Citation: Mengxiao Sun, Yue Wang, Chunsen Sun, Yan Qi, Jia Cheng, Yumei Song, Lixue Zhang. Nitrogen-doped Co₃O₄ nanowires enable high-efficiency electrochemical oxidation of 5-hydroxymethylfurfural[J]. Chinese Chemical Letters, ;2022, 33(1): 385-389. doi: 10.1016/j.cclet.2021.05.009 shu

Nitrogen-doped Co₃O₄ nanowires enable high-efficiency electrochemical oxidation of 5-hydroxymethylfurfural

Mengxiao Sun ^a ,
Yue Wang ^a ,
Chunsen Sun ^a ,
Yan Qi ^{a, *,} ,
Jia Cheng ^a ,
Yumei Song ^{b, *,} ,
Lixue Zhang ^{a, *,}

a.
College of Chemistry and Chemical Engineering, State Key Laboratory of Bio-fibers and Eco-textiles, Qingdao University, Qingdao 266071, China
b.
Guangdong Provincial Key Laboratory of Emergency Test for Dangerous Chemicals, Institute of Analysis, Guangdong Academy of Sciences, Guangzhou 510070, China

qddxqy@qdu.edu.cn

symei2011@163.com

zhanglx@qdu.edu.cn

Received Date: 31 March 2021
Revised Date: 29 April 2021
Accepted Date: 7 May 2021
Available Online: 19 May 2021

Figures(5)

Developing highly efficient and cost-effective catalysts for electrochemically oxidizing biomass-derived 5-hydroxymethylfurfural (HMF) into value-added 2,5-furandicarboxylic acid (FDCA) is of great importance. Herein, we report a controllable nitrogen doping strategy to significantly improve the catalytic activity of Co₃O₄ nanowires for highly selective electro-oxidation of HMF into FDCA. The nitrogen doping leads to the generation of defects including nitrogen dopants and oxygen vacancies in Co₃O₄ nanowires, which is conducive to the formation of catalytically active sites. As a result, the electro-oxidation potential for HMF is only 1.38 V (vs. RHE) when the current density reaches 50 mA/cm². More importantly, the conversion rate of HMF is as high as 99.5%, and the yield of FDCA is up to 96.4%.
- Electrochemical oxidation,
- HMF,
- FDCA,
- Co₃O₄,
- Nitrogen doping
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沈阳化工大学材料科学与工程学院沈阳 110142

Nitrogen-doped Co3O4 nanowires enable high-efficiency electrochemical oxidation of 5-hydroxymethylfurfural

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通讯作者: 陈斌, bchen63@163.com

Nitrogen-doped Co₃O₄ nanowires enable high-efficiency electrochemical oxidation of 5-hydroxymethylfurfural