Citation: Lintao Wu, Chun Han, Xiaobi Jing, Yong Yao. Rim-differentiated pillar[5]arenes[J]. Chinese Chemical Letters, ;2021, 32(11): 3322-3330. doi: 10.1016/j.cclet.2021.04.046 shu

Rim-differentiated pillar[5]arenes

Lintao Wu ^a ,
Chun Han ^a ,
Xiaobi Jing ^c ,
Yong Yao ^{b, *,}

a.
Department of Chemistry, Changzhi University, Changzhi 046011, China
b.
School of Chemistry and Chemical Engineering, Nantong University, Nantong 226019, China
c.
School of Chemistry and Chemical Engineering, Yangzhou University, Yangzhou 225009, China

yaoyong1986@ntu.edu.cn

Received Date: 25 February 2021
Revised Date: 20 April 2021
Accepted Date: 22 April 2021
Available Online: 28 April 2021

Figures(18)

Pillar[5]arenes, designed and prepared by Ogoshi et al. in 2008 initially, refer to fifth classical macrocyclics. Among a wide range of pillar[5]arenes, rim-differentiated pillar[5]arenes containing five identical substituents on one rim and five different identical groups on the other rims are considered the most noteworthy type of pillar[5]arenes. As compared with the perfunctionalized pillar[5]arene, the self-assembly properties of rim-differentiated pillar[5]arenes have more varieties. On the other hand, in comparison with other types of pillar[5]arenes, the rim-differentiated pillar[5]arenes exhibit a more rigid symmetrical structure. In the present review, the synthetic methods, host-guest interactions, self-assembly properties and applications of rim-differentiated pillar[5]arenes are summarized. Hopefully, this review will be conducive to researchers in macrocyclic supramolecular chemistry.
- Pillar[5]arene,
- Rim-differentiated,
- Self-assembly,
- Biological application,
- Controlled release
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