Citation: Hui Yu, Xiang Wu, Qiaoqiao Mu, Zhihe Wei, Yindong Gu, Xuzhou Yuan, Yongtao Lu, Zhao Deng, Yang Peng. Robust photocatalytic hydrogen production on metal-organic layers of Al-TCPP with ultrahigh turnover numbers[J]. Chinese Chemical Letters, ;2021, 32(12): 3833-3836. doi: 10.1016/j.cclet.2021.05.035 shu

Robust photocatalytic hydrogen production on metal-organic layers of Al-TCPP with ultrahigh turnover numbers

Hui Yu ^{a, b} ,
Xiang Wu ^{a, b} ,
Qiaoqiao Mu ^{a, b} ,
Zhihe Wei ^{a, b} ,
Yindong Gu ^{a, b} ,
Xuzhou Yuan ^{a, b} ,
Yongtao Lu ^{a, b, *,} ,
Zhao Deng ^{a, b} ,
Yang Peng ^{a, b, *,}

a.
Soochow Institute for Energy and Materials Innovations, College of Energy, Soochow University, Suzhou 215006, China
b.
Key Laboratory of Advanced Carbon Materials and Wearable Energy Technologies of Jiangsu Province, Soochow University, Suzhou 215006, China

sudalyt@suda.edu.cn

ypeng@suda.edu.cn

Received Date: 27 April 2021
Revised Date: 11 May 2021
Accepted Date: 18 May 2021
Available Online: 25 May 2021

Figures(4)

