Citation: Yuheng Zhang, Kang Ren, Lu Wang, Lin Wang, Zhuangjun Fan. Porphyrin-based heterogeneous photocatalysts for solar energy conversion[J]. Chinese Chemical Letters, ;2022, 33(1): 33-60. doi: 10.1016/j.cclet.2021.06.013 shu

Porphyrin-based heterogeneous photocatalysts for solar energy conversion

State Key Laboratory of Heavy Oil Processing, School of Materials Science and Engineering, China University of Petroleum (East China), Qingdao 266580, China

linwang@upc.edu.cn

fanzhj666@163.com

Received Date: 21 February 2021
Revised Date: 19 April 2021
Accepted Date: 6 June 2021
Available Online: 12 June 2021

Figures(16)

In recent years, porphyrins with a similar structure to chlorophyll are often used as photosensitizers or reaction centers to improve the light absorption capacity or catalytic selectivity of existing photocatalytic systems. However, photocatalytic reactions include photoelectric conversion, photocarrier transport, and surface reaction, which requires the overall design of porphyrin-based photocatalysts. In this paper, the research work of porphyrin molecular design in heterogeneous photocatalysis in recent years is reviewed. Besides, the application of interface control and spatial confinement effect in porphyrin-based hybrid photocatalyst is introduced. Finally, the future development direction of porphyrin-based photocatalysts is prospected and the main challenges in the research of porphyrin-based photocatalysts are given.
- Porphyrin,
- Photocatalyst,
- Molecular design,
- Interface engineering,
- Organic framework
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