Citation: Wenying Mi, Na Shao. Orange-emitting bimetallic nanoclusters combined with cyan-emitting Fe@TAOH as white light-emitting materials[J]. Chinese Chemical Letters, ;2022, 33(1): 298-303. doi: 10.1016/j.cclet.2021.06.039 shu

Orange-emitting bimetallic nanoclusters combined with cyan-emitting Fe@TAOH as white light-emitting materials

Wenying Mi ,
Na Shao ^*,

College of Chemistry, Beijing Normal University, Beijing 100875, China

shaona@bnu.edu.cn

Received Date: 6 March 2021
Revised Date: 6 April 2021
Accepted Date: 14 June 2021
Available Online: 25 June 2021

Figures(9)

White-light-emitting diodes (WLEDs) possess many merits, such as high efficiency and stability. Developing cost-effective, environmentally friendly, high-performance luminophores to achieve high-quality, full-spectrum, white lighting is of great importance to the construction and progress of WLEDs. In this work, solid-state, highly luminescent orange-emitting nanoclusters (MgCl₂-Lys-Ag/Au NCs) were prepared via the salt-induced precipitation of Lys-Ag/Au NCs from solution, which showed a high absolute quantum yield of 44.5%. A cyan-emitting metal-organic framework (MOF)-like nanomaterial (named Fe@TAOH) was also prepared by the self-assembly of the coordination compound of Fe³⁺ and TAOH acted upon by H₃PO₄ via H-bonding and π-π stacking interactions, which showed an emission peak at 485 nm and an absolute quantum yield of 21.7%. The potential application of the two facile-synthesis, low toxicity, and highly luminescent materials in WLEDs was investigated. The WLEDs was constructed by coating powdered Fe@TAOH and MgCl₂-Lys-Ag/Au NCs samples on commercial GaN LED chip with 365 nm emissions, and it exhibited acceptable white light characteristics with a CIE color coordinates and a color rendering index (CRI) of (0.28, 0.34) and 79.6, respectively, implying good prospects in the field of WLEDs.
- Metal nanoclusters,
- Salt-mediated precipitation,
- Fe@TAOH MOFs,
- Self-assembly,
- White light-emitting materials
1. [1]
  V. Fernández-Luna, P.B. Coto, R.D. Costa, Angew. Chem. Int. Ed.57 (2018) 8826–8836. doi: 10.1002/anie.201711433
2. [2]
  J. Cho, J.H. Park, J.K. Kim, E.F. Schubert, Laser Photonics Rev. 11 (2017) 1600147. doi: 10.1002/lpor.201600147
3. [3]
  H. Ji, L. Wang, Y. Cho, et al., J. Mater. Chem. C4 (2016) 9872–9878. doi: 10.1039/C6TC03422E
4. [4]
  X. Huang, H. Guo, L. Sun, T. Sakthivel, Y. Wu, J. Alloy. Compd. 787 (2019) 865–871. doi: 10.1016/j.jallcom.2019.02.095
5. [5]
  S. Wu, P. Xiong, X. Liu, et al., J. Mater. Chem. C8 (2020) 16584–16592. doi: 10.1039/d0tc04148c
6. [6]
  Z. Wang, Q. Meng, C. Wang, D. Fan, Y. Wang, J. Mater. Chem. C8 (2020) 14548–14558. doi: 10.1039/d0tc04098c
7. [7]
  J. Liang, B. Devakumar, L. Sun, et al., J. Mater. Chem. C8 (2020) 4934–4943. doi: 10.1039/d0tc00006j
8. [8]
  D. Liu, X. Yun, G. Li, et al., Adv. Opt. Mater. 8 (2020) 2001037. doi: 10.1002/adom.202001037
9. [9]
