Citation: Huixian Yang, Yanmei Guo, Guoning Liu, Ruowei Song, Jinxi Chen, Yongbing Lou, Yixin Zhao. Near UV luminescent Cs₂NaBi_0.75Sb_0.25Cl₆ perovskite colloidal nanocrystals with high stability[J]. Chinese Chemical Letters, ;2022, 33(1): 537-540. doi: 10.1016/j.cclet.2021.05.071 shu

Near UV luminescent Cs₂NaBi_0.75Sb_0.25Cl₆ perovskite colloidal nanocrystals with high stability

Huixian Yang ^a ,
Yanmei Guo ^a ,
Guoning Liu ^{a, *,} ,
Ruowei Song ^a ,
Jinxi Chen ^a ,
Yongbing Lou ^{a, *,} ,
Yixin Zhao ^{b, *,}

a.
School of Chemistry and Chemical Engineering, Jiangsu Key Laboratory for Science and Application of Molecular Ferroelectrics, Jiangsu Engineering Laboratory of Smart Carbon-Rich Materials and Devices, Southeast University, Nanjing 211189, China
b.
School of Environmental Science and Engineering, Shanghai Jiao Tong University, Shanghai 200240, China

liuguoning234232@163.com

lou@seu.edu.cn

yixin.zhao@sjtu.edu.cn

Received Date: 2 April 2021
Revised Date: 14 May 2021
Accepted Date: 31 May 2021
Available Online: 20 June 2021

Figures(4)

Near UV highly luminescent colloidal Cs₂NaBiCl₆ nanocrystals (NCs) were synthesized by a simple low-cost ligand-assisted reprecipitation method. In our strategy, metal chloride precursors were added to the mixture of anti-solvent and ligand at room-temperature. The obtained Cs₂NaBiCl₆ NCs exhibited a bright blue emission with significantly improved photoluminescence quantum yield (PLQY) of 39.05%. The optical properties and stability were greatly enhanced by doping Sb where Cs₂NaBi_0.75Sb_0.25Cl₆ showed a high PLQY of 46.57%, and both the powder and the colloidal solution exhibited superior stability.
- Perovskite nanocrystals,
- Ligand-assisted reprecipitation,
- Stability,
- Cs₂NaBiCl₆,
- Cs₂NaBi_0.75Sb_0.25Cl₆
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Near UV luminescent Cs2NaBi0.75Sb0.25Cl6 perovskite colloidal nanocrystals with high stability

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通讯作者: 陈斌, bchen63@163.com

Near UV luminescent Cs₂NaBi_0.75Sb_0.25Cl₆ perovskite colloidal nanocrystals with high stability