Citation: Sihan Li, Lili Xie, Guifang Luo, Yutong Han, Ming Zhou, Rawat Jaisutti, Zhigang Zhu. Indium-organic framework CPP-3(In) derived Ag/In₂O₃ porous hexagonal tubes for H₂S detection at low temperature[J]. Chinese Chemical Letters, ;2022, 33(1): 551-556. doi: 10.1016/j.cclet.2021.06.016 shu

Indium-organic framework CPP-3(In) derived Ag/In₂O₃ porous hexagonal tubes for H₂S detection at low temperature

Sihan Li ^{a, b, #} ,
Lili Xie ^{c, #} ,
Guifang Luo ^c ,
Yutong Han ^a ,
Ming Zhou ^c ,
Rawat Jaisutti ^{d, e} ,
Zhigang Zhu ^{a, c, *,}

a.
School of Medical Instrument and Food Engineering, University of Shanghai for Science and Technology, Shanghai 200093, China
b.
Shanghai Normal University Tianhua College, Shanghai 201815, China
c.
School of Environmental and Materials Engineering, College of Engineering, Shanghai Polytechnic University, Shanghai 201209, China
d.
Department of Physics, Faculty of Science and Technology, Thammasat University, Pathumthani 12120, Thailand
e.
Thammasat Research Unit in Innovative Sensor and Nanoelectronic Devices, Thammasat University, Pathumthani 12120, Thailand

zgzhu@usst.edu.cn

Received Date: 28 April 2021
Revised Date: 30 May 2021
Accepted Date: 6 June 2021
Available Online: 11 June 2021

Figures(10)