  L. Sun, B. Devakumar, J. Liang, et al., J. Mater. Chem. C8 (2020) 1095–1103. doi: 10.1039/c9tc04952e
10. [10]
  R.S. Yadav, Monika, S.B. Rai, S.J. Dhoble, Prog. Solid State Chem. 57 (2020) 100267. doi: 10.1016/j.progsolidstchem.2019.100267
11. [11]
  H. Zhang, H. Zhang, A. Pan, et al., Adv. Mater. Technol. 6 (2020) 2000648.
12. [12]
  T. Zhang, Y. Liu, B. Hu, et al., Chin. Chem. Lett. 30 (2019) 949–952. doi: 10.1016/j.cclet.2018.12.029
13. [13]
  Z.Z. Ma, Z.F. Shi, L.T. Wang, et al., Nanoscale12 (2020) 3637–3645. doi: 10.1039/c9nr10075j
14. [14]
  L. Su, X. Zhang, Y. Zhang, A.L. Rogach, Top. Curr. Chem. 374 (2016) 42. doi: 10.1007/s41061-016-0041-3
15. [15]
  Z. Wang, B. Chen, A.S. Susha, et al., Adv. Sci. 3 (2016) 1600182. doi: 10.1002/advs.201600182
16. [16]
  Z. Wang, A.S. Susha, B. Chen, et al., Nanoscale8 (2016) 7197–7202. doi: 10.1039/C6NR00806B
17. [17]
  P.S. Kuttipillai, Y. Zhao, C.J. Traverse, et al., Adv. Mater. 28 (2016) 320–326. doi: 10.1002/adma.201504548
18. [18]
  Z. Yin, Z. Wang, X. Dai, et al., ACS Sustain. Chem. Eng. 8 (2020) 15336–15343. doi: 10.1021/acssuschemeng.0c05722
19. [19]
  A. Aires, V. Fernandez-Luna, J. Fernandez-Cestau, R.D. Costa, A.L. Cortajarena, Nano Lett. 20 (2020) 2710–2716. doi: 10.1021/acs.nanolett.0c00324
20. [20]
  P. Sun, Z. Wang, Y. Bi, et al., ACS Appl. Nano Mater. 3 (2020) 2038–2046. doi: 10.1021/acsanm.0c00135
21. [21]
  H.H. Deng, Q.Q. Zhuang, K.Y. Huang, et al., Nanoscale12 (2020) 15791–15799. doi: 10.1039/d0nr03640d
22. [22]
  Z. Lionet, T.H. Kim, Y. Horiuchi, S.W. Lee, M. Matsuoka, J. Phys. Chem. C123 (2019) 27501–27508. doi: 10.1021/acs.jpcc.9b06838
23. [23]
  Y. Liu, P. Gao, C. Huang, Y. Li, Sci. China Chem. 58 (2015) 1553–1560. doi: 10.1007/s11426-015-5406-x
24. [24]
  Y. Nakabayashi, Y. Nosaka, Phys. Chem. Chem. Phys. 17 (2015) 30570–30576. doi: 10.1039/C5CP04531B
25. [25]
  Y. Wu, Y. Gao, J. Du, Talanta197 (2019) 599–604. doi: 10.1016/j.talanta.2019.01.087
26. [26]
  Y. Jiang, Y. Zhu, Y. Zheng, et al., Food Chem. 338 (2021) 128158. doi: 10.1016/j.foodchem.2020.128158
27. [27]
  K.C. Duong-Ly, S.B. Gabelli, Methods Enzymol. 541 (2014) 85–94.
28. [28]
  A. Baksi, P.L. Xavier, K. Chaudhari, et al., Nanoscale5 (2013) 2009–2016. doi: 10.1039/c2nr33180b
29. [29]
  Z. Wu, J. Liu, Y. Gao, et al., J. Am. Chem. Soc. 137 (2015) 12906–12913. doi: 10.1021/jacs.5b06550
30. [30]
  H.Y. Huang, K.B. Cai, M.J. Talite, et al., Sci. Rep. 9 (2019) 4053. doi: 10.1038/s41598-019-40706-3
31. [31]
  T.D. Bennett, A.K. Cheetham, Acc. Chem. Res. 47 (2014) 1555–1562. doi: 10.1021/ar5000314
32. [32]
  P. Sun, Z. Wang, D. Sun, et al., J. Colloid Interface Sci. 567 (2020) 235–242. doi: 10.1016/j.jcis.2020.02.016
33. [33]
  Z. Zhao, D. Yang, H. Ren, et al., Chem. Eng. J. 400 (2020) 125929. doi: 10.1016/j.cej.2020.125929
34. [34]
  M. Mohammad, M. Lisiecki, K. Liang, A. Razmjou, V. Chen, Appl. Mater. Today21 (2020) 100884. doi: 10.1016/j.apmt.2020.100884
1. [1]
