Citation: Shasha Zheng, Yue Ru, Huaiguo Xue, Huan Pang. Fluorinated pillared-layer metal-organic framework microrods for improved electrochemical cycling stability[J]. Chinese Chemical Letters, ;2021, 32(12): 3817-3820. doi: 10.1016/j.cclet.2021.05.010 shu

Fluorinated pillared-layer metal-organic framework microrods for improved electrochemical cycling stability

School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225009, China

chhgxue@yzu.edu.cn

huanpangchem@hotmail.com

panghuan@yzu.edu.cn

Received Date: 2 April 2021
Revised Date: 2 May 2021
Accepted Date: 10 May 2021
Available Online: 20 May 2021

Figures(4)

Developing metal-organic framework (MOF)-based materials with good cyclic stability is the key to their practical application. Fluorinated organic compounds are usually highly chemically stability due to the high electronegativity of fluorine. Also, the pillared-layer structures based on coordination bonds have better structure and thermal stability than those based on hydrogen bonds. Herein, the fluorinated pillared-layer [Ni(2, 3, 4, 5-tetrafluorobenzoic acid)(4, 4′-bipyridine)]_n MOF ([Ni(TFBA)(Bpy)]_n) materials were constructed through a facile room-temperature solution reaction and used as electrode materials for supercapacitors. Surprisingly, the size/morphology of Ni(TFBA)(Bpy)]_n MOFs could be adjusted by varying the synthesis time. Benefting from the short ion diffusion length, unique pillar-layer structure, and strong intercomponent synergy of organic ligands, the Ni(TFBA)(Bpy)]_n MOF microrods showed a higher electrochemical energy storage capability than bulk MOFs. At the same time, compared to the non-fluorinated [Ni(benzoic acid)(Bpy)]_n MOFs (31.5% capacitance decay), the fluorinated Ni(TFBA)(Bpy)]_n MOFs have a higher cycle stability with only 2.6% capacitance loss after 5000 cycles at 3 mA/cm².
- Fluorinated metal-organic framework,
- Pillar-layer structure,
- Microrod,
- Cyclic stability,
- Electrochemical energy storage,
- Supercapacitor
1. [1]
  Z. Jiang, X. Xu, Y. Ma, et al., Nature 586(2020) 549-554. doi: 10.1038/s41586-020-2738-2
2. [2]
  X. Li, X. Yang, H. Xue, H. Pang, Q. Xu, EnergyChem 2(2020) 100027. doi: 10.1016/j.enchem.2020.100027
3. [3]
  T. Qiu, S. Gao, Z. Liang, et al., Angew. Chem. Int. Ed. (2021), doi: 10.1002/anie.202012699. doi: 10.1002/anie.202012699
4. [4]
  D. Li, H.Q. Xu, L. Jiao, H.L. Jiang, EnergyChem 1(2019) 100005. doi: 10.1016/j.enchem.2019.100005
5. [5]
  C.C. Hou, H.F. Wang, C. Li, Q. Xu, Energy Environ. Sci. 13(2020) 1658-1693. doi: 10.1039/C9EE04040D
6. [6]
  G. Yuan, S. Yu, J. Jie, et al., Chin. Chem. Lett. 31(2020) 1941-1945. doi: 10.1016/j.cclet.2019.12.034
7. [7]
  H. Jiang, X.C. Liu, Y. Wu, et al., Angew. Chem. Int. Ed. 130(2018) 3980-3985. doi: 10.1002/ange.201712872
8. [8]
  J. Gu, Y. Xu, Q. Li, H. Pang, Chin. Chem. Lett. 32(2021) 2017-2020. doi: 10.1016/j.cclet.2020.11.066
9. [9]
  S. Zheng, X. Li, B. Yan, et al., Adv. Energy Mater. 7(2017) 1602733. doi: 10.1002/aenm.201602733
10. [10]
  D. Sheberla, J.C. Bachman, J.S. Elias, et al., Nat. Mater. 16(2017) 220-224. doi: 10.1038/nmat4766
11. [11]
  Y. Li, Y. Shan, H. Pang, Chin. Chem. Lett. 31(2020) 2280-2286. doi: 10.1016/j.cclet.2020.03.027
