Citation: Mengyang Bai, Guanyu Tao, Zhenxing Liu, Lili Wang, Zheng Duan. A facile access to mono-C-alkynylated-o-carboranes from o-carboranes and arylsulfonylacetylenes[J]. Chinese Chemical Letters, ;2022, 33(1): 201-204. doi: 10.1016/j.cclet.2021.05.062 shu

A facile access to mono-C-alkynylated-o-carboranes from o-carboranes and arylsulfonylacetylenes

College of Chemistry, Green Catalysis Center, International Phosphorus Laboratory, International Joint Research Laboratory for Functional Organophosphorus Materials of Henan Province, Zhengzhou University, Zhengzhou 450001, China

wanglili@zzu.edu.cn

duanzheng@zzu.edu.cn

Received Date: 21 March 2021
Revised Date: 27 May 2021
Accepted Date: 27 May 2021
Available Online: 3 June 2021

Figures(4)

A facile access to mono-C-alkynyl-o-carboranes from o-carboranes and arylsulfonylacetylenes was developed. This facile process tolerates a wide variety of functional groups, occurs at mild conditions in one-pot procedure with short reaction time. The obtained mono-C-alkynyl-o-carboranes can be easily derivatized to synthesize 1, 2-difunctionalized o-carboranes. This work provides a useful tool for the functionalization of o-carboranes.
- Alkynylation,
- o-Carborane,
- Arylsulfonylacetylene,
- Transition-metal-free,
- 1, 2-Difunctionalized o-carborane
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