The development of robust photocatalytic systems is key to harvest the solar power for hydrogen production. In the current study, a series of aluminum-based porphyrinic metal organic frameworks (Al-TCPP) with various morphologies of bulk, carambola-like and nanosheets are synthesized with modulated layer thickness. Morphology-dependent photocatalytic activities in hydrogen production are witnessed and inversely correlate to the thickness of the Al-TCPP micro-platelets or nanosheets. Particularly, the exfoliated metal organic layers (MOLs) of Al-TCPP demonstrated a high hydrogen yield rate of 1.32 × 10⁴ µmol h⁻¹ g⁻¹ that is 21-fold of that from the bulk catalyst, as well as an exceptional TON of 6704 that seldom seen in literature. Through comprehensive photochemical characterizations, the remarkable photocatalytic performance of Al-TCPP-MOL is attributed to the great charge separation efficiency and transfer kinetics endowed by the ultrathin 2D morphology with extended active surface area.
- Photocatalysis,
- Metal organic layers,
- Al-TCPP,
- Hydrogen production,
- Turnover numbers
1. [1]
  C. Acar, I. Dincer, G.F. Naterer, Int. J. Energ. Res. 40(2016) 1449-1473. doi: 10.1002/er.3549
2. [2]
  Y. Zheng, P.Z. Wang, Chin. J. Catal. 34(2013) 524-535. doi: 10.1016/S1872-2067(12)60548-8
3. [3]
  X. Chen, S. Shen, L. Guo, S.S. Mao, Chem. Rev. 110(2010) 6503-6570. doi: 10.1021/cr1001645
4. [4]
  A.A. Ismail, D.W. Bahnemann, Sol. Energ. Mat. Sol. C 128(2014) 85-101. doi: 10.1016/j.solmat.2014.04.037
5. [5]
  Z. Wang, C. Li, K. Domen, Chem. Soc. Rev. 48(2019) 2109-2125. doi: 10.1039/C8CS00542G
6. [6]
  Q. Wang, K. Domen, Chem. Rev. 120(2020) 919-985. doi: 10.1021/acs.chemrev.9b00201
7. [7]
  A. Kubacka, M. Fernández-García, G. Colón, Chem. Rev. 112(2012) 1555-1614. doi: 10.1021/cr100454n
8. [8]
  L.J. Guo, Y.B. Chen, J. Z Su, M.C. Liu, Y. Liu, Energy 172(2019) 1079-1086. doi: 10.1016/j.energy.2019.02.050
9. [9]
  A. Naldoni, M. Altomare, G. Zoppellaro, et al., ACS Catal. 9(2019) 345-364. doi: 10.1021/acscatal.8b04068
10. [10]
  J.A. Nasir, Z.U. Rehman, S.N.A. Shah, et al., J. Mater. Chem. A 8(2020) 20752-20780. doi: 10.1039/D0TA05834C
11. [11]
  S. Wang, J. Zhang, B. Li, H. Sun, S. Wang, Energy Fuel 35(2021) 6504-6526. doi: 10.1021/acs.energyfuels.1c00503
12. [12]
  Q. Xiang, J. Yu, J. Phys. Chem. Lett. 4(2013) 753-759. doi: 10.1021/jz302048d
13. [13]
  T. He, K. Geng, D. Jiang, ACS Mater. Lett. 1(2019) 203-208. doi: 10.1021/acsmaterialslett.9b00153
14. [14]
  P. Ganguly, M. Harb, Z. Cao, et al., ACS Energy Lett. 4(2019) 1687-1709. doi: 10.1021/acsenergylett.9b00940
15. [15]
  X. Wang, C. Zhou, R. Shi, et al., Nano Res. 12(2019) 2385-2389. doi: 10.1007/s12274-019-2357-0
16. [16]
  X.S. Wang, C. Zhou, R. Shi, Q.Q. Liu, T.R. Zhang, Rare Metal. 38(2019) 397-403. doi: 10.1007/s12598-019-01212-7
17. [17]
  Q. Mu, Y. Su,; . Z. Wei, et al., J. Catal. 397(2021) 128-136. doi: 10.1016/j.jcat.2021.03.018
18. [18]
  W. Zhu, C. Zhang, Q. Li, et al., Appl. Catal. B: Environ. 238(2018) 339-345. doi: 10.1016/j.apcatb.2018.07.024
19. [19]
  Y. Ma, Y. Lu, G. Hai, et al., Sci. Bull. 65(2020) 658-669. doi: 10.1016/j.scib.2020.02.001
20. [20]
  L. Wang, H. Fan, F. Bai, MRS Bull. 45(2020) 49-56. doi: 10.1557/mrs.2019.294
21. [21]
  Q. Zuo, T. Liu, C. Chen, et al., Angew. Chem. Int. Ed. 58(2019) 10198-10203. doi: 10.1002/anie.201904058
22. [22]
  P. Liao, Y. Hu, Z. Liang, et al., J. Mater. Chem. A 6(2018) 3195-3201. doi: 10.1039/C7TA09785A
23. [23]
  T. He, S. Chen, B. Ni, et al., Angew. Chem. Int. Ed. 57(2018) 3493-3498. doi: 10.1002/anie.201800817
24. [24]
  X. Fang, Q. Shang, Y. Wang, et al., Adv. Mater. 30(2018) 1705112. doi: 10.1002/adma.201705112
25. [25]
