Citation: Fangshuai Chen, Yanan Chen, Qing Han, Liangti Qu. One-step synthesis of hierarchical Ni₃Se₂ nanosheet-on-nanorods/Ni foam electrodes for hybrid supercapacitors[J]. Chinese Chemical Letters, ;2022, 33(1): 475-479. doi: 10.1016/j.cclet.2021.06.021 shu

One-step synthesis of hierarchical Ni₃Se₂ nanosheet-on-nanorods/Ni foam electrodes for hybrid supercapacitors

Fangshuai Chen ^a ,
Yanan Chen ^{c, *,} ,
Qing Han ^{a, *,} ,
Liangti Qu ^{b, *,}

a.
Key Laboratory of Cluster Science Ministry of Education of China, Key Laboratory of Photoelectronic/Electrophotonic Conversion Materials, School of Chemistry and Chemical Engineering, Beijing Institute of Technology, Beijing 100081, China
b.
The Key Laboratory of Organic Optoelectronics & Molecular Engineering of Ministry of Education, Department of Chemistry, Tsinghua University, Beijing 100084, China
c.
School of Materials Science and Engineering, Key Laboratory of Advanced Ceramics and Machining Technology of Ministry of Education, Tianjin Key Laboratory of Composite and Functional Materials, Tianjin University, Tianjin 300072, China

yananchen@tju.edu.cn

qhan@bit.edu.cn

lqu@mail.tsinghua.edu.cn

Received Date: 23 March 2021
Revised Date: 17 May 2021
Accepted Date: 9 June 2021
Available Online: 15 June 2021

Figures(4)

Transitional metal selenides have high conductivity, even metal quality, which makes them great for using as electrode materials for fabricating supercapacitors. Here, hierarchical Ni₃Se₂ nanosheet-on-nanorods on Ni foam (NSR-Ni₃Se₂/Ni) was fabricated by a facile three-dimensional (3D) substrate-assisted confinement assembly method, and used as a freestanding electrode material for hybrid supercapacitors (HSCs). In this design, metallic Ni₃Se₂ with hybrid 1D/2D architecture could effectively enhance the active specific surface area of electrode and improve space utilization, as well as significantly facilitate electrons transport, while Ni foam served as the Ni source of Ni₃Se₂ and provided 3D multi-electron transport channels, thus boosting the specific capacity. The constructed hierarchical NSR-Ni₃Se₂ electrode delivered a superior areal specific capacity of 1.068 mAh/cm² (7.69 F/cm²) at 2 mA/cm² and retained 68.2% of the initial capacity when the current density increases by 15 times. Furthermore, the as-assembled NSR-Ni₃Se₂ device exhibited an ultrahigh energy density of 56.4 Wh/kg and high power density of 4640.3 W/kg, and a capacity retention of 92.6% even after 6000 cycles.
- Hybrid supercapacitors,
- Hierarchical Ni₃Se₂ nanosheet-on-nanorods,
- Freestanding electrode,
- Ni foam-assisted confinement assembly,
- Microstructure
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通讯作者: 陈斌, bchen63@163.com

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沈阳化工大学材料科学与工程学院沈阳 110142

One-step synthesis of hierarchical Ni3Se2 nanosheet-on-nanorods/Ni foam electrodes for hybrid supercapacitors

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通讯作者: 陈斌, bchen63@163.com

One-step synthesis of hierarchical Ni₃Se₂ nanosheet-on-nanorods/Ni foam electrodes for hybrid supercapacitors