There is a great demand for high-performance hydrogen sulfide (H₂S) sensors with low operating temperatures. Ag/In₂O₃ hexagonal tubes with different proportions were prepared by the calcination of Ag⁺-impregnated indium-organic frameworks (CPP-3(In)), and the developed sensors exhibit enhanced gas-sensing performance toward H₂S. Gas sensing measurements indicate that the response of Ag/In₂O₃ (2.5 wt%) sensor to 5 ppm H₂S has the highest response (119), operated at 70 ℃. The Ag/In₂O₃ (2.5 wt%) based sensor exhibits short response time (20 s), low detection limit (300 ppb), and good selectivity toward H₂S gas, which imply that the CPP-3(In)-derived Ag/In₂O₃ hexagonal tube is a promising candidate to be constructed a low power-consumption H₂S sensor.
- Ag/In₂O₃,
- Indium-organic framework (CPP-3(In)),
- H₂S,
- Gas sensor,
- Low power consumption
1. [1]
  V. Nagarajam, R. Chandiramouli, J. Inorg. Organomet. Polym. Mater.26 (2016) 394–404. doi: 10.1007/s10904-016-0331-9
2. [2]
  Y.Y. Wang, G.T. Duan, Y.D. Zhu, et al., Sens. Actuat. B: Chem. 228 (2016) 74–84. doi: 10.1007/978-3-319-41827-8_7
3. [3]
  Q.L. Zhu, Q. Xu, Chem. Soc. Rev. 43 (2014) 5468–5512. doi: 10.1039/C3CS60472A
4. [4]
  H. Furukawa, K.E. Cordova, M. O'Keeffe, O.M. Yaghi, Science341 (2013) 1230444. doi: 10.1126/science.1230444
5. [5]
  Y. Sun, Z. Dong, D. Zhang, et al. Sens. Actuat. B: Chem. 326 (2021) 128791. doi: 10.1016/j.snb.2020.128791
6. [6]
  A. Corma, H. Garcia, F. Labres, et al., Chem. Rev. 110 (2010) 4606–4655. doi: 10.1021/cr9003924
7. [7]
  P. Horcajada, R. Gref, T. Baati, et al., Chem. Rev. 112 (2012) 1232–1268. doi: 10.1021/cr200256v
8. [8]
  W. Xia, A. Mahmood, R.Q. Zou, et al., Energy. Environ. Sci. 8 (2015) 1837–1866. doi: 10.1039/C5EE00762C
9. [9]
  B.R. Pimentel, A. Parulkar, E. Zhou, et al., ChemSusChem7 (2014) 3202–3240. doi: 10.1002/cssc.201402647
10. [10]
  Z.J. Zhang, Z.Z. Yao, S.C. Xiang, et al., Energy. Environ. Sci. 7 (2014) 2868–2899. doi: 10.1039/C4EE00143E
11. [11]
  X. Zhang, Y.D. Xu, B.X. Ye, J. Alloy Compd. 767 (2018) 651–656. doi: 10.1016/j.jallcom.2018.07.175
12. [12]
  L.L. Guo, F. Chen, N. Xie, et al., Sens. Actuat. B: Chem. 272 (2018) 185–194. doi: 10.1016/j.snb.2018.05.161
13. [13]
  G.Q. Li, H. Kobayashi, J.M. Taylor, et al., Nat. Mater. 13 (2014) 802–806. doi: 10.1038/nmat4030
14. [14]
  X. Wang, S.H. Li, L.L. Xie, et al., Ceram. Inter. 46 (2020) 15858–15866. doi: 10.1016/j.ceramint.2020.03.133
15. [15]
  Y.V. Kaneti, J. Tang, R.R. Salunkhe, et al., Adv. Mater. 12 (2017) 1604898. doi: 10.1002/adma.201604898
16. [16]
  S. Dang, Q.L. Zhu, Q. Xu. Nat. Rev. Mater. 1 (2017) 17075.
17. [17]
  R.R. Salunkhe, Y.V. Kaneti, Y. Yamauchi. ACS. Nano6 (2017) 5293–5308. doi: 10.1021/acsnano.7b02796
18. [18]
  M.S. Yao, W.X. Tang, G.E. Wang, et al., Adv. Mater. 26 (2016) 5229–5234. doi: 10.1002/adma.201506457
19. [19]
  H. Yu, H.S. Fan, B. Yadian, et al., ACS. Appl. Mater. Inter. 48 (2015) 26751–26757. doi: 10.1021/acsami.5b08741
20. [20]
  Y.T. Wang, Y.Y. Lü, W.W. Zhan, et al., J. Mater. Chem. A24 (2015) 12796–12803. doi: 10.1039/C5TA01108F
21. [21]
  S.H. Li, L.L. Xie, M. He, et al., Sens. Actuat. B: Chem. 310 (2020) 127828. doi: 10.1016/j.snb.2020.127828
22. [22]
  K. Tao, X. Han, Q. Yin, et al., Chem. Select. 2 (2017) 10918–10925. doi: 10.1002/slct.201701752
23. [23]
  W.T. Koo, S. Yu, S.J. Choi, et al., ACS. Appl. Mater. Inter. 9 (2017) 8201–8210. doi: 10.1021/acsami.7b01284
24. [24]
  S.T. Meek, J.A. Greathouse, M.D. Allendorf, Adv Mater. 2 (2011) 249–267. doi: 10.1002/adma.201002854
25. [25]
  J. Lee, O.K. Farha, J. Roberts, et al., Chem. Soc. Rev. 5 (2009) 1450–1459. doi: 10.1039/b807080f
26. [26]
  H. Furukawa, K.E. Cordova, M. O'Keeffe, et al., Science6149 (2013) 1230444.
27. [27]
  X.S. Liang, T.H. Kim, J.W. Yoon, et al., Sens. Actuat. B: Chem. 209 (2015) 934–942. doi: 10.1016/j.snb.2014.11.130
28. [28]