  J.D. Xiao, Q. Shang, Y. Xiong, et al., Angew. Chem. Int. Ed. 55(2016) 9389-9393. doi: 10.1002/anie.201603990
26. [26]
  M. Zhu, Y. Du, P. Yang, X. Wang, Catal. Sci. Technol. 3(2013) 2295-2302. doi: 10.1039/c3cy00236e
27. [27]
  A. Fateeva, P.A. Chater, C.P. Ireland, et al., Angew. Chem. Int. Ed. 51(2012) 7440-7444. doi: 10.1002/anie.201202471
28. [28]
  X. Zhang, M. Cibian, A. Call, K. Yamauchi, K.P. Sakai, ACS Catal. 9(2019) 11263-11273. doi: 10.1021/acscatal.9b04023
29. [29]
  Y. Kuramochi, Y. Fujisawa, A. Satake, J. Am. Chem. Soc. 142(2020) 705-709. doi: 10.1021/jacs.9b12712
30. [30]
  X. Wang, X. Zhang, W. Zhou, et al., Nano Energy 62(2019) 250-258. doi: 10.1016/j.nanoen.2019.05.023
31. [31]
  H. Hu, Z. Wang, L. Cao, et al., Nat. Chem. 13(2021) 358-366. doi: 10.1038/s41557-020-00635-5
32. [32]
  Y. Liu, L. Liu, X. Chen, et al., Y., J. Am. Chem. Soc. 143(2021) 3509-3518. doi: 10.1021/jacs.0c13005
33. [33]
  N. Sadeghi, S. Sharifnia, T.O. Do, J. Mater. Chem. A 6(2018) 18031-18035. doi: 10.1039/C8TA07158F
34. [34]
  Y. Liu, Y. Yang, Q. Sun, et al., ACS Appl. Mater. Interfaces 5(2013) 7654-7658. doi: 10.1021/am4019675
35. [35]
  D. Sun, J.W. Shi, D. Ma, et al., Chin. J. Catal. 41(2020) 1421-1429. doi: 10.1016/S1872-2067(20)63576-8
1. [1]
  Tianhao Li , Wenguang Tu , Zhigang Zou . In situ photocatalytically enhanced thermogalvanic cells for electricity and hydrogen production. Chinese Journal of Structural Chemistry, 2024, 43(1): 100195-100195. doi: 10.1016/j.cjsc.2024.100195
2. [2]
  Wengao Zeng , Yuchen Dong , Xiaoyuan Ye , Ziying Zhang , Tuo Zhang , Xiangjiu Guan , Liejin Guo . Crystalline carbon nitride with in-plane built-in electric field accelerates carrier separation for excellent photocatalytic hydrogen evolution. Chinese Chemical Letters, 2024, 35(4): 109252-. doi: 10.1016/j.cclet.2023.109252
3. [3]
  Zhen Shi , Wei Jin , Yuhang Sun , Xu Li , Liang Mao , Xiaoyan Cai , Zaizhu Lou . Interface charge separation in Cu2CoSnS4/ZnIn2S4 heterojunction for boosting photocatalytic hydrogen production. Chinese Journal of Structural Chemistry, 2023, 42(12): 100201-100201. doi: 10.1016/j.cjsc.2023.100201
4. [4]
  Guixu Pan , Zhiling Xia , Ning Wang , Hejia Sun , Zhaoqi Guo , Yunfeng Li , Xin Li . Preparation of high-efficient donor-π-acceptor system with crystalline g-C3N4 as charge transfer module for enhanced photocatalytic hydrogen evolution. Chinese Journal of Structural Chemistry, 2024, 43(12): 100463-100463. doi: 10.1016/j.cjsc.2023.100463
5. [5]
  Jiaqi Ma , Lan Li , Yiming Zhang , Jinjie Qian , Xusheng Wang . Covalent organic frameworks: Synthesis, structures, characterizations and progress of photocatalytic reduction of CO2. Chinese Journal of Structural Chemistry, 2024, 43(12): 100466-100466. doi: 10.1016/j.cjsc.2024.100466
6. [6]
  Weixu Li , Yuexin Wang , Lin Li , Xinyi Huang , Mengdi Liu , Bo Gui , Xianjun Lang , Cheng Wang . Promoting energy transfer pathway in porphyrin-based sp2 carbon-conjugated covalent organic frameworks for selective photocatalytic oxidation of sulfide. Chinese Journal of Structural Chemistry, 2024, 43(7): 100299-100299. doi: 10.1016/j.cjsc.2024.100299
7. [7]
  Jia-Cheng Hou , Wei Cai , Hong-Tao Ji , Li-Juan Ou , Wei-Min He . Recent advances in semi-heterogenous photocatalysis in organic synthesis. Chinese Chemical Letters, 2025, 36(2): 110469-. doi: 10.1016/j.cclet.2024.110469
8. [8]
  Yue Pan , Wenping Si , Yahao Li , Haotian Tan , Ji Liang , Feng Hou . Promoting exciton dissociation by metal ion modification in polymeric carbon nitride for photocatalysis. Chinese Chemical Letters, 2024, 35(12): 109877-. doi: 10.1016/j.cclet.2024.109877
9. [9]
