Citation: Munir Ullah Khan, Safir Ullah Khan, Jiraya Kiriratnikom, Shah Zareen, Xinghong Zhang. CoCo-PBA/tetrabutylammonium bromide as highly efficient catalyst for CO₂ and epoxides coupling reaction under mild conditions[J]. Chinese Chemical Letters, ;2022, 33(2): 1081-1086. doi: 10.1016/j.cclet.2021.06.002 shu

CoCo-PBA/tetrabutylammonium bromide as highly efficient catalyst for CO₂ and epoxides coupling reaction under mild conditions

a.
MOE Key Laboratory of Macromolecular Synthesis and Functionalization, Department of Polymer Science and Engineering, Zhejiang University, Hangzhou 310027, China
b.
Hefei National Laboratory for Physical Science at the Microscale, School of Life Sciences, University of Science and Technology of China, Hefei 230027, China
c.
National Synchrotron Radiation Laboratory, Department of Chemical Physics and Key Laboratory of Surface and Interface Chemistry and Energy Catalysis of Anhui Higher Education Institutes, University of Science and Technology of China, Hefei 230029, China

xhzhang@zju.edu.cn

Received Date: 19 April 2021
Revised Date: 24 May 2021
Accepted Date: 1 June 2021
Available Online: 12 June 2021

Figures(5)

The development of effective and low-energy-consumption catalysts for CO₂ conversion into high-value-added products by constructing versatile active sites on the surface of heterogeneous compounds is an urgent and challenging task. In this study, a stable and well-defined heterogeneous cobalt hexacyanocobaltate (Co₃[Co(CN)₆]₂), typical cobalt Prussian blue analogue (CoCo-PBA) modified with tetrabutylammonium bromide (TBAB), is proven to be the superior catalyst for CO₂ and epoxide coupling to produce cyclic carbonates with > 99% yield under mild reaction conditions (1.0 MPa, 65 ℃). Based on a series of characterizations, it is revealed that the CoCo-PBA structure can maintain relatively high thermal and chemical stability. Recycling experiments exhibited that the CoCo-PBA system could retain 98% of the original activity after six reaction rounds. The CoCo-PBA/TBAB catalytic system was also highly active for coupling CO₂ with other industrial-grade epoxides. These results show the CoCo-PBA catalytic system potential flexibility and the generality of the catalyst preparation strategy.
- CO₂ conversion,
- Cyclic carbonates,
- Prussian blue analogue,
- Heterogeneous catalysis,
- Co₃[Co(CN)₆]₂
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沈阳化工大学材料科学与工程学院沈阳 110142

CoCo-PBA/tetrabutylammonium bromide as highly efficient catalyst for CO2 and epoxides coupling reaction under mild conditions

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通讯作者: 陈斌, bchen63@163.com

CoCo-PBA/tetrabutylammonium bromide as highly efficient catalyst for CO₂ and epoxides coupling reaction under mild conditions