Citation: Tao Yu, Yiliang Chen, Yizhong Zhang, Xin Tan, Tao Xie, Boyu Shao, Xiang Huang. Novel reusable sulfate-type zirconium alginate ion-exchanger for fluoride removal[J]. Chinese Chemical Letters, ;2021, 32(11): 3410-3415. doi: 10.1016/j.cclet.2021.04.057 shu

Novel reusable sulfate-type zirconium alginate ion-exchanger for fluoride removal

Tao Yu ^{a, *,} ,
Yiliang Chen ^a ,
Yizhong Zhang ^b ,
Xin Tan ^{b, c} ,
Tao Xie ^a ,
Boyu Shao ^b ,
Xiang Huang ^{c, *,}

a.
School of Chemical Engineering and Technology, Tianjin University, Tianjin 300350, China
b.
School of Environmental Science and Engineering, Tianjin University, Tianjin 300350, China
c.
School of Science, Tibet University, Lhasa 850000, China

yutao@tju.edu.cn

xiang.huang@utibet.edu.cn

Received Date: 3 February 2021
Revised Date: 7 March 2021
Accepted Date: 30 April 2021
Available Online: 13 May 2021

Figures(5)

It is still a challenge to eliminate efficiently fluoride ion from groundwater, especially to design and synthesis an adsorbent possessing high adsorption capacity, recyclability and wide pH application conditions. Herein we present millimeter-sized sulfate-type zirconium alginate hydrogel beads with 3D network structure (AHB@Zr-SO₄²⁻) that exhibited a maximum adsorption capacity of 101.3 mg/g with wide pH applicability (pH 3−9). This material have ~2.5 times higher adsorption capacity than that of pure zirconium alginate hydrogel beads (AHB@Zr) and it was ascribed to ion exchange between SO₄²⁻ and F⁻ on the surface of AHB@Zr-SO₄²⁻, which was verified via ion chromatography measurement coupled with X-ray photoelectron spectroscopy (XPS) and Fourier Transform Infrared Spectrometer (FTIR Spectrometer) analysis. Density functional theory (DFT) calculations indicated that the ion exchange process between SO₄²⁻ and F⁻ in AHB@Zr-SO₄²⁻ was energetically favorable than OH⁻ and F⁻ in AHB@Zr. In addition, 310 bed volumes (BV) of effluent was realized via column adsorption of groundwater containing fluoride on AHB@Zr-SO₄²⁻ and indicated that it is a promising candidate for mitigating the problem of fluoride-containing groundwater.
- Fluoride ion,
- Zirconium alginate,
- Sulfate,
- Adsorption capacity,
- Ion exchange
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