Citation: Linhui Wu, Shuli Yao, Hui Xu, Tengfei Zheng, Suijun Liu, Jinglin Chen, Na Li, Herui Wen. Highly selective and turn-on fluorescence probe with red shift emission for naked-eye detecting Al³⁺ and Ga³⁺ based on metal-organic framework[J]. Chinese Chemical Letters, ;2022, 33(1): 541-546. doi: 10.1016/j.cclet.2021.06.009 shu

Highly selective and turn-on fluorescence probe with red shift emission for naked-eye detecting Al³⁺ and Ga³⁺ based on metal-organic framework

Linhui Wu ^a ,
Shuli Yao ^a ,
Hui Xu ^a ,
Tengfei Zheng ^a ,
Suijun Liu ^{a, *,} ,
Jinglin Chen ^a ,
Na Li ^{b, *,} ,
Herui Wen ^a

a.
School of Chemistry and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China
b.
School of Materials Science and Engineering, Tianjin Key Laboratory of Metal and Molecule-Based Material Chemistry, Nankai University, Tianjin 300350, China

sjliu@jxust.edu.cn

lina@nankai.edu.cn

Received Date: 29 April 2021
Revised Date: 31 May 2021
Accepted Date: 3 June 2021
Available Online: 12 June 2021

Figures(5)

A novel Zn^II-based metal-organic framework with the formula of {[Zn₂(BBIP)₂(NDC)₂]·H₂O}_n (JXUST-5) derived from 3, 5-bis(benzimidazol-1-yl)pyridine (BBIP) and 1, 4-naphthalenedicarboxylic acid (H₂NDC) has been synthesized. The adjacent Zn^II ions are linked through two BBIP ligands to form a [Zn₂(BBIP)₂] secondary building unit (SBU). The neighbouring SBUs are further connected by NDC²⁻ with μ₂-η¹: η¹ and μ₂-η¹: η¹: η¹ bridging modes to form a two-dimensional (2D) framework. Topological analysis shows that JXUST-5 could be simplified as an uninodal fes topology with a point symbol of {4.8²}. Furthermore, the 2D framework net could be extended through C-H···π interaction to form the three-dimensional supramolecular structure. Luminescent experiments suggest that JXUST-5 could selectively and sensitively recognize Al³⁺ and Ga³⁺ through fluorescence enhancement effect along with a relatively large red shift. The detection limits for Al³⁺ and Ga³⁺ are 0.17 and 0.69 ppm, respectively. Interestingly, the sensing process for both Al³⁺ and Ga³⁺ could be directly observed with naked eyes under 365 nm UV lamp. Notably, JXUST-5 could be recycled at least five times as a fluorescent sensor toward Al³⁺ and Ga³⁺, which is the second example of turn-on MOF based fluorescent sensor toward Ga³⁺.
- Metal-organic frameworks,
- Fluorescence probe,
- Naked-eye detection,
- Turn-on effect,
- Red shift emission,
- Al³⁺ and Ga³⁺
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Highly selective and turn-on fluorescence probe with red shift emission for naked-eye detecting Al3+ and Ga3+ based on metal-organic framework

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通讯作者: 陈斌, bchen63@163.com

Highly selective and turn-on fluorescence probe with red shift emission for naked-eye detecting Al³⁺ and Ga³⁺ based on metal-organic framework