  Xiao-Ya Yuan , Cong-Cong Wang , Bing Yu . Recent advances in FeCl₃-photocatalyzed organic reactions via hydrogen-atom transfer. Chinese Chemical Letters, 2024, 35(9): 109517-. doi: 10.1016/j.cclet.2024.109517
10. [10]
  Rongxin Zhu , Shengsheng Yu , Xuanzong Yang , Ruyu Zhu , Hui Liu , Kaikai Niu , Lingbao Xing . Construction of pyrene-based hydrogen-bonded organic frameworks as photocatalysts for photooxidation of styrene in water. Chinese Chemical Letters, 2024, 35(10): 109539-. doi: 10.1016/j.cclet.2024.109539
11. [11]
  Bowen Li , Ting Wang , Ming Xu , Yuqi Wang , Zhaoxing Li , Mei Liu , Wenjing Zhang , Ming Feng . Structuring MoO₃-polyoxometalate hybrid superstructures to boost electrocatalytic hydrogen evolution reaction. Chinese Chemical Letters, 2025, 36(2): 110467-. doi: 10.1016/j.cclet.2024.110467
12. [12]
  Qiang Zhang , Weiran Gong , Huinan Che , Bin Liu , Yanhui Ao . S doping induces to promoted spatial separation of charge carriers on carbon nitride for efficiently photocatalytic degradation of atrazine. Chinese Journal of Structural Chemistry, 2023, 42(12): 100205-100205. doi: 10.1016/j.cjsc.2023.100205
13. [13]
  Ziruo Zhou , Wenyu Guo , Tingyu Yang , Dandan Zheng , Yuanxing Fang , Xiahui Lin , Yidong Hou , Guigang Zhang , Sibo Wang . Defect and nanostructure engineering of polymeric carbon nitride for visible-light-driven CO2 reduction. Chinese Journal of Structural Chemistry, 2024, 43(3): 100245-100245. doi: 10.1016/j.cjsc.2024.100245
14. [14]
  Mengjun Zhao , Yuhao Guo , Na Li , Tingjiang Yan . Deciphering the structural evolution and real active ingredients of iron oxides in photocatalytic CO2 hydrogenation. Chinese Journal of Structural Chemistry, 2024, 43(8): 100348-100348. doi: 10.1016/j.cjsc.2024.100348
15. [15]
  Jiangqi Ning , Junhan Huang , Yuhang Liu , Yanlei Chen , Qing Niu , Qingqing Lin , Yajun He , Zheyuan Liu , Yan Yu , Liuyi Li . Alkyl-linked TiO2@COF heterostructure facilitating photocatalytic CO2 reduction by targeted electron transport. Chinese Journal of Structural Chemistry, 2024, 43(12): 100453-100453. doi: 10.1016/j.cjsc.2024.100453
16. [16]
  Yanghanbin Zhang , Dongxiao Wen , Wei Sun , Jiahe Peng , Dezhong Yu , Xin Li , Yang Qu , Jizhou Jiang . State-of-the-art evolution of g-C3N4-based photocatalytic applications: A critical review. Chinese Journal of Structural Chemistry, 2024, 43(12): 100469-100469. doi: 10.1016/j.cjsc.2024.100469
17. [17]
  Yuehai Zhi , Chen Gu , Huachao Ji , Kang Chen , Wenqi Gao , Jianmei Chen , Dafeng Yan . The advanced development of innovative photocatalytic coupling strategies for hydrogen production. Chinese Chemical Letters, 2025, 36(1): 110234-. doi: 10.1016/j.cclet.2024.110234
18. [18]
  Deqi Fan , Yicheng Tang , Yemei Liao , Yan Mi , Yi Lu , Xiaofei Yang . Two birds with one stone: Functionalized wood composites for efficient photocatalytic hydrogen production and solar water evaporation. Chinese Chemical Letters, 2024, 35(9): 109441-. doi: 10.1016/j.cclet.2023.109441
19. [19]
  Lihua Ma , Song Guo , Zhi-Ming Zhang , Jin-Zhong Wang , Tong-Bu Lu , Xian-Shun Zeng . Sensitizing photoactive metal–organic frameworks via chromophore for significantly boosting photosynthesis. Chinese Chemical Letters, 2024, 35(5): 108661-. doi: 10.1016/j.cclet.2023.108661
20. [20]
  Chaoqun Ma , Yuebo Wang , Ning Han , Rongzhen Zhang , Hui Liu , Xiaofeng Sun , Lingbao Xing . Carbon dot-based artificial light-harvesting systems with sequential energy transfer and white light emission for photocatalysis. Chinese Chemical Letters, 2024, 35(4): 108632-. doi: 10.1016/j.cclet.2023.108632

Get Citation

PDF

XML

Metrics

PDF Downloads(6)
Abstract views(445)
HTML views(8)

通讯作者: 陈斌, bchen63@163.com

1.
沈阳化工大学材料科学与工程学院沈阳 110142