  R. Raji, K.S. Sibi, K.G. Gopchandran, Appl. Surf. Sci. 427 (2018) 863–875. doi: 10.1016/j.apsusc.2017.09.050
29. [29]
  X.B. Hu, Z.G. Zhu, Z.H. Li, et al., Sens. Actuat. B: Chem. 264 (2018) 139–149. doi: 10.1016/j.snb.2018.02.110
30. [30]
  D. Andreeva, T. Tabakova, V. Idakiev, et al., Appl. Catal. A: Gen. 169 (1998) 9–14. doi: 10.1016/S0926-860X(97)00302-5
31. [31]
  M.D. Ding, N. Xie, C. Wang, et al., Sens. Actuat. B: Chem. 252 (2017) 418–427. doi: 10.1016/j.snb.2017.06.016
32. [32]
  T. Fei, H.R. Zhao, K. Jiang, et al., Sens. Actuat. B: Chem. 208 (2015) 277–282. doi: 10.1016/j.snb.2014.11.044
33. [33]
  M. He, L.L. Xie, X.L. Zhao, et al., J. Alloy. Compd. 788 (2019) 36–43. doi: 10.1016/j.jallcom.2019.01.349
34. [34]
  Y.W. Zhang, R. Si, C.S. Liao, et al., J. Phys. Chem. B107 (2003) 10159–10167.
35. [35]
  M. Wu, M. He, Q.K. Hu, et al., ACS. Sens. 4 (2019) 2763–2770. doi: 10.1021/acssensors.9b01308
36. [36]
  X.Y. Huang, Z.T. Chi, J. Liu, et al., Sens. Actuat. B: Chem. 304 (2020) 127305. doi: 10.1016/j.snb.2019.127305
37. [37]
  K.C. Wan, D. Wang, F. Wang, et al., ACS. Appl. Mater. Inter. 11 (2019) 45214–45225. doi: 10.1021/acsami.9b16599
38. [38]
  B.X. Li, Y. Xie, M. Jing, et al., Langmuir. 22 (2006) 9380–9385. doi: 10.1021/la061844k
39. [39]
  S. Zhou, M. Chen, Q. Lu, et al., Nanoscale Res. Lett. 14 (2019), 365. doi: 10.1007/978-3-030-36708-4_30
40. [40]
  Y. Wang, S.R. Wang, Y.Q. Zhao, et al., Sens. Actuat. B: Chem. 125 (2007) 79–84. doi: 10.1016/j.snb.2007.01.037
41. [41]
  M.D. Ding, N. Xie, C. Wang, et al., Sens. Actuat. B: Chem. 252 (2017) 418–427. doi: 10.1016/j.snb.2017.06.016
1. [1]
  Siqi Sun , Cheng Zhao , Zhaohuan Zhang , Ding Wang , Xinru Yin , Jingting Han , Jinlei Wei , Yong Zhao , Yongheng Zhu . Highly selective QCM sensor based on functionalized hierarchical hollow TiO₂ nanospheres for detecting ppb-level 3-hydroxy-2-butanone biomarker at room temperature. Chinese Chemical Letters, 2025, 36(5): 109939-. doi: 10.1016/j.cclet.2024.109939
2. [2]
  Shangqian Zhang , Jiaxuan Li , Xuan Hu , Zelong Chen , Junliang Dong , Chenhao Hu , Shuang Chao , Yinghua Lv , Yuxin Pei , Zhichao Pei . H₂S and NIR light-driven nanomotors induce disulfidptosis for targeted anticancer therapy by enhancing disruption of tumor metabolic symbiosis. Chinese Chemical Letters, 2025, 36(1): 110314-. doi: 10.1016/j.cclet.2024.110314
3. [3]
  Yu Deng , Yan Liu , Yonghui Deng , Jinsheng Cheng , Yidong Zou , Wei Luo . In situ sulfur-doped mesoporous tungsten oxides for gas sensing toward benzene series. Chinese Chemical Letters, 2024, 35(7): 108898-. doi: 10.1016/j.cclet.2023.108898
4. [4]
  Huakang Zong , Xinyue Li , Yanlin Zhang , Faxun Wang , Xingxing Yu , Guotao Duan , Yuanyuan Luo . Pt/Ti₃C₂ electrode material used for H₂S sensor with low detection limit and high stability. Chinese Chemical Letters, 2025, 36(5): 110195-. doi: 10.1016/j.cclet.2024.110195
5. [5]
  Cailiang Yue , Nan Sun , Yixing Qiu , Linlin Zhu , Zhiling Du , Fuqiang Liu . A direct Z-scheme 0D α-Fe₂O₃/TiO₂ heterojunction for enhanced photo-Fenton activity with low H₂O₂ consumption. Chinese Chemical Letters, 2024, 35(12): 109698-. doi: 10.1016/j.cclet.2024.109698
6. [6]
  Ping Lu , Baoyin Du , Ke Liu , Ze Luo , Abiduweili Sikandaier , Lipeng Diao , Jin Sun , Luhua Jiang , Yukun Zhu . Heterostructured In2O3/In2S3 hollow fibers enable efficient visible-light driven photocatalytic hydrogen production and 5-hydroxymethylfurfural oxidation. Chinese Journal of Structural Chemistry, 2024, 43(8): 100361-100361. doi: 10.1016/j.cjsc.2024.100361
7. [7]
  Jia-Mei Qin , Xue Li , Wei Lang , Fu-Hao Zhang , Qian-Yong Cao . An AIEgen nano-assembly for simultaneous detection of ATP and H₂S. Chinese Chemical Letters, 2024, 35(6): 108925-. doi: 10.1016/j.cclet.2023.108925
8. [8]