12. [12]
  D.D. Zhou, X.W. Zhang, Z.W. Mo, et al., EnergyChem 1(2019) 100016. doi: 10.1016/j.enchem.2019.100016
13. [13]
  S. Zheng, Q. Li, H. Xue, H. Pang, Q. Xu, Natl. Sci. Rev. 7(2020) 305-314. doi: 10.1093/nsr/nwz137
14. [14]
  L. Wang, X. Feng, L. Ren, et al., J. Am. Chem. Soc. 137(2015) 4920-4923. doi: 10.1021/jacs.5b01613
15. [15]
  X.F. Lu, P.Q. Liao, J.W. Wang, et al., J. Am. Chem. Soc. 138(2016) 8336-8339. doi: 10.1021/jacs.6b03125
16. [16]
  S. Zheng, Y. Zheng, H. Xue, H. Pang, Chem. Eng. J. 395(2020) 125166. doi: 10.1016/j.cej.2020.125166
17. [17]
  S. Zhao, Y. Wang, J. Dong, et al., Nat. Energy 1(2016) 16184. doi: 10.1038/nenergy.2016.184
18. [18]
  H. Guo, Y. Zhu, S. Wang, et al., Chem. Mater. 24(2012) 444-450. doi: 10.1021/cm202593h
19. [19]
  X. Xiao, L. Zou, H. Pang, Q. Xu, Chem. Soc. Rev. 49(2020) 301-331. doi: 10.1039/C7CS00614D
20. [20]
  M. Zhao, Y. Huang, Y. Peng, et al., Chem. Soc. Rev. 47(2018) 6267-6295. doi: 10.1039/C8CS00268A
21. [21]
  D.D. Zhou, P. Chen, C. Wang, et al., Nat. Mater. 18(2019) 994-998. doi: 10.1038/s41563-019-0427-z
22. [22]
  C. Wang, D.D. Zhou, Y.W. Gan, et al., Natl. Sci. Rev. (2020) 1-9.
23. [23]
  C. Wang, J. Huang, R.K. Huang, et al., Inorg. Chem. 58(2019) 3944-3949. doi: 10.1021/acs.inorgchem.9b00006
24. [24]
  A. Cadiau, Y. Belmabkhout, K. Adil, et al., Science 356(2017) 731-735. doi: 10.1126/science.aam8310
25. [25]
  J. Huang, Y. Li, R.K. Huang, et al., Angew. Chem. Int. Ed. 57(2018) 4632-4636. doi: 10.1002/anie.201801029
26. [26]
  L. Li, J.D. Yi, Z.B. Fang, et al., Chem. Mater. 31(2019) 7584-7589. doi: 10.1021/acs.chemmater.9b02375
27. [27]
  R.G. Pearson, J. Am. Chem. Soc. 85(1963) 3533-3539. doi: 10.1021/ja00905a001
28. [28]
  S. Yuan, L. Feng, K. Wang, et al., Adv. Mater. 30(2018) 1-35.
29. [29]
  Z. Hulvey, E. Ayala, A.K. Cheetham, Zeitschrift Für Anorg. Und Allg. Chem. 635(2009) 1753-1757. doi: 10.1002/zaac.200900312
30. [30]
  C. Shi, X. Wang, Y. Gao, et al., J. Solid State Electrochem. 21(2017) 2415-2423. doi: 10.1007/s10008-017-3591-6
31. [31]
  X. Zhang, S. Liu, Y. Zang, et al., Nano Energy 30(2016) 93-102. doi: 10.1016/j.nanoen.2016.09.040
32. [32]
  S. Huang, Y. Li, Y. Feng, et al., J. Mater. Chem. A 3(2015) 23095-23105. doi: 10.1039/C5TA06012E
33. [33]
  S. Liu, X. Zhang, G. Wang, Y. Zhang, H. Zhang, ACS Appl. Mater. Interfaces 9(2017) 34269-34278. doi: 10.1021/acsami.7b11101
34. [34]
  F. Zhou, H. Huang, C. Xiao, et al., J. Am. Chem. Soc. 140(2018) 8198-8205. doi: 10.1021/jacs.8b03235
35. [35]
  V. Augustyn, J. Come, M.A. Lowe, et al., Nat. Mater. 12(2013) 518-522. doi: 10.1038/nmat3601
36. [36]
  Q. Wang, Y. Luo, R. Hou, et al., Adv. Mater. 31(2019) 1905744. doi: 10.1002/adma.201905744
37. [37]
  J. Huang, Y. Xiong, Z. Peng, et al., ACS Nano 14(2020) 14201-14211. doi: 10.1021/acsnano.0c07326
38. [38]
  B. Fei, Z. Yao, D. Cai, et al., Energy Storage Mater. 25(2020) 105-113. doi: 10.1016/j.ensm.2019.10.025
39. [39]
  J. Yang, C. Zheng, P. Xiong, Y. Li, M. Wei, J. Mater. Chem. A 2(2014) 19005-19010. doi: 10.1039/C4TA04346D
40. [40]
  C. Qu, Y. Jiao, B. Zhao, et al., Nano Energy 26(2016) 66-73. doi: 10.1016/j.nanoen.2016.04.003
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