Citation: Yongle Ding, Chengshuo Shen, Fuwei Gan, Jinghao Wang, Guoli Zhang, Lingling Li, Mouhai Shu, Bangshang Zhu, Jeanne Crassous, Huibin Qiu. Tunable construction of transition metal-coordinated helicene cages[J]. Chinese Chemical Letters, ;2021, 32(12): 3988-3992. doi: 10.1016/j.cclet.2021.05.033 shu

Tunable construction of transition metal-coordinated helicene cages

Yongle Ding ^{a, b} ,
Chengshuo Shen ^{a, *,} ,
Fuwei Gan ^a ,
Jinghao Wang ^a ,
Guoli Zhang ^a ,
Lingling Li ^b ,
Mouhai Shu ^a ,
Bangshang Zhu ^{b, *,} ,
Jeanne Crassous ^c ,
Huibin Qiu ^{a, *,}

a.
School of Chemistry and Chemical Engineering, Frontiers Science Center for Transformative Molecules, State Key Laboratory of Metal Matrix Composites, Shanghai Jiao Tong University, Shanghai 200240, China
b.
Instrumental Analysis Center, Shanghai Jiao Tong University, Shanghai 200240, China
c.
Univ Rennes, Institut des Sciences Chimiques de Rennes, UMR CNRS 6226, Campus de Beaulieu, Rennes 35042, France

shenchengshuo@sjtu.edu.cn

shenchengshuo@live.com

bshzhu@sjtu.edu.cn

hbqiu@sjtu.edu.cn

Received Date: 24 March 2021
Revised Date: 13 May 2021
Accepted Date: 16 May 2021
Available Online: 27 May 2021

Figures(4)

We report a facile and tailored method to prepare globally twisted chiral molecular cages through tunable coordination of bis-bipyridine-terminated helicene ligands to a series of transition metals including Fe(II), Co(II), Ni(II) and Zn(II). This system shows an efficient remote transfer of stereogenecity from the helicene core to the bipyridine-metal coordination sites and subsequently the entire cages. While the Fe(II), Co(II) and Ni(II)-derived M₂L₃ (M for metal and L for ligand) cages exhibit quasi-reversible redox features, the Zn(II) analogues reveal prominent yellow circularly polarized luminescence. Interestingly, with the addition of Na₂SO₄, the Zn₂L₃ cages reassemble into sextuple-stranded Zn₆L₆(SO₄)₄ cages in which three Zn₂L₂ units are bound together by four sulfates and further coalesced by offset inter-ligand π-π interactions.
- Helicene,
- Coordination cage,
- Chiral,
- Global helicity,
- Circularly polarized luminescence
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