Citation: Kaichuan Yan, Hua He, Jianglian Li, Yi Luo, Ruizhi Lai, Li Guo, Yong Wu. Blue light-promoted cyclopropenizations of N-tosylhydrazones in water[J]. Chinese Chemical Letters, ;2021, 32(12): 3984-3987. doi: 10.1016/j.cclet.2021.05.031 shu

Blue light-promoted cyclopropenizations of N-tosylhydrazones in water

Key Laboratory of Drug-Targeting and Drug Delivery System of the Education Ministry and Department of Medicinal Chemistry, Sichuan Engineering Laboratory for Plant-Sourced Drug and Sichuan Research Center for Drug Precision Industrial Technology, West China School of Pharmacy, Sichuan University, Chengdu 610041, China

guoli@scu.edu.cn

wyong@scu.edu.cn

Received Date: 10 March 2021
Revised Date: 10 May 2021
Accepted Date: 16 May 2021
Available Online: 24 May 2021

Figures(6)

Carbene transfer reactions play an important role in the field of organic synthesis because of their ability to construct a variety of molecules. Herein, we reported on blue light-induced cyclopropenizations of N-tosylhydrazones in water, which avoids the use of expensive metal-based catalysts and toxic organic solvents. This metal-free and operationally simple methodology enable highly efficient cyclopropenizations, X-H insertion reactions, and cyclopropanation under mild reaction conditions.
- N-Tosylhydrazone,
- Carbene,
- Metal-free,
- Cyclopropenization,
- Cyclopropanation
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