  Yuanpeng Ye , Longfei Yao , Guofeng Liu . Engineering circularly polarized luminescence through symmetry manipulation in achiral tetraphenylpyrazine structures. Chinese Journal of Structural Chemistry, 2025, 44(2): 100460-100460. doi: 10.1016/j.cjsc.2024.100460
2. [2]
  Sifan Du , Yuan Wang , Fulin Wang , Tianyu Wang , Li Zhang , Minghua Liu . Evolution of hollow nanosphere to microtube in the self-assembly of chiral dansyl derivatives and inversed circularly polarized luminescence. Chinese Chemical Letters, 2024, 35(7): 109256-. doi: 10.1016/j.cclet.2023.109256
3. [3]
  Xuanyu Wang , Zhao Gao , Wei Tian . Supramolecular confinement effect enabling light-harvesting system for photocatalytic α-oxyamination reaction. Chinese Chemical Letters, 2024, 35(11): 109757-. doi: 10.1016/j.cclet.2024.109757
4. [4]
  Yuwen Zhu , Xiang Deng , Yan Wu , Baode Shen , Lingyu Hang , Yuye Xue , Hailong Yuan . Formation mechanism of herpetrione self-assembled nanoparticles based on pH-driven method. Chinese Chemical Letters, 2025, 36(1): 109733-. doi: 10.1016/j.cclet.2024.109733
5. [5]
  Jingqi Xin , Shupeng Han , Meichen Zheng , Chenfeng Xu , Zhongxi Huang , Bin Wang , Changmin Yu , Feifei An , Yu Ren . A nitroreductase-responsive nanoprobe with homogeneous composition and high loading for preoperative non-invasive tumor imaging and intraoperative guidance. Chinese Chemical Letters, 2024, 35(7): 109165-. doi: 10.1016/j.cclet.2023.109165
6. [6]
  Keyang Li , Yanan Wang , Yatao Xu , Guohua Shi , Sixian Wei , Xue Zhang , Baomei Zhang , Qiang Jia , Huanhua Xu , Liangmin Yu , Jun Wu , Zhiyu He . Flash nanocomplexation (FNC): A new microvolume mixing method for nanomedicine formulation. Chinese Chemical Letters, 2024, 35(10): 109511-. doi: 10.1016/j.cclet.2024.109511
7. [7]
  Xian Yan , Huawei Xie , Gao Wu , Fang-Xing Xiao . Boosted solar water oxidation steered by atomically precise alloy nanocluster. Chinese Chemical Letters, 2025, 36(1): 110279-. doi: 10.1016/j.cclet.2024.110279
8. [8]
  Feng Cao , Chunxiang Xian , Tianqi Yang , Yue Zhang , Haifeng Chen , Xinping He , Xukun Qian , Shenghui Shen , Yang Xia , Wenkui Zhang , Xinhui Xia . Gelation-pyrolysis strategy for fabrication of advanced carbon/sulfur cathodes for lithium-sulfur batteries. Chinese Chemical Letters, 2025, 36(3): 110575-. doi: 10.1016/j.cclet.2024.110575
9. [9]
  Fengying Ye , Ming Hu , Jun Luo , Wei Yu , Zhirong Xu , Jinjin Fu , Yansong Zheng . Significantly boosting circularly polarized luminescence by synergy of helical and planar chirality. Chinese Chemical Letters, 2025, 36(5): 110724-. doi: 10.1016/j.cclet.2024.110724
10. [10]
  Xiangan Song , Shaogang Shen , Mengyao Lu , Ying Wang , Yong Zhang . Trifluoromethyl enable high-performance single-emitter white organic light-emitting devices based on quinazoline acceptor. Chinese Chemical Letters, 2024, 35(4): 109118-. doi: 10.1016/j.cclet.2023.109118
11. [11]
