolecular interaction. The double-cable polymer exhibited a broad absorption in the range of 300-700 nm with an optical band gap (E_g) of 1.79 eV. The PCE of PBTT-BPTI-based SCOSCs was 2.15%, which may be limited by the unconstructed efficient electron transporting channels.
- Double-cable polymer,
- Single-component organic solar cells,
- BPTI,
- Electron withdrawing,
- Electron transporting channels
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