  Yudi Cheng , Xiao Wang , Jiao Chen , Zihan Zhang , Jiadong Ou , Mengyao She , Fulin Chen , Jianli Li . A near-infrared fluorescent probe for visualizing transformation pathway of Cys/Hcy and H₂S and its applications in living system. Chinese Chemical Letters, 2024, 35(5): 109156-. doi: 10.1016/j.cclet.2023.109156
9. [9]
  Yang Xia , Kangyan Zhang , Heng Yang , Lijuan Shi , Qun Yi . 构建双通道路径增强iCOF/Bi₂O₃ S型异质结在纯水体系中光催化合成H₂O₂性能. Acta Physico-Chimica Sinica, 2024, 40(11): 2407012-. doi: 10.3866/PKU.WHXB202407012
10. [10]
  Bicheng Zhu , Jingsan Xu . S-scheme heterojunction photocatalyst for H2 evolution coupled with organic oxidation. Chinese Journal of Structural Chemistry, 2024, 43(8): 100327-100327. doi: 10.1016/j.cjsc.2024.100327
11. [11]
  Ran Yu , Chen Hu , Ruili Guo , Ruonan Liu , Lixing Xia , Cenyu Yang , Jianglan Shui . 杂多酸H₃PW₁₂O₄₀高效催化MgH₂储氢. Acta Physico-Chimica Sinica, 2025, 41(1): 2308032-. doi: 10.3866/PKU.WHXB202308032
12. [12]
  Huyi Yu , Renshu Huang , Qian Liu , Xingfa Chen , Tianqi Yu , Haiquan Wang , Xincheng Liang , Shibin Yin . Te-doped Fe3O4 flower enabling low overpotential cycling of Li-CO2 batteries at high current density. Chinese Journal of Structural Chemistry, 2024, 43(3): 100253-100253. doi: 10.1016/j.cjsc.2024.100253
13. [13]
  Dong-Xue Jiao , Hui-Li Zhang , Chao He , Si-Yu Chen , Ke Wang , Xiao-Han Zhang , Li Wei , Qi Wei . Layered (C5H6ON)2[Sb2O(C2O4)3] with a large birefringence derived from the uniform arrangement of π-conjugated units. Chinese Journal of Structural Chemistry, 2024, 43(6): 100304-100304. doi: 10.1016/j.cjsc.2024.100304
14. [14]
  Ke-Ai Zhou , Lian Huang , Xing-Ping Fu , Li-Ling Zhang , Yu-Ling Wang , Qing-Yan Liu . Fluorinated metal-organic framework for methane purification from a ternary CH4/C2H6/C3H8 mixture. Chinese Journal of Structural Chemistry, 2023, 42(11): 100172-100172. doi: 10.1016/j.cjsc.2023.100172
15. [15]
  Qingwang LIU . MoS₂/Ag/g-C₃N₄ Z-scheme heterojunction: Preparation and photocatalytic performance. Chinese Journal of Inorganic Chemistry, 2025, 41(4): 821-832. doi: 10.11862/CJIC.20240148
16. [16]
  Hualin Jiang , Wenxi Ye , Huitao Zhen , Xubiao Luo , Vyacheslav Fominski , Long Ye , Pinghua Chen . Novel 3D-on-2D g-C₃N₄/AgI._x._y heterojunction photocatalyst for simultaneous and stoichiometric production of H₂ and H₂O₂ from water splitting under visible light. Chinese Chemical Letters, 2025, 36(2): 109984-. doi: 10.1016/j.cclet.2024.109984
17. [17]
  Tong Zhou , Xue Liu , Liang Zhao , Mingtao Qiao , Wanying Lei . Efficient Photocatalytic H₂O₂ Production and Cr(VI) Reduction over a Hierarchical Ti₃C₂/In₄SnS₈ Schottky Junction. Acta Physico-Chimica Sinica, 2024, 40(10): 2309020-. doi: 10.3866/PKU.WHXB202309020
18. [18]
  Jing Wang , Zhongliao Wang , Jinfeng Zhang , Kai Dai . Single-layer crystalline triazine-based organic framework photocatalysts with different linking groups for H2O2 production. Chinese Journal of Structural Chemistry, 2023, 42(12): 100202-100202. doi: 10.1016/j.cjsc.2023.100202
19. [19]
  Xinyu Yin , Haiyang Shi , Yu Wang , Xuefei Wang , Ping Wang , Huogen Yu . Spontaneously Improved Adsorption of H₂O and Its Intermediates on Electron-Deficient Mn^(3+δ)+ for Efficient Photocatalytic H₂O₂ Production. Acta Physico-Chimica Sinica, 2024, 40(10): 2312007-. doi: 10.3866/PKU.WHXB202312007
20. [20]
  Min WANG , Dehua XIN , Yaning SHI , Wenyao ZHU , Yuanqun ZHANG , Wei ZHANG . Construction and full-spectrum catalytic performance of multilevel Ag/Bi/nitrogen vacancy g-C₃N₄/Ti₃C₂T_x Schottky junction. Chinese Journal of Inorganic Chemistry, 2024, 40(6): 1123-1134. doi: 10.11862/CJIC.20230477

Get Citation

PDF

XML

Metrics

PDF Downloads(3)
Abstract views(686)
HTML views(45)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142

Indium-organic framework CPP-3(In) derived Ag/In2O3 porous hexagonal tubes for H2S detection at low temperature

Metrics

通讯作者: 陈斌, bchen63@163.com

Indium-organic framework CPP-3(In) derived Ag/In₂O₃ porous hexagonal tubes for H₂S detection at low temperature