  Zhenzhu Wang , Chenglong Liu , Yunpeng Ge , Wencan Li , Chenyang Zhang , Bing Yang , Shizhong Mao , Zeyuan Dong . Differentiated self-assembly through orthogonal noncovalent interactions towards the synthesis of two-dimensional woven supramolecular polymers. Chinese Chemical Letters, 2024, 35(5): 109127-. doi: 10.1016/j.cclet.2023.109127
12. [12]
  Cheng-Yan Wu , Yi-Nan Gao , Zi-Han Zhang , Rui Liu , Quan Tang , Zhong-Lin Lu . Enhancing self-assembly efficiency of macrocyclic compound into nanotubes by introducing double peptide linkages. Chinese Chemical Letters, 2024, 35(11): 109649-. doi: 10.1016/j.cclet.2024.109649
13. [13]
  Changlin Su , Wensheng Cai , Xueguang Shao . Water as a probe for the temperature-induced self-assembly transition of an amphiphilic copolymer. Chinese Chemical Letters, 2025, 36(4): 110095-. doi: 10.1016/j.cclet.2024.110095
14. [14]
  Xiaofei NIU , Ke WANG , Fengyan SONG , Shuyan YU . Self-assembly of [Pd₆(L)₄]⁸⁺-type macrocyclic complexes for fluorescent sensing of HSO₃^-. Chinese Journal of Inorganic Chemistry, 2024, 40(7): 1233-1242. doi: 10.11862/CJIC.20240057
15. [15]
  Zengchao Guo , Weiwei Liu , Tengfei Liu , Jinpeng Wang , Hui Jiang , Xiaohui Liu , Yossi Weizmann , Xuemei Wang . Engineered exosome hybrid copper nanoscale antibiotics facilitate simultaneous self-assembly imaging and elimination of intracellular multidrug-resistant superbugs. Chinese Chemical Letters, 2024, 35(7): 109060-. doi: 10.1016/j.cclet.2023.109060
16. [16]
  Ruike Hu , Kangmin Wang , Junxiang Liu , Jingxian Zhang , Guoliang Yang , Liqiu Wan , Bijin Li . Extended π-conjugated systems by external ligand-assisted C−H olefination of heterocycles: Facile access to single-molecular white-light-emitting and NIR fluorescence materials. Chinese Chemical Letters, 2025, 36(4): 110113-. doi: 10.1016/j.cclet.2024.110113
17. [17]
  Jin Tong , Shuyan Yu . Crystal Engineering for Supramolecular Chirality. University Chemistry, 2024, 39(3): 86-93. doi: 10.3866/PKU.DXHX202308113
18. [18]
  Ruoxi Sun , Yiqian Xu , Shaoru Rong , Chunmiao Han , Hui Xu . The Enchanting Collision of Light and Time Magic: Exploring the Footprints of Long Afterglow Lifetime. University Chemistry, 2024, 39(5): 90-97. doi: 10.3866/PKU.DXHX202310001
19. [19]
  Changhui Yu , Peng Shang , Huihui Hu , Yuening Zhang , Xujin Qin , Linyu Han , Caihe Liu , Xiaohan Liu , Minghua Liu , Yuan Guo , Zhen Zhang . Evolution of template-assisted two-dimensional porphyrin chiral grating structure by directed self-assembly using chiral second harmonic generation microscopy. Chinese Chemical Letters, 2024, 35(10): 109805-. doi: 10.1016/j.cclet.2024.109805
20. [20]
  Bing Niu , Honggao Huang , Liwei Luo , Li Zhang , Jianbo Tan . Coating colloidal particles with a well-defined polymer layer by surface-initiated photoinduced polymerization-induced self-assembly and the subsequent seeded polymerization. Chinese Chemical Letters, 2025, 36(2): 110431-. doi: 10.1016/j.cclet.2024.110431

Get Citation

PDF

XML

Metrics

PDF Downloads(5)
Abstract views(552)
HTML views(43)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142